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公开(公告)号:US11180385B2
公开(公告)日:2021-11-23
申请号:US15867616
申请日:2018-01-10
Applicant: Ecolab USA Inc.
Inventor: Junzhong Li , David McSherry , Allison Brewster , Richard Staub , Renato De Paula , John Wilhelm Bolduc , Robert J. Ryther , Victor V. Keasler
IPC: C02F1/40 , C11D3/39 , A01N25/22 , C02F1/72 , C02F1/68 , C11D7/32 , C11D7/36 , C02F1/50 , C11D7/04 , C11D7/26 , C02F103/00 , C02F103/02 , C02F103/42 , C02F103/10 , C02F101/32
Abstract: The present invention relates generally to stable percarboxylic acid compositions comprising, inter alia, at least two stabilizing agents, and various uses for water treatments, including water treatments in connection with oil- and gas-field operations. The present invention also relates to slick water compositions and gel based compositions that comprise stable percarboxylic acid compositions and the use thereof in oil- and gas-field operations.
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公开(公告)号:US20140273244A1
公开(公告)日:2014-09-18
申请号:US13838409
申请日:2013-03-15
Applicant: ECOLAB USA INC.
Inventor: John Wilhelm Bolduc , Blake Roberts Otting , Paul R. Kraus , Robert Ryther
IPC: G01N21/80
CPC classification number: G01N21/79 , G01N31/16 , Y10T436/115831 , Y10T436/116664 , Y10T436/12 , Y10T436/206664
Abstract: A system and method for performing automated titrations. An automatic titrator utilizes control devices and sensors adapted for various chemical reactions to perform titrations and determine the content of a desired component of a solution. Batch and continuous mode titrations are possible. Titrant is added to a sample either in varying amounts or rates and a titration endpoint is observed via sensors. Control devices detect when the titration endpoint occurs and calculates the desired content. Various reactions within the solution may be suppressed in order to titrate isolated components individually.
Abstract translation: 用于执行自动滴定的系统和方法。 自动滴定仪利用适于各种化学反应的控制装置和传感器来进行滴定并确定溶液的所需组分的含量。 批量和连续模式滴定是可能的。 将滴定剂以不同的量或速率添加到样品中,并通过传感器观察滴定终点。 控制装置检测何时出现滴定终点并计算所需内容。 可以抑制溶液中的各种反应,以分别滴定分离的组分。
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公开(公告)号:US10107756B2
公开(公告)日:2018-10-23
申请号:US14993960
申请日:2016-01-12
Applicant: Ecolab USA, Inc.
Inventor: John Wilhelm Bolduc , Eugene Tokhtuev , Anatoly Skirda , Anna Pilipchenko , Justin Scott Valenstein , Amanda Bakken , Stacy Fawbush , Jeffrey S. Hutchison
Abstract: A method of fluorometrically detecting the concentration of chemical components in oxidizing formulations is disclosed. In a particular embodiment the detection is of the stabilizing component of picolinic acid, present in such formulations, although any component which fluoresces may be detected. According to the invention sample preparation of the oxidizing formulation includes adding to said sample an excess of reducing agent to bind peracid, and in the case of picolinic acid, adding to said sample an excess of terbium chloride. The sample then is subjected to radiation to induce fluorescence and the concentration of said chemical component is determined by a linear relationship between fluorescence emitted and the concentration of the target chemical.
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公开(公告)号:US09321664B2
公开(公告)日:2016-04-26
申请号:US13844515
申请日:2013-03-15
Applicant: Ecolab USA Inc.
Inventor: Junzhong Li , David McSherry , Allison Brewster , Richard Staub , Renato De Paula , John Wilhelm Bolduc , Robert J. Ryther , Victor V. Keasler
IPC: C07C227/40 , C02F1/68 , C11D7/32 , C11D7/36 , C11D3/39 , A01N25/22 , C02F1/72 , C02F103/10 , C02F103/00 , C02F103/02 , C02F103/42
CPC classification number: C02F1/40 , A01N25/22 , C02F1/50 , C02F1/68 , C02F1/682 , C02F1/722 , C02F2101/32 , C02F2103/007 , C02F2103/023 , C02F2103/10 , C02F2103/42 , C02F2303/02 , C02F2303/04 , C02F2305/023 , C11D3/394 , C11D7/04 , C11D7/265 , C11D7/3281 , C11D7/36 , A01N37/16 , A01N59/00
Abstract: The present invention relates generally to stable percarboxylic acid compositions comprising, inter alia, at least two stabilizing agents, and various uses for water treatments, including water treatments in connection with oil- and gas-field operations. The present invention also relates to slick water compositions and gel based compositions that comprise stable percarboxylic acid compositions and the use thereof in oil- and gas-field operations.
Abstract translation: 本发明一般涉及稳定的过羧酸组合物,其特别包括至少两种稳定剂,以及用于水处理的各种用途,包括与油气田操作有关的水处理。 本发明还涉及包含稳定的过羧酸组合物的光滑水组合物和基于凝胶的组合物,以及其在油田和气田操作中的用途。
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公开(公告)号:US08980636B2
公开(公告)日:2015-03-17
申请号:US13838409
申请日:2013-03-15
Applicant: Ecolab USA Inc.
Inventor: John Wilhelm Bolduc , Blake Roberts Otting , Paul R. Kraus , Robert Ryther
CPC classification number: G01N21/79 , G01N31/16 , Y10T436/115831 , Y10T436/116664 , Y10T436/12 , Y10T436/206664
Abstract: A system and method for performing automated titrations. An automatic titrator utilizes control devices and sensors adapted for various chemical reactions to perform titrations and determine the content of a desired component of a solution. Batch and continuous mode titrations are possible. Titrant is added to a sample either in varying amounts or rates and a titration endpoint is observed via sensors. Control devices detect when the titration endpoint occurs and calculates the desired content. Various reactions within the solution may be suppressed in order to titrate isolated components individually.
Abstract translation: 用于执行自动滴定的系统和方法。 自动滴定仪利用适于各种化学反应的控制装置和传感器来进行滴定并确定溶液的所需组分的含量。 批量和连续模式滴定是可能的。 将滴定剂以不同的量或速率添加到样品中,并通过传感器观察滴定终点。 控制装置检测何时出现滴定终点并计算所需内容。 可以抑制溶液中的各种反应,以分别滴定分离的组分。
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公开(公告)号:US20240182328A1
公开(公告)日:2024-06-06
申请号:US18440760
申请日:2024-02-13
Applicant: ECOLAB USA INC.
Inventor: Junzhong Li , David McSherry , Allison Brewster , Richard Staub , Renato De Paula , John Wilhelm Bolduc , Robert J. Ryther , Victor V. Keasler
IPC: C02F1/40 , A01N25/22 , C02F1/50 , C02F1/68 , C02F1/72 , C02F101/32 , C02F103/00 , C02F103/02 , C02F103/10 , C02F103/42 , C11D3/39 , C11D7/04 , C11D7/26 , C11D7/32 , C11D7/36
CPC classification number: C02F1/40 , A01N25/22 , C02F1/50 , C02F1/68 , C02F1/682 , C02F1/722 , C11D3/394 , C11D7/04 , C11D7/265 , C11D7/3281 , C11D7/36 , C02F2101/32 , C02F2103/007 , C02F2103/023 , C02F2103/10 , C02F2103/42 , C02F2303/02 , C02F2303/04 , C02F2305/023
Abstract: The present invention relates generally to stable percarboxylic acid compositions comprising, inter alia, at least two stabilizing agents, and various uses for water treatments, including water treatments in connection with oil- and gas-field operations. The present invention also relates to slick water compositions and gel based compositions that comprise stable percarboxylic acid compositions and the use thereof in oil- and gas-field operations.
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公开(公告)号:US10254224B2
公开(公告)日:2019-04-09
申请号:US14970573
申请日:2015-12-16
Applicant: Ecolab USA Inc.
Inventor: John Wilhelm Bolduc , Justin Scott Valenstein , Amanda Bakken , Stacy Fawbush , Jeffrey Hutchison , Eugene Tokhtuev , Anatoly Skirda , Anna Pilipchenko
Abstract: A method of detecting concentration of dipicolinic acid and terbium chloride in a chemical composition with a fluorometer, wherein the fluorometer comprises an excitation source for emitting electromagnetic radiation at one or more wavelengths, and a detector module for detecting fluorescence emitted by dipicolinic acid, emitting electromagnetic radiation from the excitation source at wavelengths that induce fluorescence in dipicolinic acid-terbium chloride combination present in the chemical composition, detecting the fluorescence emitted by the dipicolinic acid-terbium chloride combination via the detector module, and determining the concentration of dipicolinic acid using predetermined relationship between fluorescence emitted and the concentration of dipicolinic acid-terbium chloride combination.
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公开(公告)号:US09261459B1
公开(公告)日:2016-02-16
申请号:US14457573
申请日:2014-08-12
Applicant: Ecolab USA Inc.
Inventor: Eugene Tokhtuev , Anatoly Skirda , Anna Pilipchenko , John Wilhelm Bolduc , Justin Scott Valenstein
IPC: G01N21/64
CPC classification number: G01N21/645 , G01N21/6428 , G01N21/6486 , G01N21/8507 , G01N21/8806 , G01N2021/6471 , G01N2201/068
Abstract: A fluorometer for measuring fluorescence of a sample includes an excitation source for emitting electromagnetic radiation along a first beam path to induce fluorescence in the sample. An excitation filter transmits electromagnetic radiation from the excitation source toward the sample. An excitation filter holder supports the excitation filter and defines an aperture for passage of electromagnetic radiation from the excitation source. The aperture is positioned asymmetrically relative to the first beam path such that the aperture allows an asymmetrical portion of the electromagnetic radiation in the first beam path to pass toward the sample and the excitation filter holder blocks passage of a corresponding asymmetrical portion of the electromagnetic radiation in the first beam path. The blocked passage of the corresponding asymmetrical portion of the electromagnetic radiation in the first beam path reduces the amount of electromagnetic radiation oriented directly from the emitter module to the detector module.
Abstract translation: 用于测量样品荧光的荧光计包括用于沿着第一光束路径发射电磁辐射以在样品中诱导荧光的激发源。 激发滤波器将来自激发源的电磁辐射传递给样品。 激励过滤器保持器支撑激励过滤器并且限定用于来自激发源的电磁辐射通过的孔。 孔径相对于第一光束路径不对称地定位,使得孔口允许第一光束路径中的电磁辐射的不对称部分朝向样品传递,并且激发滤光器保持器阻止电磁辐射的对应不对称部分的通过 第一个光束路径。 第一光束路径中电磁辐射的对应不对称部分的阻挡通道减少了从发射器模块直接定向到检测器模块的电磁辐射量。
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公开(公告)号:US11939241B2
公开(公告)日:2024-03-26
申请号:US17507772
申请日:2021-10-21
Applicant: Ecolab USA Inc.
Inventor: Junzhong Li , David McSherry , Allison Brewster , Richard Staub , Renato De Paula , John Wilhelm Bolduc , Robert J. Ryther , Victor V. Keasler
IPC: C02F1/40 , A01N25/22 , C02F1/50 , C02F1/68 , C02F1/72 , C11D3/39 , C11D7/04 , C11D7/26 , C11D7/32 , C11D7/36 , C02F101/32 , C02F103/00 , C02F103/02 , C02F103/10 , C02F103/42
CPC classification number: C02F1/40 , A01N25/22 , C02F1/50 , C02F1/68 , C02F1/682 , C02F1/722 , C11D3/394 , C11D7/04 , C11D7/265 , C11D7/3281 , C11D7/36 , C02F2101/32 , C02F2103/007 , C02F2103/023 , C02F2103/10 , C02F2103/42 , C02F2303/02 , C02F2303/04 , C02F2305/023 , A01N25/22 , A01N37/16 , A01N59/00
Abstract: The present invention relates generally to stable percarboxylic acid compositions comprising, inter alia, at least two stabilizing agents, and various uses for water treatments, including water treatments in connection with oil- and gas-field operations. The present invention also relates to slick water compositions and gel based compositions that comprise stable percarboxylic acid compositions and the use thereof in oil- and gas-field operations.
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公开(公告)号:US11454619B2
公开(公告)日:2022-09-27
申请号:US16378714
申请日:2019-04-09
Applicant: Ecolab USA Inc.
Inventor: Paul R. Kraus , John Wilhelm Bolduc , Robert J. Ryther
Abstract: Systems for quantifying one or more target analyte concentrations in a process solution are provided and can be used, for example, in methods for quantifying a target analyte concentration. These systems and methods include continuous and batchwise automated titration methods that use titration chemistries to measure the target analyte concentration in the process solution using a multiwavelength detector. The methods provide for efficient and robust automated titration methods for a variety of target analytes and can include methods that analyze more than one analyte and that provide for a dynamic range for measurement of more than one target analyte concentration.
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