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公开(公告)号：US11896965B2
公开(公告)日：2024-02-13
申请号：US17966176
申请日：2022-10-14
发明人： Jerzy Klosin , Kara A. Milbrandt , Scott D. Boelter , David R. Wilson , Mari S. Rosen , Dean M. Welsh , Peter M. Margl , Kyoung Moo Koh , David M. Pearson , Rafael Huacuja
IPC分类号： B01J31/24 , B01J31/14 , B01J31/18 , C07C2/36 , C07F9/6568 , C07F9/6584 , C07F11/00 , C07F17/02 , C07F9/6571 , B01J31/22
CPC分类号： B01J31/2433 , B01J31/143 , B01J31/188 , B01J31/2208 , B01J31/2438 , B01J31/2457 , B01J31/2476 , B01J31/2495 , C07C2/36 , C07F9/6568 , C07F9/6571 , C07F9/65683 , C07F9/65685 , C07F9/65842 , C07F9/65844 , C07F9/65846 , C07F9/65848 , C07F9/657154 , C07F11/005 , C07F17/02 , B01J2231/20 , B01J2531/62 , B01J2540/10 , B01J2540/22 , B01J2540/225 , B01J2540/30 , B01J2540/34 , B01J2540/444 , C07C2531/14 , C07C2531/18 , C07C2531/24 , C07C2/36 , C07C11/02 , C07C2/36 , C07C11/107
摘要： The invention relates to oligomerization of olefins, such as ethylene, to higher olefins, such as a mixture of 1-hexene and 1-octene, using a catalyst system that comprises a) a source of chromium b) one or more activators and c) a phosphacycle-containing ligating compound. Additionally, the invention relates to a phosphacycle-containing ligating compound and a process for making said compound.
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公开(公告)号：US20220033565A1
公开(公告)日：2022-02-03
申请号：US17277416
申请日：2019-09-17
发明人： Kshitish A. Patankar , Arjun Raghuraman , Thomas P. Willumstad , Mark F. Sonnenschein , Jody Henning , Heather A. Spinney , David R. Wilson , Sukrit Mukhopadhyay , William H. Heath
摘要： Polyurethanes are made in a one-shot process from one or more polyols having a hydroxyl equivalent weight of at least 350, wherein at least 50% of the weight of iii) is a hydroxyl-containing polymer of propylene oxide, the hydroxyl-containing polymer of propylene oxide having a hydroxyl equivalent weight of at least 350, an average of 1.8 to 3 hydroxyl groups per molecule of which hydroxyl groups 40 to 70% are primary hydroxyl groups, an oxyethylene content of no greater than 10% by weight based on the weight of the polymer and a polydispersity of 1.175 or less. The polyurethanes exhibit excellent mechanical properties, are highly hygroscopic and cured rapidly.
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公开(公告)号：US20210032382A1
公开(公告)日：2021-02-04
申请号：US17043304
申请日：2019-03-26
发明人： Richard J. Keaton , Rafael Huacuja , David R. Wilson , Jerzy Klosin , David M. Pearson , Todd D. Senecal , Sukrit Mukhopadhyay , William H.H. Woodward
IPC分类号： C08F210/16
摘要： Embodiments of this disclosure include processes of polymerizing olefins, the process comprising contacting ethylene and a (C3-C40)alpha-olefin comonomer in the presence of a catalyst system, the catalyst system comprising a Group IV metal-ligand complex and an ionic metallic activator complex, the ionic metallic activator complex comprising an anion and a countercation, the anion having a structure according to formula (I):formula (I)
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公开(公告)号：US20200231738A1
公开(公告)日：2020-07-23
申请号：US16644284
申请日：2018-09-14
发明人： Arjun Raghuraman , William H. Heath , Sukrit Mukhopadhyay , Heather A. Spinney , David R. Wilson , Anthony P. Gies , Manjiri R. Paradkar , Justin M. Notestein , SonBinh T. Nguyen
摘要： A method of producing a polyether polyol that includes reacting a low molecular weight initiator with one or more monomers in the presence of a polymerization catalyst, the low molecular weight initiator having a number average molecular weight of less than 1,000 g/mol and a nominal hydroxyl functionality at least 2, the one or more monomers including at least one selected from propylene oxide and butylene oxide, and the polymerization catalyst being a Lewis acid catalyst having the general formula M(R1)1(R2)1(R3)1(R4)0 or 1. Whereas, M is boron, aluminum, indium, bismuth or erbium, R1, R2, and R3 each includes a same fluoroalkyl-substituted phenyl group, and optional R4 includes a functional group or functional polymer group. The method further includes forming a polyether polyol having a number average molecular weight of greater than the number average molecular weight of the low molecular weight initiator in the presence of the Lewis acid catalyst.
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公开(公告)号：US20180291048A1
公开(公告)日：2018-10-11
申请号：US15557875
申请日：2016-03-10
发明人： Jerzy Klosin , Kara A. Milbrandt , Scott D. Boelter , David R. Wilson , Mari S. Rosen , Dean M. Welsh , Peter M. Margl , Kyoung Moo Koh , David M. Pearson , Rafael Huacuja
IPC分类号： C07F9/6568
CPC分类号： B01J31/2433 , B01J31/143 , B01J31/188 , B01J31/2208 , B01J31/2438 , B01J31/2457 , B01J31/2476 , B01J31/2495 , B01J2231/20 , B01J2531/62 , B01J2540/10 , B01J2540/22 , B01J2540/225 , B01J2540/30 , B01J2540/34 , B01J2540/444 , C07C2/36 , C07C2531/14 , C07C2531/18 , C07C2531/24 , C07F9/6568 , C07F9/65683 , C07F9/65685 , C07F9/6571 , C07F9/657154 , C07F9/65842 , C07F9/65844 , C07F9/65846 , C07F9/65848 , C07F11/005 , C07F17/02 , C07C11/02 , C07C11/107
摘要： The invention relates to oligomerization of olefins, such as ethylene, to higher olefins, such as a mixture of 1-hexene and 1-octene, using a catalyst system that comprises a) a source of chromium b) one or more activators and c) a phosphacycle-containing ligating compound. Additionally, the invention relates to a phosphacycle-containing ligating compound and a process for making said compound.
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公开(公告)号：US08765877B2
公开(公告)日：2014-07-01
申请号：US13667153
申请日：2012-11-02
CPC分类号： C08F2/38 , C08F10/00 , C08F10/14 , H01M2/1653 , H01M10/0525 , H01M10/4235 , C08F4/64113
摘要： The invention generally relates to chain shuttling agents (CSAs), a process of preparing the CSAs, a composition comprising a CSA and a catalyst, a process of preparing the composition, a processes of preparing polyolefins, end functional polyolefins, and telechelic polyolefins with the composition, and the polyolefins, end functional polyolefins, and telechelic polyolefins prepared by the processes.
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公开(公告)号：US20130072707A1
公开(公告)日：2013-03-21
申请号：US13667119
申请日：2012-11-02
IPC分类号： C07F5/06
CPC分类号： C08F2/38 , C08F10/00 , C08F10/14 , H01M2/1653 , H01M10/0525 , H01M10/4235 , C08F4/64113
摘要： The invention generally relates to chain shuttling agents (CSAs), a process of preparing the CSAs, a composition comprising a CSA and a catalyst, a process of preparing the composition, a processes of preparing polyolefins, end functional polyolefins, and telechelic polyolefins with the composition, and the polyolefins, end functional polyolefins, and telechelic polyolefins prepared by the processes.
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公开(公告)号：US11993675B2
公开(公告)日：2024-05-28
申请号：US17433045
申请日：2020-02-14
发明人： Mihir Bhagat , Charmaine Bennett , Youlong Zhu , SonBinh T. Nguyen , Linda Broadbelt , Justin M. Notestein , Matthew E. Belowich , Arjun Raghuraman , William H. Heath , Sukrit Mukhopadhyay , Heather A. Spinney , David R. Wilson
CPC分类号： C08G18/48 , C08G18/10 , C08G65/005 , C08G65/2609 , C08G65/2654 , C08G65/266
摘要： A method of producing a polyether alcohol that includes feeding an initiator into a reactor, feeding one or more monomers into the reactor, feeding a polymerization catalyst into the reactor, the polymerization catalyst being a Lewis acid catalyst having a general formula M(R1)1(R2)1(R3)1(R4)0 or 1, separate from feeding the initiator into the reactor, feeding a hydrogen bond acceptor additive into the reactor, the hydrogen bond acceptor additive being a C2 to C20 organic molecule having at least two hydroxyl groups, of which two hydroxyl groups are situated in 1,2-, 1,3-, or 1,4-positions on the organic molecule, and allowing the initiator to react with the one or more monomers in the presence of the polymerization catalyst and the hydrogen bond acceptor additive to form a polyether alcohol having a number average molecular weight greater than a number average molecular weight of the initiator.
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公开(公告)号：US11970574B2
公开(公告)日：2024-04-30
申请号：US16646060
申请日：2018-09-14
发明人： Arjun Raghuraman , William H. Heath , Bruce D. Hook , Wanglin Yu , Sukrit Mukhopadhyay , Heather A. Spinney , David R. Wilson
CPC分类号： C08G65/2654 , C07F5/027 , C08G18/48 , C08G18/4841 , C08G18/4854 , C08G18/7621 , C08G18/7671 , C08G65/266 , C08G65/2684 , C08G2650/22 , C08G2650/38 , C08G2650/44 , C10M107/34 , C11D1/72
摘要： A method of producing an alcohol ethoxylate surfactant or lubricant, the method including reacting a low molecular weight initiator with ethylene oxide in the presence of a polymerization catalyst, the low molecular weight initiator having a nominal hydroxyl functionality at least 1, and the polymerization catalyst being a Lewis acid catalyst having the general formula M(R1)I(R2)I(R3)I(R4)0 or 1, whereas M is boron, aluminum, indium, bismuth or erbium, R1, R2, R3, and R4 are each independent, R1 includes a first fluoroalkyl-substituted phenyl group, R2 includes a second fluoroalkyl-substituted phenyl group or a first fluoro/chloro-substituted phenyl group, R3 includes a third fluoroalkyl-substituted phenyl group or a second fluoro/chloro-substituted phenyl group, and optional R4 includes a functional group or functional polymer group, R1 being different from at least one of R2 and R3. The method further including forming an alcohol ethoxylate surfactant or lubricant having a number average molecular weight of greater than the number average molecular weight of the low molecular weight initiator in the presence of the Lewis acid catalyst.
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公开(公告)号：US11542350B2
公开(公告)日：2023-01-03
申请号：US17043154
申请日：2019-03-22
发明人： Richard J. Keaton , Rafael Huacuja , David R. Wilson , Jerzy Klosin , David M. Pearson , Todd D. Senecal , Sukrit Mukhopadhyay , William H. H. Woodward
摘要： Embodiments of the disclosure include processes of polymerizing olefins. The process includes contacting ethylene and a (C3-C40)alpha-olefin comonomer in the presences of a catalyst system. The catalyst system comprises a procatalyst and a bimetallic activator complex. The bimetallic activator complex comprises an anion and a countercation, and the anion has a structure according to formula (I).
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