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公开(公告)号：US07488774B2
公开(公告)日：2009-02-10
申请号：US11384737
申请日：2006-03-20
申请人： Doug Berti , Aron Griffith , Jay Reimers , Thanh Nguyen
发明人： Doug Berti , Aron Griffith , Jay Reimers , Thanh Nguyen
CPC分类号： C08F279/04
摘要： A continuous process for producing high impact polystyrene comprising feeding at least one vinyl aromatic monomer, an elastomer, and a free radical initiator to a first linear flow reactor to form a reaction mixture, polymerizing the reaction mixture in said linear flow reactor to at least the phase inversion point of the mixture, and feeding the reaction mixture from the first linear flow reactor to a second reactor for post-inversion polymerization of the mixture. A method of producing an elastomer-reinforced polymer comprising inverting a reaction mixture comprising at least one vinyl aromatic monomer, an elastomer, and a free radical initiator in a plug flow reactor. A high impact polystyrene reactor system, comprising a linear flow reactor having an inlet and an outlet, and a continuously stirred tank reactor having an inlet in fluid communication with the linear flow reactor outlet and receiving an effluent from the linear flow reactor.
摘要翻译： 一种用于生产高抗冲聚苯乙烯的连续方法，包括将至少一种乙烯基芳族单体，弹性体和自由基引发剂进料至第一线性流动反应器以形成反应混合物，将所述线性流动反应器中的反应混合物聚合至至少 混合物的相转化点，并将反应混合物从第一线性流动反应器进料到第二反应器用于混合物的反转后聚合。 一种生产弹性体增强聚合物的方法，包括在活塞流反应器中使包含至少一种乙烯基芳族单体，弹性体和自由基引发剂的反应混合物倒置。 一种高抗冲聚苯乙烯反应器系统，包括具有入口和出口的线性流动反应器和连续搅拌的罐式反应器，其具有与线性流动反应器出口流体连通的入口并接收来自线性流动反应器的流出物。
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公开(公告)号：US20070142549A1
公开(公告)日：2007-06-21
申请号：US11384737
申请日：2006-03-20
申请人： Doug Berti , Aron Griffith , Jay Reimers , Thanh Nguyen
发明人： Doug Berti , Aron Griffith , Jay Reimers , Thanh Nguyen
IPC分类号： C08F297/08
CPC分类号： C08F279/04
摘要： A continuous process for producing high impact polystyrene comprising feeding at least one vinyl aromatic monomer, an elastomer, and a free radical initiator to a first linear flow reactor to form a reaction mixture, polymerizing the reaction mixture in said linear flow reactor to at least the phase inversion point of the mixture, and feeding the reaction mixture from the first linear flow reactor to a second reactor for post-inversion polymerization of the mixture. A method of producing an elastomer-reinforced polymer comprising inverting a reaction mixture comprising at least one vinyl aromatic monomer, an elastomer, and a free radical initiator in a plug flow reactor. A high impact polystyrene reactor system, comprising a linear flow reactor having an inlet and an outlet, and a continuously stirred tank reactor having an inlet in fluid communication with the linear flow reactor outlet and receiving an effluent from the linear flow reactor.
摘要翻译： 一种用于生产高抗冲聚苯乙烯的连续方法，包括将至少一种乙烯基芳族单体，弹性体和自由基引发剂进料至第一线性流动反应器以形成反应混合物，将所述线性流动反应器中的反应混合物聚合至至少 混合物的相转化点，并将反应混合物从第一线性流动反应器进料到第二反应器用于混合物的反转后聚合。 一种生产弹性体增强聚合物的方法，包括在活塞流反应器中使包含至少一种乙烯基芳族单体，弹性体和自由基引发剂的反应混合物倒置。 一种高抗冲聚苯乙烯反应器系统，包括具有入口和出口的线性流动反应器和连续搅拌的罐式反应器，其具有与线性流动反应器出口流体连通的入口并接收来自线性流动反应器的流出物。
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公开(公告)号：US20070142594A1
公开(公告)日：2007-06-21
申请号：US11384596
申请日：2006-03-20
IPC分类号： C08F136/00
CPC分类号： C08F279/02 , B01F7/045 , B01J10/002 , B01J19/0013 , B01J19/0066 , B01J19/1818 , B01J2219/00128 , B01J2219/00243 , B01J2219/182 , C08L51/04 , F28C3/06 , C08L2666/02
摘要： A method for removing heat from a horizontal linear flow reactor, comprising introducing vapor bubbles into a liquid medium in the reactor and removing the vapor from the reactor. A method of producing an elastomer reinforced polymer comprising autorefrigerating the reactants in a horizontal linear flow reactor in which both initial polymerization and phase inversion occur. A method of removing heat from a horizontal plug flow reactor comprising aerating the reactants within the reactor, wherein the aeration promotes radial mixing of the reactants but does not substantially promote axial mixing of the reactants. A horizontal linear flow reactor, comprising a horizontal reaction chamber having one or more mechanical flow facilitators disposed therein and a sparger attached to the bottom of at least a portion of the reaction chamber.
摘要翻译： 一种用于从水平线性流动反应器中除去热量的方法，包括将蒸汽气泡引入反应器中的液体介质中并从反应器中除去蒸汽。 一种制备弹性体增强聚合物的方法，包括在初始聚合和相转化都发生的水平线性流动反应器中自动制冷反应物。 一种从卧式活塞式流动反应器中除去热的方法，包括使反应器内的反应物充气，其中曝气促进反应物的径向混合，但基本上不促进反应物的轴向混合。 一种水平线性流动反应器，包括具有一个或多个机械流动促进器的水平反应室，以及附着在反应室的至少一部分的底部的分布器。
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公开(公告)号：US20060251554A1
公开(公告)日：2006-11-09
申请号：US11121795
申请日：2005-05-04
申请人： Laurent Doucet , Philippe Tanguy , Doug Berti , Thanh Nguyen , Guillaume Franc , Jay Reimers
发明人： Laurent Doucet , Philippe Tanguy , Doug Berti , Thanh Nguyen , Guillaume Franc , Jay Reimers
CPC分类号： B01J10/002 , B01F3/04531 , B01F7/001 , B01F7/00241 , B01F7/00275 , B01F7/00633 , B01F7/183 , B01F15/00883 , B01F15/00915 , B01J19/006 , B01J19/0066 , B01J2219/00777 , B01J2219/00779
摘要： Disclosed is a reactor or sparging vessel suitable for use for reaction mixtures containing vapor and/or gas bubbles. It comprises a mechanical agitation means suitable to redistribute flow radially and at least one perforated plate suitable to provide resistance to axial flow. In desirable embodiments it may include at least one electrically or hydraulically-stimulated rotatable shaft upon which at least one blade impeller is mounted, and at least one perforated plate oriented such that it provides resistance to axial flow. The perforated plate may have channels therethrough whose cross-sectional dimension is smaller than the projected average diameter of the vapor and/or gas bubbles. The reactor or sparging vessel offers improved flow dynamics, including reduced back mixing and narrowed residence time distribution. A method of employing the reactor for a reaction mixture containing vapor and/or gas bubbles is also disclosed. An impeller blade having two curvatures is also disclosed.
摘要翻译： 公开了适用于含有蒸气和/或气泡的反应混合物的反应器或喷射容器。 它包括适于重新分布流动的机械搅拌装置和适于提供对轴向流动的阻力的至少一个多孔板。 在理想的实施例中，其可以包括至少一个电或液压刺激的可旋转轴，至少一个叶片叶轮安装在该可旋转轴上，并且至少一个多孔板定向成使得其提供对轴向流动的阻力。 多孔板可以具有通道，其横截面尺寸小于蒸气和/或气泡的投影平均直径。 反应器或喷射容器提供改善的流动动力学，包括减少后混合和缩短的停留时间分布。 还公开了使用反应器用于含有蒸气和/或气泡的反应混合物的方法。 还公开了具有两个曲率的叶轮叶片。
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公开(公告)号：US08192695B2
公开(公告)日：2012-06-05
申请号：US11121795
申请日：2005-05-04
申请人： Laurent Doucet , Philippe Tanguy , Doug Berti , Thanh Nguyen , Guillaume Franc , Jay Reimers
发明人： Laurent Doucet , Philippe Tanguy , Doug Berti , Thanh Nguyen , Guillaume Franc , Jay Reimers
CPC分类号： B01J10/002 , B01F3/04531 , B01F7/001 , B01F7/00241 , B01F7/00275 , B01F7/00633 , B01F7/183 , B01F15/00883 , B01F15/00915 , B01J19/006 , B01J19/0066 , B01J2219/00777 , B01J2219/00779
摘要： Disclosed is a reactor or sparging vessel suitable for use for reaction mixtures containing vapor and/or gas bubbles. It comprises a mechanical agitation means suitable to redistribute flow radially and at least one perforated plate suitable to provide resistance to axial flow. In desirable embodiments it may include at least one electrically or hydraulically-stimulated rotatable shaft upon which at least one blade impeller is mounted, and at least one perforated plate oriented such that it provides resistance to axial flow. The perforated plate may have channels therethrough whose cross-sectional dimension is smaller than the projected average diameter of the vapor and/or gas bubbles. The reactor or sparging vessel offers improved flow dynamics, including reduced back mixing and narrowed residence time distribution. A method of employing the reactor for a reaction mixture containing vapor and/or gas bubbles is also disclosed. An impeller blade having two curvatures is also disclosed.
摘要翻译： 公开了适用于含有蒸气和/或气泡的反应混合物的反应器或喷射容器。 它包括适于重新分布流动的机械搅拌装置和适于提供对轴向流动的阻力的至少一个多孔板。 在理想的实施例中，其可以包括至少一个电或液压刺激的可旋转轴，至少一个叶片叶轮安装在该可旋转轴上，并且至少一个多孔板定向成使得其提供对轴向流动的阻力。 多孔板可以具有通道，其横截面尺寸小于蒸气和/或气泡的投影平均直径。 反应器或喷射容器提供改善的流动动力学，包括减少后混合和缩短的停留时间分布。 还公开了使用反应器用于含有蒸汽和/或气泡的反应混合物的方法。 还公开了具有两个曲率的叶轮叶片。
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公开(公告)号：US07060736B2
公开(公告)日：2006-06-13
申请号：US10335809
申请日：2003-05-07
申请人： Jay Reimers , Doug Berti
发明人： Jay Reimers , Doug Berti
CPC分类号： C08J9/00
摘要： The selection of additives to improve the solubility of blowing agents may be facilitated by using a method that involves determining and comparing the activity coefficients of prospective additives to the activity coefficients of candidate blowing agents in a given base polymer for producing a polymeric foam article. The method for the selection of an additive may comprise selecting a representative compound for the base polymer and determining a first activity coefficient for a blowing agent in the representative compound. Also selected are several candidate additives, each having a different functional group, and determining a second activity coefficient for the blowing agent in each of the candidate additives. Among the candidate additives is selected the additive, wherein the second activity coefficient is lower than the first activity coefficient. The method may be incorporated into a process for forming polymeric foams and the manufacture of a polymeric foam.
摘要翻译： 通过使用包括确定和比较预期添加剂的活性系数与用于制备聚合物泡沫制品的给定基础聚合物中的候选发泡剂的活度系数的方法，可以促进添加剂的选择以提高发泡剂的溶解度。 选择添加剂的方法可以包括选择用于基础聚合物的代表性化合物并确定代表性化合物中发泡剂的第一活性系数。 还选择几种候选添加剂，各自具有不同的官能团，并且确定每种候选添加剂中发泡剂的第二活性系数。 在候选添加剂中选择添加剂，其中第二活性系数低于第一活性系数。 该方法可以并入用于形成聚合物泡沫的方法和聚合物泡沫的制造中。
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7.发明授权
公开(公告)号：US6143833A
公开(公告)日：2000-11-07
申请号：US262182
申请日：1999-06-11
申请人： Brad Klussmann , Jon Schweinle , Doug Berti , Thanh Nguyen , Jose Sosa
发明人： Brad Klussmann , Jon Schweinle , Doug Berti , Thanh Nguyen , Jose Sosa
IPC分类号： C08F2/01 , C08F2/00 , C08F279/02 , C08F285/00 , C08L51/04
CPC分类号： C08F279/02 , C08F285/00 , C08L51/04
摘要： A method and apparatus for use in making high impact polystyrene by polymerizing butadiene into polybutadiene, continuously exchanging styrene monomer for the solvent used to produce the polybutadiene, and polymerizing the resultant polybutadiene/styrene solution into high impact polystyrene. Apparatus is disclosed that includes butadiene and solvent preparation means, additive metering means, butadiene polymerization means, solvent exchange means, solvent recovery means and styrene polymerization means.
摘要翻译： 通过将丁二烯聚合成聚丁二烯，连续交换用于制备聚丁二烯的溶剂的苯乙烯单体，并将所得聚丁二烯/苯乙烯溶液聚合成高抗冲聚苯乙烯，制备高抗冲聚苯乙烯的方法和装置。 公开了包括丁二烯和溶剂制备装置，添加剂计量装置，丁二烯聚合装置，溶剂交换装置，溶剂回收装置和苯乙烯聚合装置的装置。
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公开(公告)号：US20070225440A1
公开(公告)日：2007-09-27
申请号：US11728447
申请日：2007-03-24
申请人： Jose Sosa , Kenneth Blackmon , Doug Berti
发明人： Jose Sosa , Kenneth Blackmon , Doug Berti
IPC分类号： C08L51/00
CPC分类号： C08F287/00 , C08F279/02 , C08L9/00 , C08L25/06 , C08L51/006 , C08L51/04 , C08L2666/02 , C08F212/08
摘要： Disclosed is a composition comprising an impact modified polystyrene prepared using a process comprising dissolving a styrene-butadiene-styrene block copolymer in styrene monomer and polymerizing the styrene monomer wherein the impact modified polystyrene has a haze value of less than or equal to 12 percent. Also disclosed is an impact modified polystyrene prepared using the same process and having a ratio of Mz/Mn of at least 4.1.
摘要翻译： 公开了包含使用包括将苯乙烯 - 丁二烯 - 苯乙烯嵌段共聚物溶解在苯乙烯单体中并使苯乙烯单体聚合的方法制备的抗冲改性聚苯乙烯的组合物，其中抗冲改性聚苯乙烯的雾度值小于或等于12％。 还公开了使用相同方法制备的具有至少4.1的Mz / Mn比的冲击改性聚苯乙烯。
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公开(公告)号：US20050070663A1
公开(公告)日：2005-03-31
申请号：US10729446
申请日：2003-12-05
申请人： Jose Sosa , Kenneth Blackmon , Doug Berti
发明人： Jose Sosa , Kenneth Blackmon , Doug Berti
IPC分类号： C08F279/02 , C08F287/00 , C08L51/00 , C08L51/04
CPC分类号： C08F287/00 , C08F279/02 , C08L9/00 , C08L25/06 , C08L51/006 , C08L51/04 , C08L2666/02 , C08F212/08
摘要： Disclosed is a composition comprising an impact modified polystyrene prepared using a process comprising dissolving a styrene-butadiene-styrene block copolymer in styrene monomer and polymerizing the styrene monomer wherein the impact modified polystyrene has a haze value of less than or equal to 12 percent. Also disclosed is an impact modified polystyrene prepared using the same process and having a ratio of Mz/Mn of at least 4.1.
摘要翻译： 公开了包含使用包括将苯乙烯 - 丁二烯 - 苯乙烯嵌段共聚物溶解在苯乙烯单体中并使苯乙烯单体聚合的方法制备的抗冲改性聚苯乙烯的组合物，其中抗冲改性聚苯乙烯的雾度值小于或等于12％。 还公开了使用相同方法制备的具有至少4.1的Mz / Mn比的冲击改性聚苯乙烯。
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