公开(公告)号：US4541938A

公开(公告)日：1985-09-17

申请号：US594651

申请日：1984-03-28

申请人： Douglas S. Jack ,  James W. Garner

发明人： Douglas S. Jack ,  James W. Garner

IPC分类号： C07G99/00 ,  C10M159/24 ,  B01J10/00

CPC分类号： C10M159/24 ,  C07G17/008

摘要： A method and apparatus for the continuous overbasing of petroleum sulfonate providing in a process in which CO.sub.2 is contacted with a reaction mixture of neutral petroleum sulfonate, lube oil stock, lime, methanol, and naphtha in a series of reaction vessels in which additional CO.sub.2 is contacted seriatim in each succeeding reaction vessel with the effluent from the preceding reaction vessel, a method and apparatus for the removal of at least a portion of the effluent from each reaction vessel with the reduction of water content in this portion and subsequent supplementing of methanol content in this portion to provide a reaction efficient amount of water and methanol in each succeeding reaction.

摘要翻译： 一种用于石油磺酸盐连续高碱性化的方法和装置，其提供了一种方法，其中CO 2与一系列反应容器中的中性石油磺酸盐，润滑油原料，石灰，甲醇和石脑油的反应混合物接触，其中附加的CO 2是 在每个后续反应容器中与来自前一反应容器的流出物接触，一种用于从每个反应容器中除去至少一部分流出物的方法和装置，其中该部分的水含量减少，随后补充甲醇含量 在该部分中，在每个后续反应中提供反应有效量的水和甲醇。

公开(公告)号：US4661318A

公开(公告)日：1987-04-28

申请号：US734714

申请日：1985-05-16

申请人： Douglas S. Jack ,  James W. Garner

发明人： Douglas S. Jack ,  James W. Garner

IPC分类号： C07G99/00 ,  C10M159/24 ,  B01J10/00 ,  B01F3/04

CPC分类号： C10M159/24 ,  C07G17/008 ,  Y10T436/12 ,  Y10T436/203332

摘要： A method and apparatus for the continuous overbasing of petroleum sulfonate providing in a process in which CO.sub.2 is contacted with a reaction mixture of neutral petroleum sulfonate, lube oil stock, lime, methanol, and naphtha in a series of reaction vessels in which additional CO.sub.2 is contacted seriatim in each succeeding reaction vessel with the effluent from the preceding reaction vessel, a method and apparatus for the removal of at least a portion of the effluent from each reaction vessel with the reduction of water content in this portion and subsequent supplementing of methanol content in this portion to provide a reaction efficient amount of water and methanol in each succeeding reaction.

摘要翻译： 一种用于石油磺酸盐连续高碱性化的方法和装置，其提供了一种方法，其中CO 2与一系列反应容器中的中性石油磺酸盐，润滑油原料，石灰，甲醇和石脑油的反应混合物接触，其中附加的CO 2是 在每个后续反应容器中与来自前一反应容器的流出物接触，一种用于从每个反应容器中除去至少一部分流出物的方法和装置，其中该部分的水含量减少，随后补充甲醇含量 在该部分中，在每个后续反应中提供反应有效量的水和甲醇。

公开(公告)号：US4039604A

公开(公告)日：1977-08-02

申请号：US605710

申请日：1975-08-18

申请人： John W. Myers ,  James W. Garner

发明人： John W. Myers ,  James W. Garner

IPC分类号： C07C5/22 ,  C07C5/27 ,  C07C5/30

CPC分类号： C07C5/226 ,  C07C5/2791 ,  C07C2521/04 ,  C07C2523/42 ,  Y10S585/951

摘要： In a process for isomerizing light hydrocarbons with a catalyst system comprising a halogenated alumina or platinum alumina when hydrogen is utilized to sustain the catalyst activity, the ratio of hydrogen to hydrocarbon in the feed is decreased and the temperature increased after a substantial period of operation. This results in an improved conversion and selectivity which allows for increasing the total catalyst life.

摘要翻译： 在使用氢气来维持催化剂活性的情况下，使用包含卤化氧化铝或铂氧化铝的催化剂体系使轻质烃异构化的方法中，进料中的氢与烃的比例降低，并且在相当长的操作时间之后温度升高。 这导致改进的转化率和选择性，这允许增加总的催化剂寿命。

公开(公告)号：US4333845A

公开(公告)日：1982-06-08

申请号：US185326

申请日：1980-09-08

申请人： James W. Garner

发明人： James W. Garner

IPC分类号： B01D53/34 ,  B05B15/12 ,  C09D7/00 ,  C09D9/00 ,  C11D7/50

CPC分类号： B01D53/34 ,  B05B15/1233 ,  C09D7/001 ,  Y02P70/36

摘要： Described is a method for decreasing the air pollution resulting from the application of paint by applying an organic solvent based paint and a water miscible organic solvent based thinner to a substrate thereby forming a gaseous effluent comprised of a mixture of air and gaseous organic solvent and gaseous thinner and passing the gaseous effluent into a gas absorbing means comprised of a non-reactive liquid solvent. Also described is a novel completely water miscible organic based solvent thinner.

摘要翻译： 描述了一种通过将基于有机溶剂的涂料和与水可混溶的有机溶剂基稀释剂施加到基材上从而施加涂料而导致的空气污染的方法，从而形成由空气和​​气体有机溶剂的混合物和气体 稀释并将气态流出物送入由非反应性液体溶剂组成的气体吸收装置中。 还描述了一种新型完全水溶性有机溶剂稀释剂。

公开(公告)号：US4265944A

公开(公告)日：1981-05-05

申请号：US932948

申请日：1978-08-11

申请人： James W. Garner

发明人： James W. Garner

IPC分类号： B01D53/34 ,  B05B15/12 ,  C09D7/00 ,  B05D3/00 ,  B01D47/00 ,  B01D47/05

CPC分类号： B05B15/1233 ,  B01D53/34 ,  C09D7/001 ,  Y02P70/36 ,  Y10S55/46

摘要： Described is a method for decreasing the air pollution resulting from the application of paint by applying an organic solvent based paint and a water miscible organic solvent based thinner to a substrate thereby forming a gaseous effluent comprised of a mixture of air and gaseous organic solvent and gaseous thinner and passing the gaseous effluent into a gas absorbing means comprised of a non-reactive liquid solvent. Also described is a novel completely water miscible organic based solvent thinner.

摘要翻译： 描述了一种通过将基于有机溶剂的涂料和与水可混溶的有机溶剂基稀释剂施加到基材上从而施加涂料而导致的空气污染的方法，从而形成由空气和​​气体有机溶剂的混合物和气体 稀释并将气态流出物送入由非反应性液体溶剂组成的气体吸收装置中。 还描述了一种新型完全水溶性有机溶剂稀释剂。

公开(公告)号：US4339248A

公开(公告)日：1982-07-13

申请号：US95337

申请日：1979-11-19

申请人： James W. Garner

发明人： James W. Garner

IPC分类号： B01D53/34 ,  B05B15/12 ,  B01D47/00

CPC分类号： B01D53/34 ,  B05B15/1233 ,  Y02P70/36 ,  Y10S55/46

摘要： Described is a process for the purification of gaseous effluent of industrial processes by providing a gas containing at least a hydrocarbon solvent and/or an oxygenated solvent and passing said gas into a gas absorbing means comprised of a nonreactive liquid solvent for said gas, said liquid solvent being liquid and substantially nonvolatile at ambient temperatures and pressures. Preferably, the liquid absorbing solvent is reclaimed by separating the gaseous effluent therefrom. The gaseous effluent is preferably that resulting from the application of paint.

摘要翻译： 描述了通过提供至少包含烃溶剂和/或氧化溶剂的气体并将所述气体传递到由用于所述气体的非反应性液体溶剂组成的气体吸收装置中来净化工业过程的气体流出物的方法，所述液体 溶剂是液体并且在环境温度和压力下基本上是非挥发性的。 优选地，通过从其中分离出气态流出物来回收液体吸收溶剂。 气态流出物优选是由涂料施用而产生的。

公开(公告)号：US4203875A

公开(公告)日：1980-05-20

申请号：US799179

申请日：1977-05-23

申请人： James W. Garner ,  Robert G. Kelso

发明人： James W. Garner ,  Robert G. Kelso

IPC分类号： C08G18/42 ,  C08G18/62 ,  C08G18/65 ,  C09D175/04 ,  C08L75/06

CPC分类号： C08G18/65 ,  C08G18/4277 ,  C08G18/6212 ,  C09D175/04

摘要： A method for applying a polyurethane coating onto a substrate by employing a catalyzed coating composition comprising the steps:(1) Providing a coating composition comprised of:(A) a polyol composition comprising (1) a polymerized low molecular weight polyol selected from the group consisting of (a) polycaprolactone; (b) a copolymer of a compound of the formula CH.sub.2 .dbd.C(R)--R.sup.1 and allyl alcohol; and (c) mixtures thereof; (2) a saturated aliphatic polyol from 4 to 12 carbon atoms or a saturated cycloaliphatic polyol of from 5 to 8 carbon atoms per ring; wherein R is methyl, ethyl or hydrogen; R.sup.1 is a group having 6 to 12 carbon atoms containing an aromatic carbocyclic ring;(B) a polyisocyanate; wherein the ratio of NCO/OH of A and B ranges from about 0.9 to 1.2; the coating composition having a range of solids content from about 40 to about 100% by weight; and(C) a compatible polyurethane catalyst;(2) Applying the coating composition to a substrate; and(3) Heating the coated substrate at a temperature-time range of from about 130.degree. F. to about 180.degree. F. for a period of time ranging from about 15 minutes to about 60 minutes to achieve a Tukon hardness of at least 3 within 24 hours.

摘要翻译： 一种通过使用催化涂层组合物将聚氨酯涂层施加到基材上的方法，包括以下步骤：（1）提供涂料组合物，其包含：（A）多元醇组合物，其包含（1）聚合的低分子量多元醇， 由（a）聚己内酯组成; （b）式CH 2 = C（R）-R1的化合物和烯丙醇的共聚物; 和（c）它们的混合物; （2）4-12个碳原子的饱和脂族多元醇或每个环碳原子数为5至8个碳原子的饱和脂环族多元醇; 其中R是甲基，乙基或氢; R1是含有芳香族碳环的碳原子数6〜12的基团。 （B）多异氰酸酯; 其中A和B的NCO / OH的比例在约0.9至1.2的范围内; 所述涂料组合物具有约40至约100重量％的固体含量范围; 和（C）相容的聚氨酯催化剂; （2）将涂料组合物涂布在基材上; 和（3）在约130°F至约180°F的温度 - 时间范围内加热涂覆的基材一段时间为约15分钟至约60分钟，以达到至少3的Tukon硬度 24小时内。

公开(公告)号：US4070509A

公开(公告)日：1978-01-24

申请号：US599833

申请日：1975-07-28

申请人： James W. Garner ,  Robert G. Kelso

发明人： James W. Garner ,  Robert G. Kelso

IPC分类号： C08G18/00 ,  C08G18/42 ,  C08G18/62 ,  C08G18/65 ,  C09D175/04 ,  C09D175/06 ,  B05D3/02 ,  B05D7/14 ,  B05D7/06 ,  B05D7/02

CPC分类号： C08G18/65 ,  C08G18/4277 ,  C08G18/6212 ,  C09D175/04

摘要： A method for applying a polyurethane coating onto a substrate by employing a catalyzed coating composition comprising the steps:1. Providing a coating composition comprised of:A. a polyol composition comprising (1) a polymerized low molecular weight polyol selected from the group consisting of (a) polycaprolactone; (b) a copolymer of a compound of the formula CH.sub.2 .dbd.C(R)--R.sup.1 and allyl alcohol; and (c) mixtures thereof; (2) a saturated aliphatic polyol from 4 to 12 carbon atoms or a saturated cycloaliphatic polyol of from 5 to 8 carbon atoms per ring; wherein R is methyl, ethyl or hydrogen; R.sup.1 is a group having 6 to 12 carbon atoms containing an aromatic carbocyclic ring;B. a polyisocyanate; wherein the ratio of NCO/OH of A and B ranges from about 0.9 to 1.2; the coating composition having a range of solids content from about 40 to about 100% by weight; andC. a compatible polyurethane catalyst;2. Applying the coating composition to a substrate; and3. Heating the coated substrate at a temperature-time range of from about 130.degree. F to about 180.degree. F for a period of time ranging from about 15 minutes to about 60 minutes to achieve a Tukon hardness of at least 3 within 24 hours.

摘要翻译： 一种通过使用催化涂层组合物将聚氨酯涂层施加到基底上的方法，包括以下步骤：