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公开(公告)号:US11708539B2
公开(公告)日:2023-07-25
申请号:US17274835
申请日:2019-09-09
申请人: ENI S.P.A.
CPC分类号: C10L3/104 , B01D53/1425 , B01D53/1475 , B01D53/1493 , B01D53/62 , B01D53/78 , C10L3/103 , B01D2252/202 , B01D2252/2053 , B01D2252/2056 , B01D2252/504 , B01D2257/504 , B01D2258/0283 , C10L2290/541
摘要: There is an absorbent mixture usable for the removal of sour gases from gas mixtures. The mixture has at least one organic base having a pKb (in water) less than or equal to 3.2; at least one alcoholic solvent of general formula R(OH)n having a boiling temperature above or equal to 100° C. at ambient pressure, wherein R is a linear or branched saturated alkyl group having a number of carbon atoms between 2 and 20 and n is a whole number varying between 1 and 20; an aprotic polar solvent having a dielectric constant ε at 25° C. greater than or equal to 30, a viscosity μ at 25° C. less than or equal to 14 cP, preferably less than or equal to 12 cP; and a boiling temperature at normal pressure equal to or above 130° C. There is also a process for the removal of sour gases using the absorbent mixture.
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2.
公开(公告)号:US20240239708A9
公开(公告)日:2024-07-18
申请号:US17769593
申请日:2020-10-16
申请人: ENI S.P.A.
IPC分类号: C04B7/13 , C04B28/04 , C04B40/00 , C04B103/00
CPC分类号: C04B7/13 , C04B28/04 , C04B40/0042 , C04B2103/0088
摘要: There is a process of CO2 mineralization with natural mineral phases with prevalent alkaline-earth metals silicate content producing a mixture of magnesium carbonate, amorphous silica and other possibly non-reacted or non-mineralizable phases. The material thus obtained, after being washed with water, develops pozzolanic properties and can be used for formulating cements.
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3.
公开(公告)号:US20240132401A1
公开(公告)日:2024-04-25
申请号:US17769593
申请日:2020-10-15
申请人: ENI S.P.A.
IPC分类号: C04B7/13 , C04B28/04 , C04B40/00 , C04B103/00
CPC分类号: C04B7/13 , C04B28/04 , C04B40/0042 , C04B2103/0088
摘要: There is a process of CO2 mineralization with natural mineral phases with prevalent alkaline-earth metals silicate content producing a mixture of magnesium carbonate, amorphous silica and other possibly non-reacted or non-mineralizable phases. The material thus obtained, after being washed with water, develops pozzolanic properties and can be used for formulating cements.
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公开(公告)号:US11878289B2
公开(公告)日:2024-01-23
申请号:US17666030
申请日:2022-02-07
申请人: ENI S.p.A.
IPC分类号: C10G45/08 , B01J27/051 , B01J21/18 , B01J37/00 , B01J37/03 , B01J37/04 , B01J37/08 , B01J37/20 , C01G53/00
CPC分类号: B01J27/0515 , B01J21/18 , B01J37/0009 , B01J37/031 , B01J37/04 , B01J37/084 , B01J37/088 , B01J37/20 , C01G53/40 , C10G45/08 , C01P2002/50 , C10G2300/1059 , C10G2300/202
摘要: A process of hydrotreating of a feed containing one or more hydrocarbons by contacting the feed with hydrogen in the presence of a metal sulphide catalyst obtained by sulphidation of a precursor which is in the form of a mixed oxide of formula (I) or of a mixed oxide of formula (I) bound to an inorganic binder B: Mea Nib Moc Wd Ale Of • pC (I).
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公开(公告)号:US10407628B2
公开(公告)日:2019-09-10
申请号:US14902204
申请日:2014-07-04
申请人: ENI S.p.A.
发明人: Giuseppe Bellussi , Vincenzo Piccolo , Alberto Maria Antonio Malandrino , Valentina Fabio , Giacomo Fernando Rispoli
IPC分类号: C10G65/00 , C10G45/02 , C10G47/26 , C10G49/12 , C10G65/12 , C10G65/14 , C10G65/16 , C10G7/00 , C10G7/06
摘要: A process for the refining of crude oil with at least one atmospheric distillation unit for separating the various fractions, a sub-atmospheric distillation unit, a conversion unit of the heavy fractions obtained, a unit for enhancing the quality of some of the fractions obtained by actions on the chemical composition of their constituents and a unit for the removal of undesired components, where the sub-atmospheric distillation residue is sent to one of the conversion units, the conversion unit includes at least one hydroconversion reactor in slurry phase, into which hydrogen or a mixture of hydrogen and H2S, is fed, in the presence of a suitable dispersed hydrogenation catalyst with dimensions ranging from 1 nanometer to 30 microns.
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公开(公告)号:US20220056361A1
公开(公告)日:2022-02-24
申请号:US17274835
申请日:2019-09-09
申请人: ENI S.P.A.
摘要: There is an absorbent mixture usable for the removal of sour gases from gas mixtures. The mixture has at least one organic base having a pKb (in water) less than or equal to 3.2; at least one alcoholic solvent of general formula R(OH)n having a boiling temperature above or equal to 100° C. at ambient pressure, wherein R is a linear or branched saturated alkyl group having a number of carbon atoms between 2 and 20 and n is a whole number varying between 1 and 20; an aprotic polar solvent having a dielectric constant E at 25° C. greater than or equal to 30, a viscosity μ at 25° C. less than or equal to 14 cP, preferably less than or equal to 12 cP; and a boiling temperature at normal pressure equal to or above 130° C. There is also a process for the removal of sour gases using the absorbent mixture.
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公开(公告)号:US20150210940A1
公开(公告)日:2015-07-30
申请号:US14584539
申请日:2014-12-29
申请人: ENI S.P.A.
CPC分类号: C10G67/02 , B01J8/10 , B01J8/22 , B01J2208/00823 , B01J2208/00893 , C10G49/00 , C10G2300/107
摘要: System and relative process for the complete and high-productivity hydroconversion of heavy oils essentially consisting of a solid accumulation reactor and a stripping section of the conversion products outside or inside the reactor itself.In particular, the system proposed consists of a solid accumulation hydroconversion reactor in which the solids deriving from and generated by the feedstock treated (metals in the form of sulphides and coke) are accumulated, up to very high levels, and a hot gas stripping section of the reaction liquid, designed in relation to the type of reactor adopted, for the direct and continuous removal of the conversion products, including high-boiling products.
摘要翻译: 用于完全和高生产率加氢转化重油的系统和相关方法,其主要由固体堆积反应器和反应器本身外部或内部的转化产物的汽提部分组成。 特别地,所提出的系统包括固体积聚加氢转化反应器,其中由处理的原料衍生并由其生成的固体(硫化物和焦炭形式的金属)被累积至高水平,热气体汽提段 的反应液体,其设计与所采用的反应器类型相关,用于直接和连续地除去包括高沸点产物在内的转化产物。
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公开(公告)号:US20220267487A1
公开(公告)日:2022-08-25
申请号:US17625191
申请日:2020-07-07
申请人: ENI S.P.A.
摘要: There is a process for high sulfur content copolymer preparation having the step of reacting sulfur in solid form with at least one crosslinker selected from organic compounds having at least a double or triple bond in the presence of at least one catalyst selected from dithiocarbamates, mercaptobenzothiazoles, xanthates, thiophosphates, at a temperature ranging from 110° C. to 180° C.
The high sulfur content copolymer, depending on the glass transition temperature, can be of elastomeric or thermoplastic type and can be advantageously used in different applications. In case of an elastomeric-type high sulfur content copolymer, the copolymer can be advantageously used in different applications such as, for example, thermal insulation, conveyor belts, transmission belts, flexible tubes, elastomeric tire compositions. In case of a thermoplastic-type high sulfur content copolymer, the copolymer can be advantageously used, as such or in a mixture with other (co)polymers (for example, styrene, divinylbenzene), in different applications such as, for example, packaging, electronics, household appliances, computer cases, CD cases, kitchen, laboratories, offices and medical items, in building and construction.-
公开(公告)号:US10590356B2
公开(公告)日:2020-03-17
申请号:US14767400
申请日:2014-02-11
申请人: ENI S.p.A.
IPC分类号: C10L1/18 , C10L1/02 , C10L1/185 , C07D317/22 , C07C45/52 , C07C41/09 , C07C29/60 , C07C67/44 , C10L10/02 , C10L10/04 , C10L10/10 , C10L10/12 , C10L10/16 , C10L1/19
摘要: The invention relates to an integrated process for the production of fuel components starting from materials of a biological origin which comprises: (A) transformation of glycerine into an alkoxy-propanediol having formula RO—CH2—CHOH—CH2OH, wherein R is a linear or branched C1-C8 alkyl, (B) transformation of glycerine into 1,2-propanediol CH3—CHOH—CH2OH, (C) dehydration of the 1,2-propanediol obtained in (B) to propionic aldehyde, (D) reaction of part of the propionic aldehyde obtained in (C) with the alkoxy-propanediol having formula RO—CH2—CHOH—CH2OH obtained in (A) to give an acetal having formula (a) wherein R is a linear or branched C1-C8 alkyl, (E) transformation of part of the propionic aldehyde obtained in (C) to a propionate having formula CH3—CH2—COOR′, wherein R′ is a linear or branched C1-C8 alkyl. Particular components for gasolines and/or diesel are also described.
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公开(公告)号:US09975112B2
公开(公告)日:2018-05-22
申请号:US14969747
申请日:2015-12-15
申请人: ENI S.p.A.
发明人: Giuseppe Bellussi , Angela Carati , Maria Federica Gagliardi , Stefano Zanardi , Marcello Marella , Roberto Scattolin , Michele Tomaselli
IPC分类号: B01J31/00 , B01J23/00 , B01J27/051 , B01J27/049 , B01J35/10 , B01J37/03 , B01J37/20 , C10G45/08 , B01J23/883 , B01J23/888 , B01J21/00 , B01J25/00
CPC分类号: B01J27/0515 , B01J23/002 , B01J23/883 , B01J23/8885 , B01J27/049 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J37/033 , B01J37/20 , B01J2523/00 , C10G45/08 , C10G2300/1044 , C10G2300/1062 , C10G2300/107 , C10G2300/1077 , C10G2300/202 , C10G2400/04 , C10G2400/06 , B01J2523/31 , B01J2523/68 , B01J2523/69 , B01J2523/845 , B01J2523/847 , B01J2523/41
摘要: New sulfided metal catalysts are described, containing a metal X selected from Ni, Co and mixtures thereof, a metal Y selected from Mo, W and mixtures thereof, an element Z selected from Si, Al and mixtures thereof, and possibly an organic residue, obtained by the sulfidation of mixed oxide precursors, also new, having general formula (A) XaYbZcOd.pC (A) possibly shaped without a binder, or by sulfidation of mixed oxides having formula (A), in shaped form with a binder, wherein X is selected from Ni, Co and mixtures thereof, Y is selected from Mo, W and mixtures thereof, Z is selected from Si, Al and mixtures thereof, O is oxygen, C is selected from: a nitrogenated compound N, an organic residue deriving from the partial calcination of the nitrogenated compound N, said nitrogenated compound N, when present, being selected from: a) an alkyl ammonium hydroxide having formula (I) RIRIIRIIIRIVNOH (I) wherein the groups RIRIV, the same or different, are aliphatic groups containing from 1 to 7 carbon atoms, b) an amine having formula (II) R1R2R3N (II) wherein R1 is a linear, branched or cyclic alkyl, containing from 4 to 12 carbon atoms, and R2 and R3, the same or different, are selected from H and a linear, branched or cyclic alkyl, containing from 4 to 12 carbon atoms, said alkyl being equal to or different from R1, a, b, c, d are the number of moles of the elements X, Y, Z, O, respectively, p is the weight percentage of C with respect to the total weight of the precursor having formula (A), a, b, c, d are higher than 0 a/b is higher than or equal to 0.3 and lower than or equal to 2, (a+b)/c is higher than or equal to 0.3 and lower than or equal to 10, preferably varying from 0.8 to 10 d=(2a+6b+Hc)/2 wherein H=4 when Z=Si H=3 when Z=Al and p is higher than or equal to 0 and lower than or equal to 40%. Said catalysts can be used as hydrotreating catalysts.
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