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    HYDROCARBON COMPOSITION USEFUL AS A FUEL AND FUEL OIL CONTAINING A PETROLEUM COMPONENT AND A COMPONENT OF A BIOLOGICAL ORIGIN
    1.
    发明申请
    HYDROCARBON COMPOSITION USEFUL AS A FUEL AND FUEL OIL CONTAINING A PETROLEUM COMPONENT AND A COMPONENT OF A BIOLOGICAL ORIGIN 审中-公开
    作为含有石油成分和生物原料成分的燃料和燃油的烃油组合物

    公开(公告)号：US20150068109A1

    公开(公告)日：2015-03-12

    申请号：US14537054

    申请日：2014-11-10

    申请人： ENI S.p.A. ,  UOP LLC

    发明人： Franco BALDIRAGHI ,  Silvia GUANZIROLI ,  Giovanni FARACI ,  Luigina Maria Flora SABATINO ,  Terry Louise MARKER ,  John Anthony PETRI

    IPC分类号： C10G65/02 ,  C10L1/196 ,  C10L10/14 ,  C10L1/08 ,  C10G67/02 ,  C10G67/14

    CPC分类号： C10G65/02 ,  C10G67/02 ,  C10G67/14 ,  C10L1/08 ,  C10L1/1966 ,  C10L10/14 ,  C10L2200/0446 ,  C10L2200/0484 ,  C10L2270/026 ,  C10L2290/542 ,  Y02E50/13

    摘要： The invention relates to a hydrocarbon composition, which can be used as a fuel and/or fuel oil, containing a petroleum component (A) and a component of a biological origin (B), wherein the component of a biological origin is present in a quantity of up to 75% by volume with respect to the total composition. Said component of a biological origin (B) is prepared starting from a mix of a biological origin (C) containing esters of fatty acids, with possible aliquots of free fatty acids, by means of a process which comprises the following steps: 1) hydrodeoxygenation of the mix of a biological origin; 2) hydroisomerization of the mix resulting from step (1), after possible water and gas flow separation, wherein said hydroisomerization is preferably carried out in the presence of a catalytic system comprising: a) a carrier of an acidic nature, comprising a completely amorphous micro-mesoporous silica-alumina, with a SiO2/Al2O3 molar ratio ranging from 30 to 500, a surface area larger than 500 m2/g, a pore volume ranging from 0.3 to 1.3 ml/g, an average pore diameter smaller than 40 Å, b) a metal component containing one or more metals of group VIII, possibly mixed with one or more metals of group VIB.

    摘要翻译： 本发明涉及一种烃组合物，其可用作燃料和/或燃料油，其含有石油组分（A）和生物来源（B）的组分，其中生物来源的组分存在于 相对于组合物的总量可达75％。 生物来源（B）的所述组分由含有脂肪酸酯的生物来源（C）与可能的游离脂肪酸等分试样混合制备，其方法包括以下步骤：1）加氢脱氧 的生物来源的组合; 2）在可能的水和气体流分离之后，由步骤（1）得到的混合物的加氢异构化，其中所述加氢异构化优选在催化体系存在下进行，所述催化体系包括：a）酸性载体，其包含完全无定形的 微孔介孔二氧化硅 - 氧化铝，SiO 2 / Al 2 O 3摩尔比为30-500，表面积大于500m2 / g，孔体积为0.3-1.3ml / g，平均孔径小于40埃 ，b）含有一种或多种VIII族金属的金属组分，可能与VIB族的一种或多种金属混合。