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公开(公告)号:US08366973B2
公开(公告)日:2013-02-05
申请号:US11933357
申请日:2007-10-31
申请人: Dong Yu , Jacqueline Fidanza , Brian M. Sager
发明人: Dong Yu , Jacqueline Fidanza , Brian M. Sager
IPC分类号: H01B1/12
CPC分类号: H01L31/06 , B82Y5/00 , B82Y10/00 , B82Y30/00 , C23C18/1204 , C23C18/1266 , C23C18/1295 , H01L31/0322 , H01L31/0749 , H01L31/18 , Y02E10/541 , Y02P70/521
摘要: An ink for forming CIGS photovoltaic cell active layers is disclosed along with methods for making the ink, methods for making the active layers and a solar cell made with the active layer. The ink contains a mixture of nanoparticles of elements of groups IB, IIIA and (optionally) VIA. The particles are in a desired particle size range of between about 1 nm and about 500 nm in diameter, where a majority of the mass of the particles comprises particles ranging in size from no more than about 40% above or below an average particle size or, if the average particle size is less than about 5 nanometers, from no more than about 2 nanometers above or below the average particle size. The use of such ink avoids the need to expose the material to an H2Se gas during the construction of a photovoltaic cell and allows more uniform melting during film annealing, more uniform intermixing of nanoparticles, and allows higher quality absorber films to be formed.
摘要翻译: 公开了一种用于形成CIGS光伏电池有源层的墨水以及用于制备墨水的方法,制备活性层的方法和由活性层制成的太阳能电池。 油墨含有IB,IIIA和(任选地)VIA组分的纳米颗粒的混合物。 颗粒的直径在约1nm至约500nm之间的所需粒度范围,其中大部分颗粒的质量包括尺寸不超过平均粒度的约40%或以下的颗粒,或 如果平均粒度小于约5纳米,高于或低于平均粒度的不超过约2纳米。 使用这种墨水避免了在构建光伏电池期间将材料暴露于H 2 Se气体的需要,并且允许在膜退火期间更均匀的熔融,更均匀的纳米颗粒的混合,并且允许形成更高质量的吸收膜。
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公开(公告)号:US08206616B2
公开(公告)日:2012-06-26
申请号:US11933285
申请日:2007-10-31
申请人: Dong Yu , Jacqueline Fidanza , Brian M. Sager
发明人: Dong Yu , Jacqueline Fidanza , Brian M. Sager
CPC分类号: H01L31/06 , B82Y5/00 , B82Y10/00 , B82Y30/00 , C23C18/1204 , C23C18/1266 , C23C18/1295 , H01L31/0322 , H01L31/0749 , H01L31/18 , Y02E10/541 , Y02P70/521
摘要: An ink for forming CIGS photovoltaic cell active layers is disclosed along with methods for making the ink, methods for making the active layers and a solar cell made with the active layer. The ink contains a mixture of nanoparticles of elements of groups IB, IIIA and (optionally) VIA. The particles are in a desired particle size range of between about 1 nm and about 500 nm in diameter, where a majority of the mass of the particles comprises particles ranging in size from no more than about 40% above or below an average particle size or, if the average particle size is less than about 5 nanometers, from no more than about 2 nanometers above or below the average particle size. The use of such ink avoids the need to expose the material to an H2Se gas during the construction of a photovoltaic cell and allows more uniform melting during film annealing, more uniform intermixing of nanoparticles, and allows higher quality absorber films to be formed.
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公开(公告)号:US08168089B2
公开(公告)日:2012-05-01
申请号:US11933322
申请日:2007-10-31
申请人: Dong Yu , Jacqueline Fidanza , Brian M. Sager
发明人: Dong Yu , Jacqueline Fidanza , Brian M. Sager
CPC分类号: H01L31/06 , B82Y5/00 , B82Y10/00 , B82Y30/00 , C23C18/1204 , C23C18/1266 , C23C18/1295 , H01L31/0322 , H01L31/0749 , H01L31/18 , Y02E10/541 , Y02P70/521
摘要: An ink for forming CIGS photovoltaic cell active layers is disclosed along with methods for making the ink, methods for making the active layers and a solar cell made with the active layer. The ink contains a mixture of nanoparticles of elements of groups IB, IIIA and (optionally) VIA. The particles are in a desired particle size range of between about 1 nm and about 500 nm in diameter, where a majority of the mass of the particles comprises particles ranging in size from no more than about 40% above or below an average particle size or, if the average particle size is less than about 5 nanometers, from no more than about 2 nanometers above or below the average particle size. The use of such ink avoids the need to expose the material to an H2Se gas during the construction of a photovoltaic cell and allows more uniform melting during film annealing, more uniform intermixing of nanoparticles, and allows higher quality absorber films to be formed.
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公开(公告)号:US20080135099A1
公开(公告)日:2008-06-12
申请号:US11933407
申请日:2007-10-31
申请人: Dong Yu , Jacqueline Fidanza , Brian M. Sager
发明人: Dong Yu , Jacqueline Fidanza , Brian M. Sager
IPC分类号: H01L31/0216
CPC分类号: H01L31/06 , B82Y5/00 , B82Y10/00 , B82Y30/00 , C23C18/1204 , C23C18/1266 , C23C18/1295 , H01L31/0322 , H01L31/0749 , H01L31/18 , Y02E10/541 , Y02P70/521
摘要: An ink for forming CIGS photovoltaic cell active layers is disclosed along with methods for making the ink, methods for making the active layers and a solar cell made with the active layer. The ink contains a mixture of nanoparticles of elements of groups IB, IIIA and (optionally) VIA. The particles are in a desired particle size range of between about 1 nm and about 500 nm in diameter, where a majority of the mass of the particles comprises particles ranging in size from no more than about 40% above or below an average particle size or, if the average particle size is less than about 5 nanometers, from no more than about 2 nanometers above or below the average particle size. The use of such ink avoids the need to expose the material to an H2Se gas during the construction of a photovoltaic cell and allows more uniform melting during film annealing, more uniform intermixing of nanoparticles, and allows higher quality absorber films to be formed.
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公开(公告)号:US08182720B2
公开(公告)日:2012-05-22
申请号:US11933136
申请日:2007-10-31
申请人: Dong Yu , Jacqueline Fidanza , Brian M. Sager
发明人: Dong Yu , Jacqueline Fidanza , Brian M. Sager
CPC分类号: H01L31/06 , B82Y5/00 , B82Y10/00 , B82Y30/00 , C23C18/1204 , C23C18/1266 , C23C18/1295 , H01L31/0322 , H01L31/0749 , H01L31/18 , Y02E10/541 , Y02P70/521
摘要: An ink for forming CIGS photovoltaic cell active layers is disclosed along with methods for making the ink, methods for making the active layers and a solar cell made with the active layer. The ink contains a mixture of nanoparticles of elements of groups IB, IIIA and (optionally) VIA. The particles are in a desired particle size range of between about 1 nm and about 500 nm in diameter, where a majority of the mass of the particles comprises particles ranging in size from no more than about 40% above or below an average particle size or, if the average particle size is less than about 5 nanometers, from no more than about 2 nanometers above or below the average particle size. The use of such ink avoids the need to expose the material to an H2Se gas during the construction of a photovoltaic cell and allows more uniform melting during film annealing, more uniform intermixing of nanoparticles, and allows higher quality absorber films to be formed.
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公开(公告)号:US20100267189A1
公开(公告)日:2010-10-21
申请号:US12705945
申请日:2010-02-15
申请人: Dong Yu , Jacqueline Fidanza , Brian M. Sager
发明人: Dong Yu , Jacqueline Fidanza , Brian M. Sager
CPC分类号: H01L31/06 , B82Y5/00 , B82Y10/00 , B82Y30/00 , C23C18/1204 , C23C18/1266 , C23C18/1295 , H01L31/0322 , H01L31/0749 , H01L31/18 , Y02E10/541 , Y02P70/521
摘要: An ink for forming CIGS photovoltaic cell active layers is disclosed along with methods for making the ink, methods for making the active layers and a solar cell made with the active layer. The ink contains a mixture of nanoparticles of elements of groups IB, IIIA and (optionally) VIA. The particles are in a desired particle size range of between about 1 nm and about 500 nm in diameter, where a majority of the mass of the particles comprises particles ranging in size from no more than about 40% above or below an average particle size or, if the average particle size is less than about 5 nanometers, from no more than about 2 nanometers above or below the average particle size. The use of such ink avoids the need to expose the material to an H2Se gas during the construction of a photovoltaic cell and allows more uniform melting during film annealing, more uniform intermixing of nanoparticles, and allows higher quality absorber films to be formed.
摘要翻译: 公开了一种用于形成CIGS光伏电池有源层的墨水以及用于制造墨水的方法,制备活性层的方法和由活性层制成的太阳能电池。 油墨含有IB,IIIA和(任选地)VIA组分的纳米颗粒的混合物。 颗粒的直径在约1nm至约500nm之间的所需粒度范围,其中大部分颗粒的质量包括尺寸不超过平均粒度的约40%或以下的颗粒,或 如果平均粒度小于约5纳米,高于或低于平均粒度的不超过约2纳米。 使用这种墨水避免了在构建光伏电池期间将材料暴露于H 2 Se气体的需要,并且允许在膜退火期间更均匀的熔融,更均匀的纳米颗粒的混合,并且允许形成更高质量的吸收膜。
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公开(公告)号:US07663057B2
公开(公告)日:2010-02-16
申请号:US10782017
申请日:2004-02-19
CPC分类号: H01L31/06 , B82Y5/00 , B82Y10/00 , B82Y30/00 , C23C18/1204 , C23C18/1266 , C23C18/1295 , H01L31/0322 , H01L31/0749 , H01L31/18 , Y02E10/541 , Y02P70/521
摘要: An ink for forming CIGS photovoltaic cell active layers is disclosed along with methods for making the ink, methods for making the active layers and a solar cell made with the active layer. The ink contains a mixture of nanoparticles of elements of groups IB, IIIA and (optionally) VIA. The particles are in a desired particle size range of between about 1 nm and about 500 nm in diameter, where a majority of the mass of the particles comprises particles ranging in size from no more than about 40% above or below an average particle size or, if the average particle size is less than about 5 nanometers, from no more than about 2 nanometers above or below the average particle size. The use of such ink avoids the need to expose the material to an H2Se gas during the construction of a photovoltaic cell and allows more uniform melting during film annealing, more uniform intermixing of nanoparticles, and allows higher quality absorber films to be formed.
摘要翻译: 公开了一种用于形成CIGS光伏电池有源层的墨水以及用于制造墨水的方法,制备活性层的方法和由活性层制成的太阳能电池。 油墨含有IB,IIIA和(任选地)VIA组分的纳米颗粒的混合物。 颗粒的直径在约1nm至约500nm之间的所需粒度范围,其中大部分颗粒的质量包括尺寸不超过平均粒度的约40%或以下的颗粒,或 如果平均粒度小于约5纳米,高于或低于平均粒度的不超过约2纳米。 使用这种墨水避免了在构建光伏电池期间将材料暴露于H 2 Se气体的需要,并且允许在膜退火期间更均匀的熔融,更均匀的纳米颗粒的混合,并且允许形成更高质量的吸收膜。
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公开(公告)号:US20080142080A1
公开(公告)日:2008-06-19
申请号:US11933315
申请日:2007-10-31
申请人: Dong Yu , Jacqueline Fidanza , Brian M. Sager
发明人: Dong Yu , Jacqueline Fidanza , Brian M. Sager
IPC分类号: H01L31/0216 , C09D11/00
CPC分类号: H01L31/06 , B82Y5/00 , B82Y10/00 , B82Y30/00 , C23C18/1204 , C23C18/1266 , C23C18/1295 , H01L31/0322 , H01L31/0749 , H01L31/18 , Y02E10/541 , Y02P70/521
摘要: An ink for forming CIGS photovoltaic cell active layers is disclosed along with methods for making the ink, methods for making the active layers and a solar cell made with the active layer. The ink contains a mixture of nanoparticles of elements of groups IB, IIIA and (optionally) VIA. The particles are in a desired particle size range of between about 1 nm and about 500 nm in diameter, where a majority of the mass of the particles comprises particles ranging in size from no more than about 40% above or below an average particle size or, if the average particle size is less than about 5 nanometers, from no more than about 2 nanometers above or below the average particle size. The use of such ink avoids the need to expose the material to an H2Se gas during the construction of a photovoltaic cell and allows more uniform melting during film annealing, more uniform intermixing of nanoparticles, and allows higher quality absorber films to be formed.
摘要翻译: 公开了一种用于形成CIGS光伏电池有源层的墨水以及用于制造墨水的方法,制备活性层的方法和由活性层制成的太阳能电池。 油墨含有IB,IIIA和(任选地)VIA组分的纳米颗粒的混合物。 颗粒的直径在约1nm至约500nm之间的所需粒度范围,其中大部分颗粒的质量包括尺寸不超过平均粒度的约40%或以下的颗粒,或 如果平均粒度小于约5纳米,高于或低于平均粒度的不超过约2纳米。 使用这种墨水避免了在构建光伏电池期间将材料暴露于H 2 S 2 Se气体,并且允许在膜退火期间更均匀的熔融,更均匀的纳米颗粒的混合,并且允许更高的 要形成的质量吸收膜。
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公开(公告)号:US06946597B2
公开(公告)日:2005-09-20
申请号:US10443456
申请日:2003-05-21
申请人: Brian M. Sager , Martin R. Roscheisen , Klus Petritsch , Karl Pichler , Jacqueline Fidanza , Dong Yu
发明人: Brian M. Sager , Martin R. Roscheisen , Klus Petritsch , Karl Pichler , Jacqueline Fidanza , Dong Yu
IPC分类号: H01L20060101 , H01L31/00 , H01L31/0256 , H01L31/0352 , H01L31/042 , H01L31/18
CPC分类号: H01L51/4213 , H01L51/0036 , H01L51/0037 , H01L51/422 , H01L51/4253 , H01L51/447 , Y02E10/549 , Y02P70/521
摘要: Photovoltaic devices, such as solar cells, and methods for their manufacture are disclosed. A device may be characterized by an architecture where two more materials having different electron affinities are regularly arrayed such that their presence alternates within distances of between about 1 nm and about 100 nm. The materials are present in a matrix based on a porous template with an array of template pores. The porous template is formed by anodizing a layer of metal. A photovoltaic device may include such a porous template disposed between a base electrode and a transparent conducting electrode. A first charge-transfer material fills the template pores, A second (complementary) charge-transfer material fills additional space not occupied by the first charge-transfer material.
摘要翻译: 公开了太阳能电池等光伏器件及其制造方法。 器件的特征可以在于其中两个具有不同电子亲和力的材料被规则排列的结构,使得它们的存在在约1nm和约100nm之间的距离内交替。 该材料基于具有模板孔阵列的多孔模板存在于基质中。 通过阳极氧化一层金属形成多孔模板。 光伏器件可以包括设置在基极和透明导电电极之间的这种多孔模板。 第一电荷转移材料填充模板孔。第二(互补)电荷转移材料填充未被第一电荷转移材料占据的附加空间。
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公开(公告)号:US08038909B2
公开(公告)日:2011-10-18
申请号:US11933338
申请日:2007-10-31
申请人: Dong Yu , Jacqueline Fidanza , Brian M. Sager
发明人: Dong Yu , Jacqueline Fidanza , Brian M. Sager
CPC分类号: H01L31/06 , B82Y5/00 , B82Y10/00 , B82Y30/00 , C23C18/1204 , C23C18/1266 , C23C18/1295 , H01L31/0322 , H01L31/0749 , H01L31/18 , Y02E10/541 , Y02P70/521
摘要: An ink for forming CIGS photovoltaic cell active layers is disclosed along with methods for making the ink, methods for making the active layers and a solar cell made with the active layer. The ink contains a mixture of nanoparticles of elements of groups IB, IIIA and (optionally) VIA. The particles are in a desired particle size range of between about 1 nm and about 500 nm in diameter, where a majority of the mass of the particles comprises particles ranging in size from no more than about 40% above or below an average particle size or, if the average particle size is less than about 5 nanometers, from no more than about 2 nanometers above or below the average particle size. The use of such ink avoids the need to expose the material to an H2Se gas during the construction of a photovoltaic cell and allows more uniform melting during film annealing, more uniform intermixing of nanoparticles, and allows higher quality absorber films to be formed.
摘要翻译: 公开了一种用于形成CIGS光伏电池有源层的墨水以及用于制造墨水的方法,制备活性层的方法和由活性层制成的太阳能电池。 油墨含有IB,IIIA和(任选地)VIA组分的纳米颗粒的混合物。 颗粒的直径在约1nm至约500nm之间的所需粒度范围,其中大部分颗粒的质量包括尺寸不超过平均粒度的约40%或以下的颗粒,或 如果平均粒度小于约5纳米,高于或低于平均粒度的不超过约2纳米。 使用这种墨水避免了在构建光伏电池期间将材料暴露于H 2 Se气体的需要,并且允许在膜退火期间更均匀的熔融,更均匀的纳米颗粒的混合,并且允许形成更高质量的吸收膜。
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