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公开(公告)号:US06608149B2
公开(公告)日:2003-08-19
申请号:US09729453
申请日:2000-12-04
申请人: Simon Mawson , Sun-Chueh Kao , Tae Hoon Kwalk , Timothy Roger Lynn , David H. McConville , Matthew Gary McKee , John Francis Szul , Kersten Anne Terry , Timothy T. Wenzel , Mark Gregory Goode , John Henry Oskam , Robert J. Jorgensen , Robert Harold Vogel
发明人: Simon Mawson , Sun-Chueh Kao , Tae Hoon Kwalk , Timothy Roger Lynn , David H. McConville , Matthew Gary McKee , John Francis Szul , Kersten Anne Terry , Timothy T. Wenzel , Mark Gregory Goode , John Henry Oskam , Robert J. Jorgensen , Robert Harold Vogel
IPC分类号: C08F234
CPC分类号: C08F10/00 , C08F4/659 , C08F4/65912 , C08F4/65925 , C08F210/16 , Y10S526/905 , Y10S526/943 , C08F4/65904 , C08F4/65916 , C08F2/00 , C08F210/14 , C08F2500/12 , C08F2500/24 , C08F2500/18 , C08F2500/26
摘要: The invention provides for polymerization catalyst compositions, and for methods for introducing the catalyst compositions into a polymerization reactor. More particularly, the method combines a catalyst component containing slurry and a catalyst component containing solution to form the completed catalyst composition for introduction into the polymerization reactor. The invention is also directed to methods of preparing the catalyst component slurry, the catalyst component solution and the catalyst compositions, to methods of controlling the properties of polymer products utilizing the catalyst compositions, and to polymers produced therefrom.
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公开(公告)号:US06956094B2
公开(公告)日:2005-10-18
申请号:US10772823
申请日:2004-02-05
申请人: Simon Mawson , Sun-Chueh Kao , Tae Hoon Kwalk , Timothy Roger Lynn , David H. McConville , Matthew Gary McKee , John Francis Szul , Kersten Anne Terry , Timothy T. Wenzel , Mark Gregory Goode , John Henry Oskam , Robert J. Jorgensen , Robert Harold Vogel
发明人: Simon Mawson , Sun-Chueh Kao , Tae Hoon Kwalk , Timothy Roger Lynn , David H. McConville , Matthew Gary McKee , John Francis Szul , Kersten Anne Terry , Timothy T. Wenzel , Mark Gregory Goode , John Henry Oskam , Robert J. Jorgensen , Robert Harold Vogel
IPC分类号: C08F2/00 , C08F2/34 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F210/16 , C08F12/06
CPC分类号: C08F10/00 , C08F4/659 , C08F4/65912 , C08F4/65925 , C08F210/16 , Y10S526/905 , Y10S526/943 , C08F4/65904 , C08F4/65916 , C08F2/00 , C08F210/14 , C08F2500/12 , C08F2500/24 , C08F2500/18 , C08F2500/26
摘要: The invention provides for polymerization catalyst compositions, and for methods for introducing the catalyst compositions into a polymerization reactor. More particularly, the method combines a catalyst component containing slurry and a catalyst component containing solution to form the completed catalyst composition for introduction into the polymerization reactor. The invention is also directed to methods of preparing the catalyst component slurry, the catalyst component solution and the catalyst compositions, to methods of controlling the properties of polymer products utilizing the catalyst compositions, and to polymers produced therefrom.
摘要翻译: 本发明提供聚合催化剂组合物以及用于将催化剂组合物引入聚合反应器的方法。 更具体地说,该方法结合了含催化剂组分的浆料和含催化剂组分的溶液以形成用于引入聚合反应器的完成的催化剂组合物。 本发明还涉及制备催化剂组分浆料,催化剂组分溶液和催化剂组合物的方法,以及使用该催化剂组合物控制聚合物产品性能的方法以及由其制备的聚合物。
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公开(公告)号:US06605675B2
公开(公告)日:2003-08-12
申请号:US09729550
申请日:2000-12-04
申请人: Simon Mawson , Sun-Chueh Kao , Tae Hoon Kwalk , Timothy Roger Lynn , David H. McConville , Matthew Gary McKee , John Francis Szul , Kersten Anne Terry , Timothy T. Wenzel , Mark Gregory Goode , John Henry Oskam , Robert J. Jorgensen , Robert Harold Vogel
发明人: Simon Mawson , Sun-Chueh Kao , Tae Hoon Kwalk , Timothy Roger Lynn , David H. McConville , Matthew Gary McKee , John Francis Szul , Kersten Anne Terry , Timothy T. Wenzel , Mark Gregory Goode , John Henry Oskam , Robert J. Jorgensen , Robert Harold Vogel
IPC分类号: C08F444
CPC分类号: B01J8/1827 , B01J4/002 , B01J2219/00108 , C08F4/659 , C08F4/65912 , C08F4/65925 , C08F10/00 , C08F210/16 , Y10S526/943 , C08F4/65916 , C08F4/65904 , C08F2/00 , C08F210/14 , C08F2500/12 , C08F2500/24 , C08F2500/18 , C08F2500/26
摘要: The invention provides for polymerization catalyst compositions, and for methods for introducing the catalyst compositions into a polymerization reactor. More particularly, the method combines a catalyst component containing slurry and a catalyst component containing solution to form the completed catalyst composition for introduction into the polymerization reactor. The invention is also directed to methods of preparing the catalyst component slurry, the catalyst component solution and the catalyst compositions, to methods of controlling the properties of polymer products utilizing the catalyst compositions, and to polymers produced therefrom.
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公开(公告)号:US06846886B2
公开(公告)日:2005-01-25
申请号:US10373259
申请日:2003-02-24
申请人: Simon Mawson , Sun-Chueh Kao , Tae Hoon Kwalk , Timothy Roger Lynn , David H. McConville , Matthew Gary McKee , John Francis Szul , Kersten Anne Terry , Timothy T. Wenzel , Mark Gregory Goode , John Henry Oskam , Robert J. Jorgensen , Robert Harold Vogel
发明人: Simon Mawson , Sun-Chueh Kao , Tae Hoon Kwalk , Timothy Roger Lynn , David H. McConville , Matthew Gary McKee , John Francis Szul , Kersten Anne Terry , Timothy T. Wenzel , Mark Gregory Goode , John Henry Oskam , Robert J. Jorgensen , Robert Harold Vogel
IPC分类号: C08F4/659 , C08F4/6592 , C08F10/00 , C08F210/16 , C08F4/44 , C08F4/70
CPC分类号: B01J8/1827 , B01J4/002 , B01J2219/00108 , C08F4/659 , C08F4/65912 , C08F4/65925 , C08F10/00 , C08F210/16 , Y10S526/943 , C08F4/65916 , C08F4/65904 , C08F2/00 , C08F210/14 , C08F2500/12 , C08F2500/24 , C08F2500/18 , C08F2500/26
摘要: The invention provides for polymerization catalyst compositions, and for methods for introducing the catalyst compositions into a polymerization reactor. More particularly, the method combines a catalyst component containing slurry and a catalyst component containing solution to form the completed catalyst composition for introduction into the polymerization reactor. The invention is also directed to methods of preparing the catalyst component slurry, the catalyst component solution and the catalyst compositions, to methods of controlling the properties of polymer products utilizing the catalyst compositions, and to polymers produced therefrom.
摘要翻译: 本发明提供聚合催化剂组合物以及用于将催化剂组合物引入聚合反应器的方法。 更具体地说,该方法结合了含催化剂组分的浆料和含催化剂组分的溶液以形成用于引入聚合反应器的完成的催化剂组合物。 本发明还涉及制备催化剂组分浆料,催化剂组分溶液和催化剂组合物的方法,以及使用该催化剂组合物控制聚合物产品性能的方法以及由其制备的聚合物。
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公开(公告)号:US06956089B2
公开(公告)日:2005-10-18
申请号:US10373121
申请日:2003-02-24
申请人: Simon Mawson , Sun-Chueh Kao , Tae Hoon Kwalk , Timothy Roger Lynn , David H. McConville , Matthew Gary McKee , John Francis Szul , Kersten Anne Terry , Timothy T. Wenzel , Mark Gregory Goode , John Henry Oskam , Robert J. Jorgensen , Robert Harold Vogel
发明人: Simon Mawson , Sun-Chueh Kao , Tae Hoon Kwalk , Timothy Roger Lynn , David H. McConville , Matthew Gary McKee , John Francis Szul , Kersten Anne Terry , Timothy T. Wenzel , Mark Gregory Goode , John Henry Oskam , Robert J. Jorgensen , Robert Harold Vogel
IPC分类号: C08F4/659 , C08F4/6592 , C08F10/00 , C08F210/16 , C08F4/64 , B01J31/38 , C08F210/14
CPC分类号: B01J8/1827 , B01J4/002 , B01J2219/00108 , C08F4/659 , C08F4/65912 , C08F4/65925 , C08F10/00 , C08F210/16 , Y10S526/943 , C08F4/65916 , C08F4/65904 , C08F2/00 , C08F210/14 , C08F2500/12 , C08F2500/24 , C08F2500/18 , C08F2500/26
摘要: The invention provides for polymerization catalyst compositions, and for methods for introducing the catalyst compositions into a polymerization reactor. More particularly, the method combines a catalyst component containing slurry and a catalyst component containing solution to form the completed catalyst composition for introduction into the polymerization reactor. The invention is also directed to methods of preparing the catalyst component slurry, the catalyst component solution and the catalyst compositions, to methods of controlling the properties of polymer products utilizing the catalyst compositions, and to polymers produced therefrom.
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公开(公告)号:US06825287B2
公开(公告)日:2004-11-30
申请号:US10772921
申请日:2004-02-05
申请人: Simon Mawson , Sun-Chueh Kao , Tae Hoon Kwalk , Timothy Roger Lynn , David H. McConville , Matthew Gary McKee , John Francis Szul , Kersten Anne Terry , Timothy T. Wenzel , Mark Gregory Goode , John Henry Oskam , Robert J. Jorgensen , Robert Harold Vogel
发明人: Simon Mawson , Sun-Chueh Kao , Tae Hoon Kwalk , Timothy Roger Lynn , David H. McConville , Matthew Gary McKee , John Francis Szul , Kersten Anne Terry , Timothy T. Wenzel , Mark Gregory Goode , John Henry Oskam , Robert J. Jorgensen , Robert Harold Vogel
IPC分类号: C08F234
CPC分类号: C08F10/00 , C08F4/659 , C08F4/65912 , C08F4/65925 , C08F210/16 , Y10S526/905 , Y10S526/943 , C08F4/65904 , C08F4/65916 , C08F2/00 , C08F210/14 , C08F2500/12 , C08F2500/24 , C08F2500/18 , C08F2500/26
摘要: The invention provides for polymerization catalyst compositions, and for methods for introducing the catalyst compositions into a polymerization reactor. More particularly, the method combines a catalyst component containing slurry and a catalyst component containing solution to form the completed catalyst composition for introduction into the polymerization reactor. The invention is also directed to methods of preparing the catalyst component slurry, the catalyst component solution and the catalyst compositions, to methods of controlling the properties of polymer products utilizing the catalyst compositions, and to polymers produced therefrom.
摘要翻译: 本发明提供聚合催化剂组合物以及用于将催化剂组合物引入聚合反应器的方法。 更具体地说,该方法结合了含催化剂组分的浆料和含催化剂组分的溶液以形成用于引入聚合反应器的完成的催化剂组合物。 本发明还涉及制备催化剂组分浆料,催化剂组分溶液和催化剂组合物的方法,以及使用该催化剂组合物控制聚合物产品性能的方法以及由其制备的聚合物。
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公开(公告)号:US06689847B2
公开(公告)日:2004-02-10
申请号:US09995043
申请日:2001-11-27
申请人: Simon Mawson , Sun-Chueh Kao , Tae Hoon Kwalk , Timothy Roger Lynn , David H. McConville , Matthew Gary McKee , John Francis Szul , Kersten Anne Terry , Timothy T. Wenzel , Mark Gregory Goode , John Henry Oskam , Robert J. Jorgensen , Robert Harold Vogel
发明人: Simon Mawson , Sun-Chueh Kao , Tae Hoon Kwalk , Timothy Roger Lynn , David H. McConville , Matthew Gary McKee , John Francis Szul , Kersten Anne Terry , Timothy T. Wenzel , Mark Gregory Goode , John Henry Oskam , Robert J. Jorgensen , Robert Harold Vogel
IPC分类号: C08F464
CPC分类号: C08F10/00 , C08F4/659 , C08F4/65912 , C08F4/65925 , C08F210/16 , Y10S526/903 , Y10S526/907 , Y10S526/943 , C08F4/65916 , C08F4/65904 , C08F2/00 , C08F210/14 , C08F2500/12 , C08F2500/24 , C08F2500/18 , C08F2500/26
摘要: The invention provides for polymerization catalyst compositions, and for methods for introducing the catalyst compositions into a polymerization reactor. More particularly, the method combines a catalyst component containing slurry and a catalyst component containing solution to form the completed catalyst composition for introduction into the polymerization reactor. The invention is also directed to methods of preparing the catalyst component slurry, the catalyst component solution and the catalyst compositions, to methods of controlling the properties of polymer products utilizing the catalyst compositions, and to polymers produced therefrom.
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8.
公开(公告)号:USRE41897E1
公开(公告)日:2010-10-26
申请号:US10761101
申请日:2004-01-20
申请人: Donald R. Loveday , David H. McConville , John F. Szul , Kersten Anne Terry , Simon Mawson , Tae Hoon Kwalk , Frederick J. Karol , David James Schreck
发明人: Donald R. Loveday , David H. McConville , John F. Szul , Kersten Anne Terry , Simon Mawson , Tae Hoon Kwalk , Frederick J. Karol , David James Schreck
CPC分类号: C08F10/02 , C08F4/659 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F10/00 , C08F210/16 , C08F2420/04 , C08L23/0815 , C08L23/16 , C08L2205/02 , C08L2314/06 , Y10S526/943 , C08F2/00 , C08F4/025 , C08L2666/04 , C08F210/14 , C08F2500/12 , C08F2500/04 , C08F2500/02 , C08F2500/01 , C08F2500/26 , C08F2500/05 , C08F4/64148 , C08F4/65904 , C08F4/64158 , C08F4/64144 , C08F4/64151
摘要: Catalyst compositions and methods, useful in polymerization processes, utilizing at least two metal compounds are disclosed. At least one of the metal compounds is a Group 15 containing metal compound and the other metal compound is preferably a bulky ligand metallocene-type catalyst. The invention also discloses a new polyolefin, generally polyethylene, particularly a multimodal polymer and more specifically, a bimodal polymer, and its use in various end-use applications such as film, molding and pipe.
摘要翻译: 公开了使用至少两种金属化合物的聚合方法中的催化剂组合物和方法。 至少一种金属化合物是含有第15族金属化合物,另一种金属化合物优选为大体积配体金属茂型催化剂。 本发明还公开了一种新的聚烯烃,一般为聚乙烯,特别是多峰聚合物,更具体地说是双峰聚合物,以及其在各种最终用途应用如薄膜,模塑和管材中的应用。
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9.
公开(公告)号:US06274684B1
公开(公告)日:2001-08-14
申请号:US09425387
申请日:1999-10-22
申请人: Donald R. Loveday , David H. McConville , John F. Szul , Kersten Anne Erickson , Simon Mawson , Tae Hoon Kwack , Frederick J. Karol , David James Schreck
发明人: Donald R. Loveday , David H. McConville , John F. Szul , Kersten Anne Erickson , Simon Mawson , Tae Hoon Kwack , Frederick J. Karol , David James Schreck
IPC分类号: C08F444
CPC分类号: C08F10/02 , C08F4/659 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F10/00 , C08F210/16 , C08F2420/04 , C08L23/0815 , C08L23/16 , C08L2205/02 , C08L2314/06 , Y10S526/943 , C08F2/00 , C08F4/025 , C08L2666/04 , C08F210/14 , C08F2500/12 , C08F2500/04 , C08F2500/02 , C08F2500/01 , C08F2500/26 , C08F2500/05 , C08F4/64148 , C08F4/65904 , C08F4/64158 , C08F4/64144 , C08F4/64151
摘要: Catalyst compositions and methods, useful in polymerization processes, utilizing at least two metal compounds are disclosed. At least one of the metal compounds is a Group 15 containing metal compound and the other metal compound is preferably a bulky ligand metallocene-type catalyst. The invention also discloses a new polyolefin, generally polyethylene, particularly a multimodal polymer and more specifically, a bimodal polymer, and its use in various end-use applications such as film, molding and pipe.
摘要翻译: 公开了使用至少两种金属化合物的聚合方法中的催化剂组合物和方法。 至少一种金属化合物是含有第15族金属化合物,另一种金属化合物优选为大体积配体金属茂型催化剂。 本发明还公开了一种新的聚烯烃,一般为聚乙烯,特别是多峰聚合物,更具体地说是双峰聚合物,以及其在各种最终用途应用如薄膜,模塑和管材中的应用。
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10.
公开(公告)号:US06894128B2
公开(公告)日:2005-05-17
申请号:US10634474
申请日:2003-08-05
申请人: Donald R. Loveday , David H. McConville , John F. Szul , Kersten Anne Erickson , Simon Mawson , Tae Hoon Kwack , Frederick J. Karol , David James Schreck
发明人: Donald R. Loveday , David H. McConville , John F. Szul , Kersten Anne Erickson , Simon Mawson , Tae Hoon Kwack , Frederick J. Karol , David James Schreck
IPC分类号: C08F4/02 , C08F4/06 , C08F4/44 , C08F4/642 , C08F4/645 , C08F4/659 , C08F4/6592 , C08F4/68 , C08F4/69 , C08F10/00 , C08F10/02 , C08F210/16 , C08L23/08 , C08L23/16 , C08F4/72 , C08F4/80
CPC分类号: C08F10/02 , C08F4/659 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F10/00 , C08F210/16 , C08F2420/04 , C08L23/0815 , C08L23/16 , C08L2205/02 , C08L2314/06 , Y10S526/943 , C08F2/00 , C08F4/025 , C08L2666/04 , C08F210/14 , C08F2500/12 , C08F2500/04 , C08F2500/02 , C08F2500/01 , C08F2500/26 , C08F2500/05 , C08F4/64148 , C08F4/65904 , C08F4/64158 , C08F4/64144 , C08F4/64151
摘要: Catalyst compositions and methods useful in polymerization processes utilizing at least two metal compounds are disclosed. At least one of the metal compounds is a Group 15 containing metal compound and the other metal compound is preferably a bulky ligand metallocene-type catalyst. The invention also discloses a new polyolefin, generally polyethylene, particularly a multimodal polymer and more specifically, a bimodal polymer, and its use in various end-use applications such as film, molding and pipe. The Group 15 containing metal compound is represented in one embodiment by the formulae: wherein M is a Group 4, 5, or 6 metal; each X is independently a leaving group; y is 0 or 1; n is the oxidation state of M; m is the formal change of the ligand comprising the YZL or YZL′ groups; L is a Group 15 or 16 element; L′ is a Group 15 or 16 element or Group 14 containing group; Y is a Group 15 element; Z is a Group 15 element; and the other groups are as defined herein.
摘要翻译: 公开了在使用至少两种金属化合物的聚合方法中有用的催化剂组合物和方法。 至少一种金属化合物是含有第15族金属化合物,另一种金属化合物优选为大体积配体金属茂型催化剂。 本发明还公开了一种新的聚烯烃,一般为聚乙烯,特别是多峰聚合物,更具体地说是双峰聚合物,以及其在各种最终用途应用如薄膜,模塑和管材中的应用。 含有金属化合物的第15族在一个实施方案中由下式表示:其中M是第4,5或6族金属; 每个X独立地为离去基团; y为0或1; n是M的氧化态; m是包含YZL或YZL'基团的配体的正式变化; L是15或16组元素; L'是15或16族元素或含14族的基团; Y是第15组元素; Z是15组元素; 并且其它基团如本文所定义。
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