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1.发明申请Method for Carrying Out Multiphase Aldol Condensation Reactions to Give Mixed a, beta-Unsaturated Aldehydes 有权进行多相醛缩醇反应以得到混合的β-不饱和醛的方法公开(公告)号：US20140005441A1
公开(公告)日：2014-01-02
申请号：US13989455
申请日：2012-02-09
申请人： Dirk Bermann , Guido D. Frey , Norman Nowotny , Kurt Schalapski , Heinz Strutz
发明人： Dirk Bermann , Guido D. Frey , Norman Nowotny , Kurt Schalapski , Heinz Strutz
IPC分类号： C07C45/45
摘要： The invention relates to a continuous method for carrying out a multiphase aldol condensation reaction to obtain mixed α, β-unsaturated aldehydes by reacting a mixture of two aliphatic aldehydes having different numbers of carbon atoms, i.e. 2 to 5, in the molecule in a vertical tubular reactor in a concurrent flow in the presence of an aqueous solution of a basically reacting compound. In said method, the aldehyde mixture is dispersed in the aqueous phase in the form of drops, and the aqueous solution of the basically reacting compound flows through the tubular reactor as a continuous phase in laminar conditions.
摘要翻译： 本发明涉及一种用于进行多相醛醇缩合反应以获得混合的α，β-不饱和醛的连续方法，其通过使具有不同数目的碳原子的两个脂族醛的混合物（即2至5）在分子中以垂直方式 在基本上反应的化合物的水溶液存在的情况下，同时流动的管状反应器。 在所述方法中，醛混合物以液滴的形式分散在水相中，基本反应的化合物的水溶液在层流条件下作为连续相流动通过管式反应器。
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2.发明授权Method for carrying out multiphase aldol condensation reactions to give mixed α, β-unsaturated aldehydes 有权进行多相醛醇缩合反应的方法，得到混合的α，β-不饱和醛公开(公告)号：US08841489B2
公开(公告)日：2014-09-23
申请号：US13989455
申请日：2012-02-09
申请人： Dirk Bermann , Guido D. Frey , Norman Nowotny , Kurt Schalapski , Heinz Strutz
发明人： Dirk Bermann , Guido D. Frey , Norman Nowotny , Kurt Schalapski , Heinz Strutz
摘要： The invention relates to a continuous method for carrying out a multiphase aldol condensation reaction to obtain mixed α,β-unsaturated aldehydes by reacting a mixture of two aliphatic aldehydes having different numbers of carbon atoms, i.e. 2 to 5, in the molecule in a vertical tubular reactor in a concurrent flow in the presence of an aqueous solution of a basically reacting compound. In said method, the aldehyde mixture is dispersed in the aqueous phase in the form of drops, and the aqueous solution of the basically reacting compound flows through the tubular reactor as a continuous phase in laminar conditions.
摘要翻译： 本发明涉及一种用于进行多相醛醇缩合反应的连续方法，以通过使分子中具有不同数目的碳原子的两个脂族醛（即2至5）的混合物在分子中反应获得混合的α，β-不饱和醛 在基本上反应的化合物的水溶液存在下，并行流动的立管式反应器。 在所述方法中，醛混合物以液滴的形式分散在水相中，基本反应的化合物的水溶液在层流条件下作为连续相流动通过管式反应器。
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公开(公告)号：US08664444B2
公开(公告)日：2014-03-04
申请号：US13817155
申请日：2011-08-18
申请人： Kurt Schalapski , Norman Nowotny , Matthias Eisenacher , Dirk Bermann , Thorsten Kreickmann , Peter Heymanns , Heinz Strutz
发明人： Kurt Schalapski , Norman Nowotny , Matthias Eisenacher , Dirk Bermann , Thorsten Kreickmann , Peter Heymanns , Heinz Strutz
IPC分类号： C07C209/26
CPC分类号： C07B43/04 , B01J21/08 , B01J23/40 , B01J23/70 , B01J23/866 , C07C209/26 , C07C211/07
摘要： A continuous process for producing primary aliphatic amines having 9 to 18 carbon atoms by reaction of corresponding aliphatic aldehydes with ammonia and hydrogen in the presence of a hydrogenation catalyst in the liquid phase, characterized in that the reaction is carried out solventlessly at a molar ratio of aliphatic aldehyde:ammonia of at least 1:30, at a temperature of 100 to 200° C. and at a pressure of 6 to 11 MPa.
摘要翻译： 在液相中在氢化催化剂存在下，通过相应的脂族醛与氨和氢的反应制备具有9至18个碳原子的伯脂肪族胺的连续方法，其特征在于该反应以 脂肪醛：氨至少1:30，温度为100〜200℃，压力为6〜11MPa。
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公开(公告)号：US20130150624A1
公开(公告)日：2013-06-13
申请号：US13817155
申请日：2011-08-18
申请人： Kurt Schalapski , Norman Nowotny , Matthias Eisenacher , Dirk Bermann , Thorsten Kreickmann , Peter Heymanns , Heinz Strutz
发明人： Kurt Schalapski , Norman Nowotny , Matthias Eisenacher , Dirk Bermann , Thorsten Kreickmann , Peter Heymanns , Heinz Strutz
IPC分类号： C07B43/04 , C07C209/26
CPC分类号： C07B43/04 , B01J21/08 , B01J23/40 , B01J23/70 , B01J23/866 , C07C209/26 , C07C211/07
摘要： A continuous process for producing primary aliphatic amines having 9 to 18 carbon atoms by reaction of corresponding aliphatic aldehydes with ammonia and hydrogen in the presence of a hydrogenation catalyst in the liquid phase, characterized in that the reaction is carried out solventlessly at a molar ratio of aliphatic aldehyde:ammonia of at least 1:30, at a temperature of 100 to 200° C. and at a pressure of 6 to 11 MPa.
摘要翻译： 在液相中在氢化催化剂存在下，通过相应的脂族醛与氨和氢的反应制备具有9至18个碳原子的伯脂肪族胺的连续方法，其特征在于该反应以 脂肪醛：氨至少1:30，温度为100〜200℃，压力为6〜11MPa。
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5.发明授权Method for obtaining ditrimethylolpropane and trimethylolpropane-enriched product streams from the side-streams in trimethylolpropane production 有权在三羟甲基丙烷生产中从侧流获得二羟甲基丙烷和三羟甲基丙烷富集产物流的方法公开(公告)号：US08987523B2
公开(公告)日：2015-03-24
申请号：US13810723
申请日：2011-07-28
CPC分类号： C07C29/74 , C07C29/10 , C07C29/80 , C07C29/90 , C07C41/34 , C07C41/42 , C07C41/44 , C07C31/22 , C07C43/132
摘要： The present invention relates to a process for obtaining ditrimethylolpropane and trimethylolpropane-enriched product streams from the high-boiling fractions and residues which are obtained in the distillative purification of trimethylolpropane, wherein an aqueous solution of these fractions and residues is catalytically hydrogenated in the presence of an acidic compound and, after removing solids, contacted both with basic and with acidic ion exchangers. A trimethylolpropane-enriched product stream can be distilled out of the aqueous eluate obtained, leaving ditrimethylolpropane as the distillation residue.
摘要翻译： 本发明涉及从三沸石馏分中获得的二羟甲基丙烷和三羟甲基丙烷富集产物流以及在三羟甲基丙烷的蒸馏提纯中获得的残留物的方法，其中这些级分和残基的水溶液在 在除去固体后，与碱性和酸性离子交换剂接触。 富含三羟甲基丙烷的产物流可以从获得的水溶液中蒸馏掉，留下二羟甲基丙烷作为蒸馏残余物。
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公开(公告)号：US20130131391A1
公开(公告)日：2013-05-23
申请号：US13810723
申请日：2011-07-28
CPC分类号： C07C29/74 , C07C29/10 , C07C29/80 , C07C29/90 , C07C41/34 , C07C41/42 , C07C41/44 , C07C31/22 , C07C43/132
摘要： The present invention relates to a process for obtaining ditrimethylolpropane and trimethylolpropane-enriched product streams from the high-boiling fractions and residues which are obtained in the distillative purification of trimethylolpropane, wherein an aqueous solution of these fractions and residues is catalytically hydrogenated in the presence of an acidic compound and, after removing solids, contacted both with basic and with acidic ion exchangers. A trimethylolpropane-enriched product stream can be distilled out of the aqueous eluate obtained, leaving ditrimethylolpropane as the distillation residue.
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