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公开(公告)号：US11104791B2
公开(公告)日：2021-08-31
申请号：US15517264
申请日：2015-10-01
Applicant: Dow Global Technologies LLC
Inventor： Robert R. Bills , Patricia A. Peart , Christian Piechocki , Jay D. Romick , Jamie L. Sullivan
Abstract: An epoxy functionalized surfactant composition including a reaction product of: (a) a hydrophilic material and (b) an epoxy resin hydrophobe material having an average molecular weight of greater than about 370 Daltons; the above epoxy functionalized surfactant composition being used to prepare a waterborne epoxy dispersion composition including (A) the above epoxy functionalized surfactant composition, (B) an epoxy resin, and (C) water; and processes for preparing the epoxy functionalized surfactant composition and the above waterborne epoxy dispersion composition.
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Patent Agency Ranking
公开(公告)号：US11447600B2
公开(公告)日：2022-09-20
申请号：US16092458
申请日：2017-05-01
Applicant: Dow Global Technologies LLC
Inventor： Robert R. Bills , Liang Chen , David L. Malotky , Jay D. Romick
IPC: C08G59/42 , C09D7/48 , C09D163/00 , C09D123/26 , B01F23/41
Abstract: The present invention provides aqueous compositions for making damage tolerant coatings comprising a blend of (i) from 2 to 30 wt. %, based on the total weight of solids in the composition, of an acid or anhydride functionalized polyolefin dispersion having an average particle size of from 0.2 to 5 microns, and (ii) a film forming dispersion of one or more epoxy resins chosen from epoxy resins having an epoxy equivalent weight (EEW) of from 150 to 4,000 having an average particle size of from 0.2 to 1.0 microns, wherein the polyolefin dispersion is stabilized with from 2 to 8 wt. %, based on the total weight of solids in the composition, one or more anionic surfactants, such as a sulfate containing surfactant, and, further wherein, the compositions have a pH of from 3 to 8.
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公开(公告)号：US20170306142A1
公开(公告)日：2017-10-26
申请号：US15517264
申请日：2015-10-01
Applicant: Dow Global Technologies LLC
Inventor： Robert R. Bills , Patricia A. Peart , Christian Piechocki , Jay D. Romick , Jamie L. Sullivan
IPC: C08L63/00
CPC classification number: C08L63/00 , C08G59/066 , C08G59/245 , C08L71/02
Abstract: An epoxy functionalized surfactant composition including a reaction product of: (a) a hydrophilic material and (b) an epoxy resin hydrophobe material having an average molecular weight of greater than about 370 Daltons; the above epoxy functionalized surfactant composition being used to prepare a waterborne epoxy dispersion composition including (A) the above epoxy functionalized surfactant composition, (B) an epoxy resin, and (C) water; and processes for preparing the epoxy functionalized surfactant composition and the above waterborne epoxy dispersion composition.
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公开(公告)号：US12173452B2
公开(公告)日：2024-12-24
申请号：US17917684
申请日：2021-04-15
Applicant: Dow Global Technologies LLC
Inventor： Alan M. Piwowar , Ray E. Drumright , Christina N. Ellison , David L. Malotky , Jonathan F. Mason , Hari Katepalli , Luqing Qi , Houxiang Tang , Robert R. Bills
Abstract: The present invention relates to an article and a method for its preparation; the article comprises a cured polymeric film superposing paper or paperboard. The polymeric film is derived from a dispersion which comprises: a) a dispersant which is a copolymer with an acid value of 130 or less, comprising structural units of ethylene and a carboxylic acid monomer, wherein the copolymer has a melt flow index in the range of from 50 to 2000 g/10 min at 190° C./2.16 kg; wherein the weight-to-weight ratio of structural units of ethylene to carboxylic acid monomer is in the range of from 95:5 to 70:30; and wherein the dispersant has a concentration in the range of from 9 to 50 weight percent based on the weight of polymer solids in the dispersion; b) a base polymer comprising non-functionalized ethylene-co-alkene copolymers, wherein the weight-to-weight ratio of the structural units of ethylene to alkene is in the range of from 99.8:0.2 to 50:50; and c) a neutralizing agent which is a hard base and excludes an organic base having a boiling point of less than 250° C.; wherein the concentration of the neutralizing agent is sufficient to neutralize at least half of the carboxylic acid groups associated with the dispersion composition. The article of the present invention is useful as a barrier to a wide range of hydrophobic and hydrophilic materials.
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公开(公告)号：US20230151549A1
公开(公告)日：2023-05-18
申请号：US17917684
申请日：2021-04-15
Applicant: Dow Global Technologies LLC
Inventor： Alan M. Piwowar , Ray E. Drumright , Christina N. Ellison , David L. Malotky , Jonathan F. Mason , Hari Katepalli , Luqing Qi , Houxiang Tang , Robert R. Bills
Abstract: The present invention relates to an article and a method for its preparation; the article comprises a cured polymeric film superposing paper or paperboard. The polymeric film is derived from a dispersion which comprises:
a) a dispersant which is a copolymer with an acid value of 130 or less, comprising structural units of ethylene and a carboxylic acid monomer, wherein the copolymer has a melt flow index in the range of from 50 to 2000 g/10 min at 190° C./2.16 kg; wherein the weight-to-weight ratio of structural units of ethylene to carboxylic acid monomer is in the range of from 95:5 to 70:30; and wherein the dispersant has a concentration in the range of from 9 to 50 weight percent based on the weight of polymer solids in the dispersion;
b) a base polymer comprising non-functionalized ethylene-co-alkene copolymers, wherein the weight-to-weight ratio of the structural units of ethylene to alkene is in the range of from 99.8:0.2 to 50:50; and
c) a neutralizing agent which is a hard base and excludes an organic base having a boiling point of less than 250° C.; wherein the concentration of the neutralizing agent is sufficient to neutralize at least half of the carboxylic acid groups associated with the dispersion composition.
The article of the present invention is useful as a barrier to a wide range of hydrophobic and hydrophilic materials.-
公开(公告)号：US20210301073A1
公开(公告)日：2021-09-30
申请号：US16092458
申请日：2017-11-09
Applicant: Dow Global Technologies LLC
Inventor： Robert R. Bills , Liang Chen , David L. Malotky , Jay D. Romick
IPC: C08G59/42 , C09D163/00 , C09D7/48
Abstract: The present invention provides aqueous compositions for making damage tolerant coatings comprising a blend of (i) from 2 to 30 wt. %, based on the total weight of solids in the composition, of an acid or anhydride functionalized polyolefin dispersion having an average particle size of from 0.2 to 5 microns, and (ii) a film forming dispersion of one or more epoxy resins chosen from epoxy resins having an epoxy equivalent weight (EEW) of from 150 to 4,000 having an average particle size of from 0.2 to 1.0 microns, wherein the polyolefin dispersion is stabilized with from 2 to 8 wt. %, based on the total weight of solids in the composition, one or more anionic surfactants, such as a sulfate containing surfactant, and, further wherein, the compositions have a pH of from 3 to 8.
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