摘要:
A process for hydrocracking a crude oil feed, a hydrocracking catalyst employed therein, and a process for the preparation of this catalyst are disclosed. The hydrocracking catalyst comprises a zeolitic aluminosilicate which has an SiO.sub.2 /Al.sub.2 O.sub.3 molar ratio of at least 6 and which has been treated by (i) thermal treatment at an effective temperature and for an effective time in the presence of steam, followed by (ii) ion-exchange with a solution containing ammonium ion; and (2) an effective amount of a hydrogenation component. In a preferred embodiment, the starting crystalline zeolitic aluminosilicate is a Y-type zeolite having an SiO.sub.2 /Al.sub.2 O.sub.3 molar ratio of at least about 9 and a unit cell dimension (a.sub.o) of less than about 24.55 .ANG., and the steam treatment is carried out for a period sufficient to cause a decrease of not more than about 0.1 .ANG. in the unit cell dimension, thereby producing a Y-type zeolite product having a SiO.sub.2 /Al.sub.2 O.sub.3 molar ratio of at least about 9 and a unit cell dimension of less than about 24.45 .ANG..
摘要翻译:公开了一种用于加氢裂化原油进料的方法,其中使用的加氢裂化催化剂和制备该催化剂的方法。 加氢裂化催化剂包括SiO 2 / Al 2 O 3摩尔比至少为6的沸石硅铝酸盐,其已经通过(i)在有效温度下热处理并在蒸汽存在下持续有效时间进行处理,随后是(ii) 与含有铵离子的溶液进行离子交换; 和(2)有效量的氢化组分。 在优选的实施方案中,起始结晶沸石硅铝酸盐是具有至少约9的SiO 2 / Al 2 O 3摩尔比和小于约24.55埃的晶胞尺寸(ao)的Y型沸石,并且进行蒸汽处理 使其在单元电极尺寸内足够降低不大于约0.1Ag的范围内,由此生产SiO 2 / Al 2 O 3摩尔比为至少约9的Y型沸石产物,并且晶胞尺寸小于约 24.45 ANGSTROM。
摘要:
Hydrocracking processes are disclosed using novel catalysts comprising medium and large pore non-zeolitic molecular sieves selected from novel compositions such as the silicoaluminophosphates of U.S. Pat. No. 4,440,871, preferably in combination with traditional hydrocracking catalysts such as zeolitic aluminosilicates. The products of the instant processes are characterized by higher isoparaffin to n-paraffin ratios.
摘要:
Process for hydrocracking a crude oil feed, hydrocracking catalyst employed therein and the process for its preparation. The instant invention employs new aluminosilicate zeolite catalysts derived from a new zeolites denominated "LZ-210" which provide hydrocracking catalysts which demonstrate improved activity in first and/or second stage operation.
摘要:
Catalytic cracking catalysts, the process of their preparation and the process of their use. The cracking catalyst comprises a zeolite having a mole ratio of oxides in the dehydrated state of (0.85-1.1) M.sub.2/n O:Al.sub.2 O.sub.3 :xSiO.sub.2 wherein "M" is a cation having a valence of "n", "x" has a value greater than 6.0, has a x-ray powder diffraction pattern having at least the d-spacings of Table A, has extraneous silicon atoms in the crystal lattice in the form of framework SiO.sub.4 tetrahedra and has been thermally treated and/or cation exchanged with a multivalent cation. The catalyst of the instant invention are unique in the fact that the zeolitic aluminosilicate has less than 1.2 weight percent Na.sub.2 O and such is achieved without the requirement of a pre-calcination step.
摘要:
Dewaxing processes for hydrocarbon feedstocks are disclosed using novel catalysts comprising specific silicoaluminophosphates of U.S. Pat. No. 4,440,871. The products of the instant dewaxing processes are characterized by lower pour points than the hydrocarbon feedstock.
摘要:
Hydrocracking processes are disclosed using novel catalysts comprising non-zeolitic molecular sieves such as the silicoaluminophosphates of U.S. Pat. No. 4,440,871. The products of the instant processes are characterized by higher i-paraffin to n-paraffin ratios.
摘要:
Catalytic cracking catalysts, the process of their preparation and the process of their use. The cracking catalyst comprises a zeolite having a mole ratio of oxides in the dehydrated state of (0.85-1.1) M.sub.2/n O:Al.sub.2 O.sub.3 :xSiO.sub.2 wherein "M" is a cation having a valence of "n", "x" has a value greater than 6.0, has a x-ray powder diffraction pattern having at least the d-spacings of Table A, has extraneous silicon atoms in the crystal lattice in the form of framework SiO.sub.4 tetrahedra and has been thermally treated and/or cation exchanged with a multivalent cation. The catalyst of the instant invention are unique in the fact that the zeolitic aluminosilicate has less than 1.2 weight percent Na.sub.2 O and such is achieved without the requirement of a pre-calcination step.
摘要:
Dewaxing processes for hydrocarbon feedstocks are disclosed using novel catalysts comprising non-zeolitic molecular sieves, such as the silicoaluminophosphates of U.S. Pat. No. 4,440,871. The products of the instant dewaxing processes are characterized by lower pour points than the hydrocarbon feedstock.
摘要:
Dewaxing processes for hydrocarbon feedstocks are disclosed using novel catalysts comprising non-zeolitic molecular sieves, such as the silicoaluminophosphates of U.S. Pat. No. 4,440,871. The products of the instant dewaxing processes are characterized by lower pour points than the hydrocarbon feedstock.