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公开(公告)号:US10254224B2
公开(公告)日:2019-04-09
申请号:US14970573
申请日:2015-12-16
Applicant: Ecolab USA Inc.
Inventor: John Wilhelm Bolduc , Justin Scott Valenstein , Amanda Bakken , Stacy Fawbush , Jeffrey Hutchison , Eugene Tokhtuev , Anatoly Skirda , Anna Pilipchenko
Abstract: A method of detecting concentration of dipicolinic acid and terbium chloride in a chemical composition with a fluorometer, wherein the fluorometer comprises an excitation source for emitting electromagnetic radiation at one or more wavelengths, and a detector module for detecting fluorescence emitted by dipicolinic acid, emitting electromagnetic radiation from the excitation source at wavelengths that induce fluorescence in dipicolinic acid-terbium chloride combination present in the chemical composition, detecting the fluorescence emitted by the dipicolinic acid-terbium chloride combination via the detector module, and determining the concentration of dipicolinic acid using predetermined relationship between fluorescence emitted and the concentration of dipicolinic acid-terbium chloride combination.
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公开(公告)号:US09261459B1
公开(公告)日:2016-02-16
申请号:US14457573
申请日:2014-08-12
Applicant: Ecolab USA Inc.
Inventor: Eugene Tokhtuev , Anatoly Skirda , Anna Pilipchenko , John Wilhelm Bolduc , Justin Scott Valenstein
IPC: G01N21/64
CPC classification number: G01N21/645 , G01N21/6428 , G01N21/6486 , G01N21/8507 , G01N21/8806 , G01N2021/6471 , G01N2201/068
Abstract: A fluorometer for measuring fluorescence of a sample includes an excitation source for emitting electromagnetic radiation along a first beam path to induce fluorescence in the sample. An excitation filter transmits electromagnetic radiation from the excitation source toward the sample. An excitation filter holder supports the excitation filter and defines an aperture for passage of electromagnetic radiation from the excitation source. The aperture is positioned asymmetrically relative to the first beam path such that the aperture allows an asymmetrical portion of the electromagnetic radiation in the first beam path to pass toward the sample and the excitation filter holder blocks passage of a corresponding asymmetrical portion of the electromagnetic radiation in the first beam path. The blocked passage of the corresponding asymmetrical portion of the electromagnetic radiation in the first beam path reduces the amount of electromagnetic radiation oriented directly from the emitter module to the detector module.
Abstract translation: 用于测量样品荧光的荧光计包括用于沿着第一光束路径发射电磁辐射以在样品中诱导荧光的激发源。 激发滤波器将来自激发源的电磁辐射传递给样品。 激励过滤器保持器支撑激励过滤器并且限定用于来自激发源的电磁辐射通过的孔。 孔径相对于第一光束路径不对称地定位,使得孔口允许第一光束路径中的电磁辐射的不对称部分朝向样品传递,并且激发滤光器保持器阻止电磁辐射的对应不对称部分的通过 第一个光束路径。 第一光束路径中电磁辐射的对应不对称部分的阻挡通道减少了从发射器模块直接定向到检测器模块的电磁辐射量。
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公开(公告)号:US20170199124A1
公开(公告)日:2017-07-13
申请号:US14993960
申请日:2016-01-12
Applicant: Ecolab USA, Inc.
Inventor: John Wilhelm Bolduc , Eugene Tokhtuev , Anatoly Skirda , Anna Pilipchenko , Justin Scott Valenstein , Amanda Bakken , Stacy Fawbush , Jeffrey S. Hutchison
IPC: G01N21/64
CPC classification number: G01N21/643
Abstract: A method of fluorometrically detecting the concentration of chemical components in oxidizing formulations is disclosed. In a particular embodiment the detection is of the stabilizing component of picolinic acid, present in such formulations, although any component which fluoresces may be detected. According to the invention sample preparation of the oxidizing formulation includes adding to said sample an excess of reducing agent to bind peracid, and in the case of picolinic acid, adding to said sample an excess of terbium chloride. The sample then is subjected to radiation to induce fluorescence and the concentration of said chemical component is determined by a linear relationship between fluorescence emitted and the concentration of the target chemical.
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公开(公告)号:US09441998B2
公开(公告)日:2016-09-13
申请号:US14336921
申请日:2014-07-21
Applicant: Ecolab USA Inc.
Inventor: Anna Pilipchenko , William M. Christensen , Eugene Tokhtuev
Abstract: Embodiments include a flow measuring system for measuring characteristics of a fluid flow. The flow measuring system can include a pair of rotating members rotating synchronously to the fluid flow. At least one rotating member can include a normally-reflecting portion and a non-normally reflecting portion. The normally-reflecting portion reflects an incident beam in a direction parallel to the normal direction of the plane of the normally-reflecting portion. The non-normally reflecting portion reflects the incident beam in a direction non-parallel to the normal direction of the plane of the normally-reflecting portion. The flow measuring system measures the optical characteristics of a beam reflected by the normally-reflecting portion and determines rotational characteristics of the rotating member. The flow measuring system determines characteristics of the flow based on the rotational characteristics of the rotating member.
Abstract translation: 实施例包括用于测量流体流动特性的流量测量系统。 流量测量系统可以包括与流体流同步旋转的一对旋转构件。 至少一个旋转构件可以包括正常反射部分和非正常反射部分。 正反射部分在与正常反射部分的平面的法线方向平行的方向上反射入射光束。 非正常反射部分在与正常反射部分的平面的法线方向不平行的方向上反射入射光束。 流量测量系统测量由正反射部分反射的光束的光学特性,并确定旋转部件的旋转特性。 流量测量系统基于旋转构件的旋转特性确定流动的特性。
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公开(公告)号:US20160018247A1
公开(公告)日:2016-01-21
申请号:US14336921
申请日:2014-07-21
Applicant: Ecolab USA Inc.
Inventor: Anna Pilipchenko , William M. Christensen , Eugene Tokhtuev
IPC: G01F3/10
Abstract: Embodiments include a flow measuring system for measuring characteristics of a fluid flow. The flow measuring system can include a pair of rotating members rotating synchronously to the fluid flow. At least one rotating member can include a normally-reflecting portion and a non-normally reflecting portion. The normally-reflecting portion reflects an incident beam in a direction parallel to the normal direction of the plane of the normally-reflecting portion. The non-normally reflecting portion reflects the incident beam in a direction non-parallel to the normal direction of the plane of the normally-reflecting portion. The flow measuring system measures the optical characteristics of a beam reflected by the normally-reflecting portion and determines rotational characteristics of the rotating member. The flow measuring system determines characteristics of the flow based on the rotational characteristics of the rotating member.
Abstract translation: 实施例包括用于测量流体流动特性的流量测量系统。 流量测量系统可以包括与流体流同步旋转的一对旋转构件。 至少一个旋转构件可以包括正常反射部分和非正常反射部分。 正反射部分在与正常反射部分的平面的法线方向平行的方向上反射入射光束。 非正常反射部分在与正常反射部分的平面的法线方向不平行的方向上反射入射光束。 流量测量系统测量由正反射部分反射的光束的光学特性,并确定旋转部件的旋转特性。 流量测量系统基于旋转构件的旋转特性确定流动的特性。
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公开(公告)号:US10107756B2
公开(公告)日:2018-10-23
申请号:US14993960
申请日:2016-01-12
Applicant: Ecolab USA, Inc.
Inventor: John Wilhelm Bolduc , Eugene Tokhtuev , Anatoly Skirda , Anna Pilipchenko , Justin Scott Valenstein , Amanda Bakken , Stacy Fawbush , Jeffrey S. Hutchison
Abstract: A method of fluorometrically detecting the concentration of chemical components in oxidizing formulations is disclosed. In a particular embodiment the detection is of the stabilizing component of picolinic acid, present in such formulations, although any component which fluoresces may be detected. According to the invention sample preparation of the oxidizing formulation includes adding to said sample an excess of reducing agent to bind peracid, and in the case of picolinic acid, adding to said sample an excess of terbium chloride. The sample then is subjected to radiation to induce fluorescence and the concentration of said chemical component is determined by a linear relationship between fluorescence emitted and the concentration of the target chemical.
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公开(公告)号:US09110049B2
公开(公告)日:2015-08-18
申请号:US14051784
申请日:2013-10-11
Applicant: Ecolab USA Inc.
Inventor: Eugene Tokhtuev , Christopher Owen , Anna Pilipchenko , Paul Schilling , Daniel Kamben
IPC: G01N21/00 , G01N31/22 , G01N21/05 , G01N21/31 , G01N35/08 , G01N21/79 , B01L3/00 , G01N33/52 , G01N35/10 , C12Q1/22 , G01N21/27 , G01N35/00 , G01N21/03
CPC classification number: G01N31/228 , B01L3/502 , B01L3/502738 , C12Q1/22 , G01N21/0303 , G01N21/05 , G01N21/274 , G01N21/31 , G01N21/79 , G01N33/52 , G01N35/00594 , G01N35/085 , G01N35/1095 , G01N35/1097 , G01N2035/00465 , G01N2035/0097 , Y10T436/201666 , Y10T436/206664
Abstract: A use composition monitor determines the concentration of peracid and/or peroxide in a use composition using a kinetic assay procedure. A sample mixture containing a sample of the use composition, a diluent and at least one reagent is prepared and analyzed using, for example, an optical detector. A reduced-turbulence optical detector can be used to improve collected response data. A reduced-turbulence optical detector can include a cell body disposed about a length of transparent tubing. The cell body positions one or more emitter/receiver pairs about the transparent tubing. Thus, tube junctions are eliminated and sample flow within the tube is substantially turbulence free.
Abstract translation: 使用组合物监测器使用动力学测定程序确定使用组合物中过酸和/或过氧化物的浓度。 使用例如光学检测器制备并分析含有使用组合物样品,稀释剂和至少一种试剂的样品混合物。 减少湍流光学检测器可用于改善收集的响应数据。 减少湍流光学检测器可以包括围绕一定长度的透明管设置的电池体。 细胞体围绕透明管定位一个或多个发射器/接收器对。 因此,管接头被消除,管内的样品流动基本上是无湍流的。
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公开(公告)号:US08912009B2
公开(公告)日:2014-12-16
申请号:US13854589
申请日:2013-04-01
Applicant: Ecolab USA Inc.
Inventor: Eugene Tokhtuev , Christopher J. Owen , Anna Pilipchenko
CPC classification number: G01N35/00 , B01L3/50273 , B01L3/502738 , B01L2300/0867 , B01L2300/087 , B01L2300/0874 , B01L2300/0887 , B01L2300/1822 , B01L2400/0481 , B01L2400/0638 , F04B19/006 , G01N21/0332 , G01N21/05 , G01N35/1097 , G01N2021/0346 , G01N2035/00237 , Y10T436/15 , Y10T436/206664 , Y10T436/25 , Y10T436/2575
Abstract: A microflow analytical system includes a laminate pump assembly connectable with one or more sources of fluid, one or more pneumatic control pumps, a mixer, and a sensor. The laminate pump assembly is adapted to deliver predetermined volumes of the fluid(s) through a plurality of flow paths which are formed within layers of the assembly. Each flow path can include an inlet valve, a pump valve, and an outlet valve each of which are controllable by the pneumatic control pumps. A series of manifolds can be formed within the layers of the pump assembly to provide for simultaneous activation of selected flow paths. Delivered fluid volumes can be mixed in the mixer which, in some embodiments, may be integral with the laminate pump assembly. The sensor can measure one or more characteristics of the mixed fluids to determine one or more properties of the fluids.
Abstract translation: 微流分析系统包括可与一个或多个流体源连接的层压泵组件,一个或多个气动控制泵,混合器和传感器。 层压泵组件适于通过形成在组件的层内的多个流动路径输送预定体积的流体。 每个流动路径可包括入口阀,泵阀和出口阀,每个阀可由气动控制泵控制。 可以在泵组件的层内形成一系列歧管以提供选择的流动路径的同时激活。 输送的流体积可以混合在混合器中,在一些实施例中,该混合器可以与层压泵组件成一体。 传感器可以测量混合流体的一个或多个特性以确定流体的一个或多个特性。
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公开(公告)号:US20160097721A1
公开(公告)日:2016-04-07
申请号:US14970573
申请日:2015-12-16
Applicant: Ecolab USA Inc.
Inventor: John Wilhelm Bolduc , Justin Scott Valenstein , Amanda Bakken , Stacy Fawbush , Jeffrey Hutchison , Eugene Tokhtuev , Anatoly Skirda , Anna Pilipchenko
IPC: G01N21/64
CPC classification number: G01N21/645 , G01N21/6428 , G01N21/6486 , G01N21/8507 , G01N21/8806 , G01N2021/6471 , G01N2201/068
Abstract: A method of detecting concentration of dipicolinic acid and terbium chloride in a chemical composition with a fluorometer, wherein the fluorometer comprises an excitation source for emitting electromagnetic radiation at one or more wavelengths, and a detector module for detecting fluorescence emitted by dipicolinic acid, emitting electromagnetic radiation from the excitation source at wavelengths that induce fluorescence in dipicolinic acid-terbium chloride combination present in the chemical composition, detecting the fluorescence emitted by the dipicolinic acid-terbium chloride combination via the detector module, and determining the concentration of dipicolinic acid using predetermined relationship between fluorescence emitted and the concentration of dipicolinic acid-terbium chloride combination.
Abstract translation: 一种利用荧光计检测化学成分中二吡啶甲酸和铽的浓度的方法,其中所述荧光计包括用于发射一个或多个波长的电磁辐射的激发源,以及用于检测由吡啶二酸发射的荧光的检测器模块,发射电磁 在化学组成中存在于二吡啶甲酸 - 铽氯化物组合中诱导荧光的波长处的激发源的辐射,通过检测器模块检测由二吡啶甲酸 - 氯化铽组合发出的荧光,并使用预定关系确定二吡啶甲酸的浓度 荧光发射和二吡啶甲酸 - 铽的组合浓度。
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公开(公告)号:US20160047746A1
公开(公告)日:2016-02-18
申请号:US14457573
申请日:2014-08-12
Applicant: Ecolab USA Inc.
Inventor: Eugene Tokhtuev , Anatoly Skirda , Anna Pilipchenko , John Wilhelm Bolduc , Justin Scott Valenstein
IPC: G01N21/64
CPC classification number: G01N21/645 , G01N21/6428 , G01N21/6486 , G01N21/8507 , G01N21/8806 , G01N2021/6471 , G01N2201/068
Abstract: A fluorometer for measuring fluorescence of a sample includes an excitation source for emitting electromagnetic radiation along a first beam path to induce fluorescence in the sample. An excitation filter transmits electromagnetic radiation from the excitation source toward the sample. An excitation filter holder supports the excitation filter and defines an aperture for passage of electromagnetic radiation from the excitation source. The aperture is positioned asymmetrically relative to the first beam path such that the aperture allows an asymmetrical portion of the electromagnetic radiation in the first beam path to pass toward the sample and the excitation filter holder blocks passage of a corresponding asymmetrical portion of the electromagnetic radiation in the first beam path. The blocked passage of the corresponding asymmetrical portion of the electromagnetic radiation in the first beam path reduces the amount of electromagnetic radiation oriented directly from the emitter module to the detector module.
Abstract translation: 用于测量样品荧光的荧光计包括用于沿着第一光束路径发射电磁辐射以在样品中诱导荧光的激发源。 激发滤波器将来自激发源的电磁辐射传递给样品。 激励过滤器保持器支撑激励过滤器并且限定用于来自激发源的电磁辐射通过的孔。 孔径相对于第一光束路径不对称地定位,使得孔口允许第一光束路径中的电磁辐射的不对称部分朝向样品传递,并且激发滤光器保持器阻止电磁辐射的对应不对称部分的通过 第一个光束路径。 第一光束路径中电磁辐射的对应不对称部分的阻挡通道减少了从发射器模块直接定向到检测器模块的电磁辐射量。
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