Hydrocracking catalyst and hydrocracking process
    1.
    发明授权
    Hydrocracking catalyst and hydrocracking process 失效
    加氢裂化催化剂和加氢裂化工艺

    公开(公告)号:US4897178A

    公开(公告)日:1990-01-30

    申请号:US143473

    申请日:1988-01-13

    IPC分类号: B01J29/06 C10G47/16

    CPC分类号: B01J29/061 C10G47/16

    摘要: A process for hydrocracking a crude oil feed, a hydrocracking catalyst employed therein, and a process for the preparation of this catalyst are disclosed. The hydrocracking catalyst comprises a zeolitic aluminosilicate which has an SiO.sub.2 /Al.sub.2 O.sub.3 molar ratio of at least 6 and which has been treated by (i) thermal treatment at an effective temperature and for an effective time in the presence of steam, followed by (ii) ion-exchange with a solution containing ammonium ion; and (2) an effective amount of a hydrogenation component. In a preferred embodiment, the starting crystalline zeolitic aluminosilicate is a Y-type zeolite having an SiO.sub.2 /Al.sub.2 O.sub.3 molar ratio of at least about 9 and a unit cell dimension (a.sub.o) of less than about 24.55 .ANG., and the steam treatment is carried out for a period sufficient to cause a decrease of not more than about 0.1 .ANG. in the unit cell dimension, thereby producing a Y-type zeolite product having a SiO.sub.2 /Al.sub.2 O.sub.3 molar ratio of at least about 9 and a unit cell dimension of less than about 24.45 .ANG..

    摘要翻译: 公开了一种用于加氢裂化原油进料的方法,其中使用的加氢裂化催化剂和制备该催化剂的方法。 加氢裂化催化剂包括SiO 2 / Al 2 O 3摩尔比至少为6的沸石硅铝酸盐,其已经通过(i)在有效温度下热处理并在蒸汽存在下持续有效时间进行处理,随后是(ii) 与含有铵离子的溶液进行离子交换; 和(2)有效量的氢化组分。 在优选的实施方案中,起始结晶沸石硅铝酸盐是具有至少约9的SiO 2 / Al 2 O 3摩尔比和小于约24.55埃的晶胞尺寸(ao)的Y型沸石,并且进行蒸汽处理 使其在单元电极尺寸内足够降低不大于约0.1Ag的范围内,由此生产SiO 2 / Al 2 O 3摩尔比为至少约9的Y型沸石产物,并且晶胞尺寸小于约 24.45 ANGSTROM。

    Catalytic cracking catalysts and process
    5.
    发明授权
    Catalytic cracking catalysts and process 失效
    催化裂化催化剂及工艺

    公开(公告)号:US4687754A

    公开(公告)日:1987-08-18

    申请号:US657417

    申请日:1984-10-03

    IPC分类号: B01J29/08 C10G11/05 B01J29/06

    CPC分类号: C10G11/05 B01J29/084

    摘要: Catalytic cracking catalysts, the process of their preparation and the process of their use. The cracking catalyst comprises a zeolite having a mole ratio of oxides in the dehydrated state of (0.85-1.1) M.sub.2/n O:Al.sub.2 O.sub.3 :xSiO.sub.2 wherein "M" is a cation having a valence of "n", "x" has a value greater than 6.0, has a x-ray powder diffraction pattern having at least the d-spacings of Table A, has extraneous silicon atoms in the crystal lattice in the form of framework SiO.sub.4 tetrahedra and has been thermally treated and/or cation exchanged with a multivalent cation. The catalyst of the instant invention are unique in the fact that the zeolitic aluminosilicate has less than 1.2 weight percent Na.sub.2 O and such is achieved without the requirement of a pre-calcination step.

    摘要翻译: 催化裂化催化剂,其制备过程及其使用过程。 裂化催化剂包括具有(0.85-1.1)M2 / nO:Al2O3:xSiO2脱水状态的氧化物摩尔比的沸石,其中“M”为化合价“n”的阳离子,“x”具有值 大于6.0,具有至少具有表A的d间距的x射线粉末衍射图,在框架SiO 4四面体形式的晶格中具有外来的硅原子,并且已经被热处理和/或阳离子交换 多价阳离子 本发明的催化剂在沸石铝硅酸盐具有小于1.2重量%的Na 2 O的情况下是独特的,并且不需要预煅烧步骤即可实现。

    Catalytic cracking process
    8.
    发明授权
    Catalytic cracking process 失效
    催化裂化过程

    公开(公告)号:US4781815A

    公开(公告)日:1988-11-01

    申请号:US42801

    申请日:1987-04-27

    CPC分类号: C10G11/05 B01J29/084

    摘要: Catalytic cracking catalysts, the process of their preparation and the process of their use. The cracking catalyst comprises a zeolite having a mole ratio of oxides in the dehydrated state of (0.85-1.1) M.sub.2/n O:Al.sub.2 O.sub.3 :xSiO.sub.2 wherein "M" is a cation having a valence of "n", "x" has a value greater than 6.0, has a x-ray powder diffraction pattern having at least the d-spacings of Table A, has extraneous silicon atoms in the crystal lattice in the form of framework SiO.sub.4 tetrahedra and has been thermally treated and/or cation exchanged with a multivalent cation. The catalyst of the instant invention are unique in the fact that the zeolitic aluminosilicate has less than 1.2 weight percent Na.sub.2 O and such is achieved without the requirement of a pre-calcination step.

    摘要翻译: 催化裂化催化剂,其制备过程及其使用过程。 裂化催化剂包括具有(0.85-1.1)M2 / nO:Al2O3:xSiO2脱水状态的氧化物摩尔比的沸石,其中“M”为化合价“n”的阳离子,“x”具有值 大于6.0,具有至少具有表A的d间距的x射线粉末衍射图,在框架SiO 4四面体形式的晶格中具有外来的硅原子,并且已经被热处理和/或阳离子交换 多价阳离子 本发明的催化剂在沸石铝硅酸盐具有小于1.2重量%的Na 2 O的情况下是独特的,并且不需要预煅烧步骤即可实现。