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公开(公告)号:US20150210940A1
公开(公告)日:2015-07-30
申请号:US14584539
申请日:2014-12-29
申请人: ENI S.P.A.
CPC分类号: C10G67/02 , B01J8/10 , B01J8/22 , B01J2208/00823 , B01J2208/00893 , C10G49/00 , C10G2300/107
摘要: System and relative process for the complete and high-productivity hydroconversion of heavy oils essentially consisting of a solid accumulation reactor and a stripping section of the conversion products outside or inside the reactor itself.In particular, the system proposed consists of a solid accumulation hydroconversion reactor in which the solids deriving from and generated by the feedstock treated (metals in the form of sulphides and coke) are accumulated, up to very high levels, and a hot gas stripping section of the reaction liquid, designed in relation to the type of reactor adopted, for the direct and continuous removal of the conversion products, including high-boiling products.
摘要翻译: 用于完全和高生产率加氢转化重油的系统和相关方法,其主要由固体堆积反应器和反应器本身外部或内部的转化产物的汽提部分组成。 特别地,所提出的系统包括固体积聚加氢转化反应器,其中由处理的原料衍生并由其生成的固体(硫化物和焦炭形式的金属)被累积至高水平,热气体汽提段 的反应液体,其设计与所采用的反应器类型相关,用于直接和连续地除去包括高沸点产物在内的转化产物。
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公开(公告)号:US10407628B2
公开(公告)日:2019-09-10
申请号:US14902204
申请日:2014-07-04
申请人: ENI S.p.A.
发明人: Giuseppe Bellussi , Vincenzo Piccolo , Alberto Maria Antonio Malandrino , Valentina Fabio , Giacomo Fernando Rispoli
IPC分类号: C10G65/00 , C10G45/02 , C10G47/26 , C10G49/12 , C10G65/12 , C10G65/14 , C10G65/16 , C10G7/00 , C10G7/06
摘要: A process for the refining of crude oil with at least one atmospheric distillation unit for separating the various fractions, a sub-atmospheric distillation unit, a conversion unit of the heavy fractions obtained, a unit for enhancing the quality of some of the fractions obtained by actions on the chemical composition of their constituents and a unit for the removal of undesired components, where the sub-atmospheric distillation residue is sent to one of the conversion units, the conversion unit includes at least one hydroconversion reactor in slurry phase, into which hydrogen or a mixture of hydrogen and H2S, is fed, in the presence of a suitable dispersed hydrogenation catalyst with dimensions ranging from 1 nanometer to 30 microns.
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公开(公告)号:US09850436B2
公开(公告)日:2017-12-26
申请号:US14758315
申请日:2014-01-22
申请人: ENI S.p.A.
CPC分类号: B01J8/22 , B01J8/1809 , B01J2208/00584 , B01J2219/002 , B01J2219/00209 , B01J2219/00243 , B01J2219/0025 , H01L21/67276
摘要: Method for maximizing the reaction volume in a slurry phase reactor by determining the ratio (f) between the height of the foams (Hf) and the height of the reactor (HR) through an algorithm defining the gas hold-up in three zones, a first lower zone in which a bubble regime is established, a second intermediate zone where there can be the presence of foams, a third zone situated in the upper hemispherical part in which the multiphase mixture is accelerated until it reaches outlet conditions, the average gas hold-up being given by the weighted average of each of the three gas hold-ups of the three zones, characterized in that it uses nuclear densimeters positioned inside the reactor at different heights and comprises: measuring, for each nuclear densimeter used, gas density values, relating to different gas and/or slurry velocities, which correspond through said algorithm to calculated gas hold-up values, revealing, with a calculated gas hold-up of less than 40%, the absence of foams at least up to the height at which the densimeter is positioned, whose density measured corresponds to said gas hold-up, with a calculated gas hold-up higher than 70%, the presence of foams starting at least from the height of the reactor in which the densimeter is positioned, whose density measured corresponds to said gas hold-up, finally, determining through said algorithm, the ratio f and the extension in height of the possible presence of foams, calculating the consequent height Hf.
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公开(公告)号:US09708554B2
公开(公告)日:2017-07-18
申请号:US14584539
申请日:2014-12-29
申请人: ENI S.P.A.
CPC分类号: C10G67/02 , B01J8/10 , B01J8/22 , B01J2208/00823 , B01J2208/00893 , C10G49/00 , C10G2300/107
摘要: Provided is a system for the hydroconversion of heavy oils essentially consisting of a solid accumulation reactor and a stripping section of the products of hydroconversion outside or inside the reactor itself.
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