公开(公告)号：USRE41897E1

公开(公告)日：2010-10-26

申请号：US10761101

申请日：2004-01-20

申请人： Donald R. Loveday ,  David H. McConville ,  John F. Szul ,  Kersten Anne Terry ,  Simon Mawson ,  Tae Hoon Kwalk ,  Frederick J. Karol ,  David James Schreck

发明人： Donald R. Loveday ,  David H. McConville ,  John F. Szul ,  Kersten Anne Terry ,  Simon Mawson ,  Tae Hoon Kwalk ,  Frederick J. Karol ,  David James Schreck

IPC分类号： C08F4/44 ,  C08F4/06 ,  C08F10/14

CPC分类号： C08F10/02 ,  C08F4/659 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  C08F10/00 ,  C08F210/16 ,  C08F2420/04 ,  C08L23/0815 ,  C08L23/16 ,  C08L2205/02 ,  C08L2314/06 ,  Y10S526/943 ,  C08F2/00 ,  C08F4/025 ,  C08L2666/04 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/04 ,  C08F2500/02 ,  C08F2500/01 ,  C08F2500/26 ,  C08F2500/05 ,  C08F4/64148 ,  C08F4/65904 ,  C08F4/64158 ,  C08F4/64144 ,  C08F4/64151

摘要： Catalyst compositions and methods, useful in polymerization processes, utilizing at least two metal compounds are disclosed. At least one of the metal compounds is a Group 15 containing metal compound and the other metal compound is preferably a bulky ligand metallocene-type catalyst. The invention also discloses a new polyolefin, generally polyethylene, particularly a multimodal polymer and more specifically, a bimodal polymer, and its use in various end-use applications such as film, molding and pipe.

摘要翻译： 公开了使用至少两种金属化合物的聚合方法中的催化剂组合物和方法。 至少一种金属化合物是含有第15族金属化合物，另一种金属化合物优选为大体积配体金属茂型催化剂。 本发明还公开了一种新的聚烯烃，一般为聚乙烯，特别是多峰聚合物，更具体地说是双峰聚合物，以及其在各种最终用途应用如薄膜，模塑和管材中的应用。

公开(公告)号：US06897273B2

公开(公告)日：2005-05-24

申请号：US09729557

申请日：2000-12-04

申请人： John F. Szul ,  Tae Hoon Kwalk ,  David James Schreck ,  Simon Mawson ,  Matthew G. McKee ,  Kersten Anne Terry ,  Mark G. Goode ,  Gregory T. Whiteker ,  Eric A. Lucas

发明人： John F. Szul ,  Tae Hoon Kwalk ,  David James Schreck ,  Simon Mawson ,  Matthew G. McKee ,  Kersten Anne Terry ,  Mark G. Goode ,  Gregory T. Whiteker ,  Eric A. Lucas

IPC分类号： C08J5/18 ,  C08F4/642 ,  C08F4/646 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F10/02 ,  C08F210/16 ,  C08L23/08 ,  C08F4/44 ,  B01J31/38

CPC分类号： C08F10/02 ,  C08F4/659 ,  C08F4/65912 ,  C08F4/65925 ,  C08F210/16 ,  C08L23/0815 ,  C08L2314/06 ,  Y10S526/943 ,  C08F2/34 ,  C08F4/65916 ,  C08F4/65904 ,  C08L2666/04 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/26

摘要： This invention relates to a process to polymerize olefin(s) comprising combining a solution, slurry or solid comprising one or more bulky ligand metallocene catalyst compounds, an optional support, and or one or more activator(s) with a solution comprising one or more phenoxide catalyst compounds, and thereafter, introducing one or more olefin(s) and the combination into a polymerization reactor. This invention also relates to a polymer of ethylene wherein the polymer has a density of 0.910 to 0.930 g/cc, a melt index of 0.3 to 2.0 dg/min, and a 15 to 35 μm thick film of the polymer has a 45° gloss of 60 or more, a haze of 7% or less, and a dart impact of 600 g or more.

摘要翻译： 本发明涉及聚合烯烃的方法，包括将包含一种或多种庞大配体茂金属催化剂化合物，任选的载体和/或一种或多种活化剂的溶液，浆料或固体与包含一种或多种 酚氧化物催化剂化合物，然后将一种或多种烯烃和组合引入聚合反应器中。 本发明还涉及一种乙烯聚合物，其中聚合物的密度为0.910至0.930g / cc，熔体指数为0.3至2.0dg / min，而15至35μm厚的聚合物膜具有45°的光泽度 为60以上，雾度为7％以下，落镖冲击为600g以上。

公开(公告)号：US06608149B2

公开(公告)日：2003-08-19

申请号：US09729453

申请日：2000-12-04

申请人： Simon Mawson ,  Sun-Chueh Kao ,  Tae Hoon Kwalk ,  Timothy Roger Lynn ,  David H. McConville ,  Matthew Gary McKee ,  John Francis Szul ,  Kersten Anne Terry ,  Timothy T. Wenzel ,  Mark Gregory Goode ,  John Henry Oskam ,  Robert J. Jorgensen ,  Robert Harold Vogel

发明人： Simon Mawson ,  Sun-Chueh Kao ,  Tae Hoon Kwalk ,  Timothy Roger Lynn ,  David H. McConville ,  Matthew Gary McKee ,  John Francis Szul ,  Kersten Anne Terry ,  Timothy T. Wenzel ,  Mark Gregory Goode ,  John Henry Oskam ,  Robert J. Jorgensen ,  Robert Harold Vogel

IPC分类号： C08F234

CPC分类号： C08F10/00 ,  C08F4/659 ,  C08F4/65912 ,  C08F4/65925 ,  C08F210/16 ,  Y10S526/905 ,  Y10S526/943 ,  C08F4/65904 ,  C08F4/65916 ,  C08F2/00 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/24 ,  C08F2500/18 ,  C08F2500/26

摘要： The invention provides for polymerization catalyst compositions, and for methods for introducing the catalyst compositions into a polymerization reactor. More particularly, the method combines a catalyst component containing slurry and a catalyst component containing solution to form the completed catalyst composition for introduction into the polymerization reactor. The invention is also directed to methods of preparing the catalyst component slurry, the catalyst component solution and the catalyst compositions, to methods of controlling the properties of polymer products utilizing the catalyst compositions, and to polymers produced therefrom.

公开(公告)号：US06956094B2

公开(公告)日：2005-10-18

申请号：US10772823

申请日：2004-02-05

申请人： Simon Mawson ,  Sun-Chueh Kao ,  Tae Hoon Kwalk ,  Timothy Roger Lynn ,  David H. McConville ,  Matthew Gary McKee ,  John Francis Szul ,  Kersten Anne Terry ,  Timothy T. Wenzel ,  Mark Gregory Goode ,  John Henry Oskam ,  Robert J. Jorgensen ,  Robert Harold Vogel

发明人： Simon Mawson ,  Sun-Chueh Kao ,  Tae Hoon Kwalk ,  Timothy Roger Lynn ,  David H. McConville ,  Matthew Gary McKee ,  John Francis Szul ,  Kersten Anne Terry ,  Timothy T. Wenzel ,  Mark Gregory Goode ,  John Henry Oskam ,  Robert J. Jorgensen ,  Robert Harold Vogel

IPC分类号： C08F2/00 ,  C08F2/34 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F210/16 ,  C08F12/06

CPC分类号： C08F10/00 ,  C08F4/659 ,  C08F4/65912 ,  C08F4/65925 ,  C08F210/16 ,  Y10S526/905 ,  Y10S526/943 ,  C08F4/65904 ,  C08F4/65916 ,  C08F2/00 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/24 ,  C08F2500/18 ,  C08F2500/26

摘要： The invention provides for polymerization catalyst compositions, and for methods for introducing the catalyst compositions into a polymerization reactor. More particularly, the method combines a catalyst component containing slurry and a catalyst component containing solution to form the completed catalyst composition for introduction into the polymerization reactor. The invention is also directed to methods of preparing the catalyst component slurry, the catalyst component solution and the catalyst compositions, to methods of controlling the properties of polymer products utilizing the catalyst compositions, and to polymers produced therefrom.

摘要翻译： 本发明提供聚合催化剂组合物以及用于将催化剂组合物引入聚合反应器的方法。 更具体地说，该方法结合了含催化剂组分的浆料和含催化剂组分的溶液以形成用于引入聚合反应器的完成的催化剂组合物。 本发明还涉及制备催化剂组分浆料，催化剂组分溶液和催化剂组合物的方法，以及使用该催化剂组合物控制聚合物产品性能的方法以及由其制备的聚合物。

公开(公告)号：US06605675B2

公开(公告)日：2003-08-12

申请号：US09729550

申请日：2000-12-04

申请人： Simon Mawson ,  Sun-Chueh Kao ,  Tae Hoon Kwalk ,  Timothy Roger Lynn ,  David H. McConville ,  Matthew Gary McKee ,  John Francis Szul ,  Kersten Anne Terry ,  Timothy T. Wenzel ,  Mark Gregory Goode ,  John Henry Oskam ,  Robert J. Jorgensen ,  Robert Harold Vogel

发明人： Simon Mawson ,  Sun-Chueh Kao ,  Tae Hoon Kwalk ,  Timothy Roger Lynn ,  David H. McConville ,  Matthew Gary McKee ,  John Francis Szul ,  Kersten Anne Terry ,  Timothy T. Wenzel ,  Mark Gregory Goode ,  John Henry Oskam ,  Robert J. Jorgensen ,  Robert Harold Vogel

IPC分类号： C08F444

CPC分类号： B01J8/1827 ,  B01J4/002 ,  B01J2219/00108 ,  C08F4/659 ,  C08F4/65912 ,  C08F4/65925 ,  C08F10/00 ,  C08F210/16 ,  Y10S526/943 ,  C08F4/65916 ,  C08F4/65904 ,  C08F2/00 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/24 ,  C08F2500/18 ,  C08F2500/26

摘要： The invention provides for polymerization catalyst compositions, and for methods for introducing the catalyst compositions into a polymerization reactor. More particularly, the method combines a catalyst component containing slurry and a catalyst component containing solution to form the completed catalyst composition for introduction into the polymerization reactor. The invention is also directed to methods of preparing the catalyst component slurry, the catalyst component solution and the catalyst compositions, to methods of controlling the properties of polymer products utilizing the catalyst compositions, and to polymers produced therefrom.

公开(公告)号：US06956089B2

公开(公告)日：2005-10-18

申请号：US10373121

申请日：2003-02-24

申请人： Simon Mawson ,  Sun-Chueh Kao ,  Tae Hoon Kwalk ,  Timothy Roger Lynn ,  David H. McConville ,  Matthew Gary McKee ,  John Francis Szul ,  Kersten Anne Terry ,  Timothy T. Wenzel ,  Mark Gregory Goode ,  John Henry Oskam ,  Robert J. Jorgensen ,  Robert Harold Vogel

发明人： Simon Mawson ,  Sun-Chueh Kao ,  Tae Hoon Kwalk ,  Timothy Roger Lynn ,  David H. McConville ,  Matthew Gary McKee ,  John Francis Szul ,  Kersten Anne Terry ,  Timothy T. Wenzel ,  Mark Gregory Goode ,  John Henry Oskam ,  Robert J. Jorgensen ,  Robert Harold Vogel

IPC分类号： C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F210/16 ,  C08F4/64 ,  B01J31/38 ,  C08F210/14

CPC分类号： B01J8/1827 ,  B01J4/002 ,  B01J2219/00108 ,  C08F4/659 ,  C08F4/65912 ,  C08F4/65925 ,  C08F10/00 ,  C08F210/16 ,  Y10S526/943 ,  C08F4/65916 ,  C08F4/65904 ,  C08F2/00 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/24 ,  C08F2500/18 ,  C08F2500/26

摘要： The invention provides for polymerization catalyst compositions, and for methods for introducing the catalyst compositions into a polymerization reactor. More particularly, the method combines a catalyst component containing slurry and a catalyst component containing solution to form the completed catalyst composition for introduction into the polymerization reactor. The invention is also directed to methods of preparing the catalyst component slurry, the catalyst component solution and the catalyst compositions, to methods of controlling the properties of polymer products utilizing the catalyst compositions, and to polymers produced therefrom.

公开(公告)号：US06825287B2

公开(公告)日：2004-11-30

申请号：US10772921

申请日：2004-02-05

申请人： Simon Mawson ,  Sun-Chueh Kao ,  Tae Hoon Kwalk ,  Timothy Roger Lynn ,  David H. McConville ,  Matthew Gary McKee ,  John Francis Szul ,  Kersten Anne Terry ,  Timothy T. Wenzel ,  Mark Gregory Goode ,  John Henry Oskam ,  Robert J. Jorgensen ,  Robert Harold Vogel

发明人： Simon Mawson ,  Sun-Chueh Kao ,  Tae Hoon Kwalk ,  Timothy Roger Lynn ,  David H. McConville ,  Matthew Gary McKee ,  John Francis Szul ,  Kersten Anne Terry ,  Timothy T. Wenzel ,  Mark Gregory Goode ,  John Henry Oskam ,  Robert J. Jorgensen ,  Robert Harold Vogel

IPC分类号： C08F234

CPC分类号： C08F10/00 ,  C08F4/659 ,  C08F4/65912 ,  C08F4/65925 ,  C08F210/16 ,  Y10S526/905 ,  Y10S526/943 ,  C08F4/65904 ,  C08F4/65916 ,  C08F2/00 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/24 ,  C08F2500/18 ,  C08F2500/26

摘要： The invention provides for polymerization catalyst compositions, and for methods for introducing the catalyst compositions into a polymerization reactor. More particularly, the method combines a catalyst component containing slurry and a catalyst component containing solution to form the completed catalyst composition for introduction into the polymerization reactor. The invention is also directed to methods of preparing the catalyst component slurry, the catalyst component solution and the catalyst compositions, to methods of controlling the properties of polymer products utilizing the catalyst compositions, and to polymers produced therefrom.

摘要翻译： 本发明提供聚合催化剂组合物以及用于将催化剂组合物引入聚合反应器的方法。 更具体地说，该方法结合了含催化剂组分的浆料和含催化剂组分的溶液以形成用于引入聚合反应器的完成的催化剂组合物。 本发明还涉及制备催化剂组分浆料，催化剂组分溶液和催化剂组合物的方法，以及使用该催化剂组合物控制聚合物产品性能的方法以及由其制备的聚合物。

公开(公告)号：US06689847B2

公开(公告)日：2004-02-10

申请号：US09995043

申请日：2001-11-27

申请人： Simon Mawson ,  Sun-Chueh Kao ,  Tae Hoon Kwalk ,  Timothy Roger Lynn ,  David H. McConville ,  Matthew Gary McKee ,  John Francis Szul ,  Kersten Anne Terry ,  Timothy T. Wenzel ,  Mark Gregory Goode ,  John Henry Oskam ,  Robert J. Jorgensen ,  Robert Harold Vogel

发明人： Simon Mawson ,  Sun-Chueh Kao ,  Tae Hoon Kwalk ,  Timothy Roger Lynn ,  David H. McConville ,  Matthew Gary McKee ,  John Francis Szul ,  Kersten Anne Terry ,  Timothy T. Wenzel ,  Mark Gregory Goode ,  John Henry Oskam ,  Robert J. Jorgensen ,  Robert Harold Vogel

IPC分类号： C08F464

CPC分类号： C08F10/00 ,  C08F4/659 ,  C08F4/65912 ,  C08F4/65925 ,  C08F210/16 ,  Y10S526/903 ,  Y10S526/907 ,  Y10S526/943 ,  C08F4/65916 ,  C08F4/65904 ,  C08F2/00 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/24 ,  C08F2500/18 ,  C08F2500/26

摘要： The invention provides for polymerization catalyst compositions, and for methods for introducing the catalyst compositions into a polymerization reactor. More particularly, the method combines a catalyst component containing slurry and a catalyst component containing solution to form the completed catalyst composition for introduction into the polymerization reactor. The invention is also directed to methods of preparing the catalyst component slurry, the catalyst component solution and the catalyst compositions, to methods of controlling the properties of polymer products utilizing the catalyst compositions, and to polymers produced therefrom.

公开(公告)号：US06846886B2

公开(公告)日：2005-01-25

申请号：US10373259

申请日：2003-02-24

申请人： Simon Mawson ,  Sun-Chueh Kao ,  Tae Hoon Kwalk ,  Timothy Roger Lynn ,  David H. McConville ,  Matthew Gary McKee ,  John Francis Szul ,  Kersten Anne Terry ,  Timothy T. Wenzel ,  Mark Gregory Goode ,  John Henry Oskam ,  Robert J. Jorgensen ,  Robert Harold Vogel

发明人： Simon Mawson ,  Sun-Chueh Kao ,  Tae Hoon Kwalk ,  Timothy Roger Lynn ,  David H. McConville ,  Matthew Gary McKee ,  John Francis Szul ,  Kersten Anne Terry ,  Timothy T. Wenzel ,  Mark Gregory Goode ,  John Henry Oskam ,  Robert J. Jorgensen ,  Robert Harold Vogel

IPC分类号： C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F210/16 ,  C08F4/44 ,  C08F4/70

CPC分类号： B01J8/1827 ,  B01J4/002 ,  B01J2219/00108 ,  C08F4/659 ,  C08F4/65912 ,  C08F4/65925 ,  C08F10/00 ,  C08F210/16 ,  Y10S526/943 ,  C08F4/65916 ,  C08F4/65904 ,  C08F2/00 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/24 ,  C08F2500/18 ,  C08F2500/26

摘要： The invention provides for polymerization catalyst compositions, and for methods for introducing the catalyst compositions into a polymerization reactor. More particularly, the method combines a catalyst component containing slurry and a catalyst component containing solution to form the completed catalyst composition for introduction into the polymerization reactor. The invention is also directed to methods of preparing the catalyst component slurry, the catalyst component solution and the catalyst compositions, to methods of controlling the properties of polymer products utilizing the catalyst compositions, and to polymers produced therefrom.

摘要翻译： 本发明提供聚合催化剂组合物以及用于将催化剂组合物引入聚合反应器的方法。 更具体地说，该方法结合了含催化剂组分的浆料和含催化剂组分的溶液以形成用于引入聚合反应器的完成的催化剂组合物。 本发明还涉及制备催化剂组分浆料，催化剂组分溶液和催化剂组合物的方法，以及使用该催化剂组合物控制聚合物产品性能的方法以及由其制备的聚合物。

公开(公告)号：US07504055B2

公开(公告)日：2009-03-17

申请号：US11981098

申请日：2007-10-31

申请人： Tae Hoon Kwalk

发明人： Tae Hoon Kwalk

IPC分类号： B29C47/00 ,  B29C49/00 ,  B29C49/04 ,  C08L23/00 ,  C08L23/04

CPC分类号： C08J5/18 ,  C08J2323/02 ,  C08L23/02 ,  C08L23/06 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2207/062 ,  C08L2666/06

摘要： Disclosed herein are various processes, including a process for producing a film, comprising (including) forming a film from a blended polyolefin composition at a line speed of at least 170 feet per minute, wherein the blended polyolefin composition comprises: (a) a bimodal polyethylene component that includes a high molecular weight polyethylene component having a high average molecular weight (MWHMW) and a low molecular weight polyethylene component having a low average molecular weight (MWLMW), wherein the ratio of the high average molecular weight to the low average molecular weight (MWHMW:MWLMW) is 20 or more wherein the high and low molecular weight polyethylene components of the bimodal polyethylene component are formed in a single reactor; and (b) a unimodal polyethylene component that occupies more than 15 wt % of the composition.

摘要翻译： 本文公开了各种方法，包括制造膜的方法，其包括（包括）以至少170英尺/分钟的线速度从混合的聚烯烃组合物形成膜，其中所述共混聚烯烃组合物包含：（a）双峰 包括具有高平均分子量（MWHMW）的高分子量聚乙烯组分和低平均分子量（MWLMW）的低分子量聚乙烯组分的聚乙烯组分，其中高平均分子量与低平均分子量 重量（MWHMW：MWLMW）为20以上，其中双峰聚乙烯组分的高分子量和低分子量聚乙烯组分在单个反应器中形成; 和（b）占据组合物重量的15重量％以上的单峰聚乙烯成分。