摘要:
A sintered ceramic that exhibits an average linear coefficient of thermal expansion (25-800° C.) below about 5.0×10−7° C.−1, a total porosity between the range of 20% to about 30%. Furthermore, the sintered ceramic article exhibits a pore size distribution such that at least about 86% of pores are of a pore size of less than about 2 &mgr;m. Lastly, the ceramic article exhibits an interconnected pore structure with the pores exhibiting a generally elongated shape, i.e., the pores are predominately oriented with their long axis in the plane of the webs. This invention also relates to a method for producing a sintered cordierite ceramic article involving first compounding and plasticizing a cordierite-forming inorganic powder batch comprising a platy talc having median particle of size less than about 2 &mgr;m, and preferably a talc morphology index greater than about 0.75. The batch further comprises at least 4% by weight of the inorganic powder batch mixture of a dispersible Al2O3-forming source having a specific surface area in excess of 50 m2/g and one or more of the components of kaolin, calcined kaolin, silica, and corundum, each having a median particle sizes less than 5 &mgr;m. The plasticized powder batch thus provided is next formed into a green honeycomb by extrusion through a honeycomb extrusion die and the green honeycomb is fired to a temperature and for a time sufficient to convert the green honeycomb into a crystallized cordierite ceramic article having the aforementioned properties.
摘要:
A sintered ceramic honeycomb article that exhibits an average linear coefficient of thermal expansion (25-800° C.) below about 5.0×10−7° C.−1, a total porosity between the range of 20% to about 30%, and a pore size distribution such that at least about 86% of pores are of a pore size of less than about 2 &mgr;m with the pores exhibiting a generally elongated shape oriented with their long axis in the plane of the webs, the article being made from a cordierite-forming inorganic powder batch comprising a platy talc having median particle of size less than about 2 &mgr;m, at least 4% by weight of a dispersible Al2O3-forming source having a specific surface area in excess of 50 m2/g, and one or more of the components of kaolin, calcined kaolin, silica, and corundum, each having a median particle sizes less than 5 &mgr;m.
摘要翻译:一种烧结陶瓷蜂窝体制品,其平均线性热膨胀系数(25-800℃)低于约5.0×10-7℃-1,总孔隙率在20%至30%之间,和 孔尺寸分布使得至少约86%的孔具有小于约2μm的孔径,其中孔具有以其长轴在幅平面中定向的大致细长形状,该制品由堇青石制成 包含具有中值粒径小于约2μm的片状滑石的至少4重量%的比表面积超过50m 2 / g的可分散Al 2 O 3形成源的至少4重量%的无机粉末批料,以及一种或多种 的高岭土,煅烧高岭土,二氧化硅和刚玉的组分,各自具有小于5μm的中值粒度。
摘要:
Fine circumferential skin cracking in extruded thin-walled cordierite honeycombs having channel wall thicknesses not exceeding about 0.004 inches (100 &mgr;m) but skin layers of substantially higher thickness is prevented by extruding the honeycombs under conditions that enhance cordierite crystal alignment in the skin; thin-walled honeycomb products having skins free of fine cracks that are well-matched in thermal expansion to the honeycomb cores are provided.
摘要:
A binder system for use in the formation of ceramic or other powder-formed greenware comprising a binder, a solvent for the binder, a surfactant, and a component that is non-solvent with respect to the binder and solvent. The non-solvent component exhibits a lower viscosity than the solvent when containing the binder and comprises a low molecular weight oil having a 90% recovered distillation temperature range of between about 220 to 400° C. Also disclosed is a process of forming and shaping plasticized powder mixtures and a process for forming ceramic articles utilizing the binder system.
摘要:
A binder system for use in the formation of ceramic or other powder-formed greenware including a binder, a solvent for the binder, a surfactant, and a component that is non-solvent with respect to the binder and solvent. The non-solvent component exhibits a lower viscosity than the solvent when containing the binder and includes a low molecular weight oil having a 90% recovered distillation temperature range of between about 220 to 400° C. Also disclosed is a process of forming and shaping plasticized powder mixtures and a process for forming ceramic articles utilizing the binder system.
摘要:
Methods of manufacturing a honeycomb structure comprise the step of providing a honeycomb body having a multiplicity of cells extending therethrough between opposing end faces. The cells are defined by intersecting porous walls. The methods further include the steps of applying an after-applied skin layer on the honeycomb body and chamfering an edge of the after-applied skin. The chamfering step is performed on a wet after-applied skin layer.
摘要:
A method of drying plastically deformable metal structures using high frequency energy in a frequency range greater than 10 MHz. The highly efficient drying of the invention is accomplished by shielding the structure from the electrodes using a material whose dielectric constant is greater than that of air.
摘要:
The present invention provides methods for manufacturing a honeycomb filter having an after-applied skin with chamfered edges formed on the face-ends of the honeycomb filter structure. Apparatus for the manufacture of these honeycomb structures having after-applied skin with chamfered edges are also provided. In addition, honeycomb filter structures with chamfered after-applied skins are provided
摘要:
An improvement in a method of extruding a plasticized inorganic powder mixture having a plasticizing organic binder carried in an aqueous vehicle, by passing the mixture through an extruder and then through a die to produce an extrudate. The improvement involves homogeneously blending in the extruder as part of the mixture, carbon dioxide in the supercritical and/or liquid form, to lower the viscosity of the mixture and produce an extrudate that is stiffer in a shorter time than it would be, absent the carbon dioxide, without increasing the extrusion pressure.
摘要:
An improvement in a process of making honeycomb articles, which process utilizes a co-rotating, intermeshing twin screw extrusion apparatus to mix, screen, and extrude a batch of ceramic materials through a die, the improvement which comprises the steps of separating the mixing and screening phase from the extrusion phase, by passing the batch through a first co-rotating, intermeshing twin screw extruder or a mixer extruder to mix and screen the batch, and then directly passing the mixed and screened batch through a second co-rotating, intermeshing twin screw extruder or a pumping extruder to extrude said batch through a die assembly to produce a honeycomb article.