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1.发明申请Method for Carrying Out Multiphase Aldol Condensation Reactions to Give Mixed a, beta-Unsaturated Aldehydes 有权进行多相醛缩醇反应以得到混合的β-不饱和醛的方法公开(公告)号：US20140005441A1
公开(公告)日：2014-01-02
申请号：US13989455
申请日：2012-02-09
申请人： Dirk Bermann , Guido D. Frey , Norman Nowotny , Kurt Schalapski , Heinz Strutz
发明人： Dirk Bermann , Guido D. Frey , Norman Nowotny , Kurt Schalapski , Heinz Strutz
IPC分类号： C07C45/45
摘要： The invention relates to a continuous method for carrying out a multiphase aldol condensation reaction to obtain mixed α, β-unsaturated aldehydes by reacting a mixture of two aliphatic aldehydes having different numbers of carbon atoms, i.e. 2 to 5, in the molecule in a vertical tubular reactor in a concurrent flow in the presence of an aqueous solution of a basically reacting compound. In said method, the aldehyde mixture is dispersed in the aqueous phase in the form of drops, and the aqueous solution of the basically reacting compound flows through the tubular reactor as a continuous phase in laminar conditions.
摘要翻译： 本发明涉及一种用于进行多相醛醇缩合反应以获得混合的α，β-不饱和醛的连续方法，其通过使具有不同数目的碳原子的两个脂族醛的混合物（即2至5）在分子中以垂直方式 在基本上反应的化合物的水溶液存在的情况下，同时流动的管状反应器。 在所述方法中，醛混合物以液滴的形式分散在水相中，基本反应的化合物的水溶液在层流条件下作为连续相流动通过管式反应器。
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2.发明授权Method for carrying out multiphase aldol condensation reactions to give mixed α, β-unsaturated aldehydes 有权进行多相醛醇缩合反应的方法，得到混合的α，β-不饱和醛公开(公告)号：US08841489B2
公开(公告)日：2014-09-23
申请号：US13989455
申请日：2012-02-09
申请人： Dirk Bermann , Guido D. Frey , Norman Nowotny , Kurt Schalapski , Heinz Strutz
发明人： Dirk Bermann , Guido D. Frey , Norman Nowotny , Kurt Schalapski , Heinz Strutz
摘要： The invention relates to a continuous method for carrying out a multiphase aldol condensation reaction to obtain mixed α,β-unsaturated aldehydes by reacting a mixture of two aliphatic aldehydes having different numbers of carbon atoms, i.e. 2 to 5, in the molecule in a vertical tubular reactor in a concurrent flow in the presence of an aqueous solution of a basically reacting compound. In said method, the aldehyde mixture is dispersed in the aqueous phase in the form of drops, and the aqueous solution of the basically reacting compound flows through the tubular reactor as a continuous phase in laminar conditions.
摘要翻译： 本发明涉及一种用于进行多相醛醇缩合反应的连续方法，以通过使分子中具有不同数目的碳原子的两个脂族醛（即2至5）的混合物在分子中反应获得混合的α，β-不饱和醛 在基本上反应的化合物的水溶液存在下，并行流动的立管式反应器。 在所述方法中，醛混合物以液滴的形式分散在水相中，基本反应的化合物的水溶液在层流条件下作为连续相流动通过管式反应器。
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3.发明授权Method for obtaining ditrimethylolpropane and trimethylolpropane-enriched product streams from the side-streams in trimethylolpropane production 有权在三羟甲基丙烷生产中从侧流获得二羟甲基丙烷和三羟甲基丙烷富集产物流的方法公开(公告)号：US08987523B2
公开(公告)日：2015-03-24
申请号：US13810723
申请日：2011-07-28
CPC分类号： C07C29/74 , C07C29/10 , C07C29/80 , C07C29/90 , C07C41/34 , C07C41/42 , C07C41/44 , C07C31/22 , C07C43/132
摘要： The present invention relates to a process for obtaining ditrimethylolpropane and trimethylolpropane-enriched product streams from the high-boiling fractions and residues which are obtained in the distillative purification of trimethylolpropane, wherein an aqueous solution of these fractions and residues is catalytically hydrogenated in the presence of an acidic compound and, after removing solids, contacted both with basic and with acidic ion exchangers. A trimethylolpropane-enriched product stream can be distilled out of the aqueous eluate obtained, leaving ditrimethylolpropane as the distillation residue.
摘要翻译： 本发明涉及从三沸石馏分中获得的二羟甲基丙烷和三羟甲基丙烷富集产物流以及在三羟甲基丙烷的蒸馏提纯中获得的残留物的方法，其中这些级分和残基的水溶液在 在除去固体后，与碱性和酸性离子交换剂接触。 富含三羟甲基丙烷的产物流可以从获得的水溶液中蒸馏掉，留下二羟甲基丙烷作为蒸馏残余物。
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公开(公告)号：US20130131391A1
公开(公告)日：2013-05-23
申请号：US13810723
申请日：2011-07-28
CPC分类号： C07C29/74 , C07C29/10 , C07C29/80 , C07C29/90 , C07C41/34 , C07C41/42 , C07C41/44 , C07C31/22 , C07C43/132
摘要： The present invention relates to a process for obtaining ditrimethylolpropane and trimethylolpropane-enriched product streams from the high-boiling fractions and residues which are obtained in the distillative purification of trimethylolpropane, wherein an aqueous solution of these fractions and residues is catalytically hydrogenated in the presence of an acidic compound and, after removing solids, contacted both with basic and with acidic ion exchangers. A trimethylolpropane-enriched product stream can be distilled out of the aqueous eluate obtained, leaving ditrimethylolpropane as the distillation residue.
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公开(公告)号：US20130116467A1
公开(公告)日：2013-05-09
申请号：US13805693
申请日：2011-06-29
IPC分类号： C07C67/48
摘要： A process for aftertreatment of polyol esters prepared by reacting polyols of the general formula H—(—O—[—CR1R2—]m—)o—OH in which R1 and R2 are each independently hydrogen, an alkyl radical having 1 to 5 carbon atoms, or a hydroxyalkyl radical having 1 to 5 carbon atoms, m is an integer of 1 to 10, o is an integer of 2 to 15, with linear or branched aliphatic monocarboxylic acids having 3 to 20 carbon atoms in the presence of an adsorbent and in the presence of metal compounds selected from the group of titanium compounds, zirconium compounds, tin compounds, zinc compounds, iron compounds and aluminium compounds as a catalyst while removing the water formed and subsequently treating with steam, characterized in that the polyol ester obtained is aftertreated first with an oxidizing or reducing compound and immediately thereafter with steam at a temperature of 150 to 250° C. and over a period of 0.5 to 5 hours.
摘要翻译： 一种通过使通式为H - （ - O - [ - CR 1 R 2 - ] m - ）o-OH的多元醇反应制备的多元醇酯的方法，其中R 1和R 2各自独立地为氢，具有1至5个碳原子的烷基 原子或具有1至5个碳原子的羟烷基，m是1至10的整数，o是2至15的整数，在吸附剂存在下具有3至20个碳原子的直链或支链脂肪族单羧酸 在选择钛化合物，锆化合物，锡化合物，锌化合物，铁化合物和铝化合物作为催化剂的金属化合物的存在下，同时除去形成的水并随后用蒸汽处理，其特征在于获得的多元醇酯 首先用氧化或还原化合物进行后处理，然后立即用蒸汽在150至250℃的温度和0.5至5小时的时间内进行处理。
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公开(公告)号：US08796486B2
公开(公告)日：2014-08-05
申请号：US13805693
申请日：2011-06-29
摘要： A process for aftertreatment of polyol esters prepared by reacting polyols of the general formula H—(—O—[—CR1R2—]m—)o—OH in which R1 and R2 are each independently hydrogen, an alkyl radical having 1 to 5 carbon atoms, or a hydroxyalkyl radical having 1 to 5 carbon atoms, m is an integer of 1 to 10, o is an integer of 2 to 15, with linear or branched aliphatic monocarboxylic acids having 3 to 20 carbon atoms in the presence of an adsorbent and in the presence of metal compounds selected from the group of titanium compounds, zirconium compounds, tin compounds, zinc compounds, iron compounds and aluminum compounds as a catalyst while removing the water formed and subsequently treating with steam, characterized in that the polyol ester obtained is aftertreated first with an oxidizing or reducing compound and immediately thereafter with steam at a temperature of 150 to 250° C. and over a period of 0.5 to 5 hours.
摘要翻译： 一种通过使通式为H - （ - O - [ - CR 1 R 2 - ] m - ）o-OH的多元醇反应制备的多元醇酯的方法，其中R 1和R 2各自独立地为氢，具有1至5个碳原子的烷基 原子或具有1至5个碳原子的羟烷基，m是1至10的整数，o是2至15的整数，在吸附剂存在下具有3至20个碳原子的直链或支链脂肪族单羧酸 在选择钛化合物，锆化合物，锡化合物，锌化合物，铁化合物和铝化合物作为催化剂的金属化合物的存在下，同时除去形成的水并随后用蒸汽处理，其特征在于获得的多元醇酯 首先用氧化或还原化合物进行后处理，然后立即用蒸汽在150至250℃的温度和0.5至5小时的时间内进行处理。
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公开(公告)号：US20120190883A1
公开(公告)日：2012-07-26
申请号：US13499176
申请日：2010-09-17
申请人： Guido D. Frey , Heinz Strutz
发明人： Guido D. Frey , Heinz Strutz
IPC分类号： C07C67/08
摘要： The present invention relates to a process for preparing polyol esters by reacting polyols with linear or branched aliphatic monocarbocxylic acids having 3 to 20 carbon atoms, the reaction taking place in the presence of a Lewis acid comprising at least one element from groups 4 to 14 of the Periodic Table of the Elements as catalyst, and in the presence of an adsorbent, the reaction product being subjected subsequently to a steam treatment.
摘要翻译： 本发明涉及通过使多元醇与具有3-20个碳原子的直链或支链脂肪族单羧酸反应制备多元醇酯的方法，该反应在路易斯酸存在下进行，该路易斯酸包含至少一种来自第4〜14族的元素 元素周期表作为催化剂，并且在吸附剂存在下，反应产物随后进行蒸汽处理。
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公开(公告)号：US09006479B2
公开(公告)日：2015-04-14
申请号：US13499176
申请日：2010-09-17
申请人： Guido D. Frey , Heinz Strutz
发明人： Guido D. Frey , Heinz Strutz
IPC分类号： C07C67/08
摘要： The present invention relates to a process for preparing polyol esters by reacting polyols with linear or branched aliphatic monocarbocxylic acids having 3 to 20 carbon atoms, the reaction taking place in the presence of a Lewis acid comprising at least one element from groups 4 to 14 of the Periodic Table of the Elements as catalyst, and in the presence of an adsorbent, the reaction product being subjected subsequently to a steam treatment.
摘要翻译： 本发明涉及通过使多元醇与具有3-20个碳原子的直链或支链脂肪族单羧酸反应制备多元醇酯的方法，该反应在路易斯酸存在下进行，该路易斯酸包含至少一种来自第4〜14族的元素 元素周期表作为催化剂，并且在吸附剂存在下，反应产物随后进行蒸汽处理。
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公开(公告)号：US08399697B2
公开(公告)日：2013-03-19
申请号：US12924822
申请日：2010-10-06
申请人： Tonia Weber , Oliver Borgmeier , Guido D. Frey , Heinz Strutz
发明人： Tonia Weber , Oliver Borgmeier , Guido D. Frey , Heinz Strutz
摘要： The present invention relates to a process for preparing polyol esters by reacting polyols with linear or branched aliphatic monocarboxylic acids having 3 to 20 carbon atoms in the presence of an adsorbent and subsequent steam treatment in the course of workup of the crude ester.
摘要翻译： 本发明涉及通过使多元醇与吸附剂存在下具有3-20个碳原子的直链或支链脂族单羧酸反应制备多元醇酯的方法，随后在粗酯加工过程中进行蒸汽处理。
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公开(公告)号：US08524938B2
公开(公告)日：2013-09-03
申请号：US12924830
申请日：2010-10-06
申请人： Guido D. Frey , Thorsten Kreickmann , Heinz Strutz
发明人： Guido D. Frey , Thorsten Kreickmann , Heinz Strutz
IPC分类号： C07C69/003
摘要： The present invention relates to a process for lightening the color of polyol esters by reacting polyols with linear or branched aliphatic monocarboxylic acids having 3 to 20 carbon atoms, wherein the reaction product is worked up without using adsorbents and comprises a treatment with ozone or ozone-containing gases and an immediately subsequent steam treatment with subsequent drying.
摘要翻译： 本发明涉及通过使多元醇与碳原子数为3〜20的直链或支链脂族一元羧酸反应来减轻多元醇酯的颜色的方法，其中反应产物在不使用吸附剂的情况下进行处理，并且包括用臭氧或臭氧 - 随后进行干燥处理。
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