公开(公告)号：US20180345244A1

公开(公告)日：2018-12-06

申请号：US15778768

申请日：2016-11-24

申请人： ERAMET ,  IFP ENERGIES NOUVELLES

发明人： Malika BOUALLEG ,  Fabien André Pierre BURDET ,  Morgan Julien Florian GOHIN

IPC分类号： B01J20/04 ,  B01J20/30 ,  B01J20/28

CPC分类号： C01F7/002 ,  B01J20/041 ,  B01J20/3007 ,  C01D15/00 ,  C01F7/004 ,  C01F7/025 ,  C01P2002/72

摘要： The present invention relates to the field of solid materials for the adsorption of lithium. In particular, the present invention relates to a new method for the preparation of a crystallized and shaped solid material, preferably in extruded form, of formula LiXx.2Al(OH)3,nH2O, wherein n is between 0.01 and 10, x is 1 when X is an anion selected from among chloride, hydroxide and nitrate anions, and x is 0.5 when X is an anion selected from among sulfate and carbonate anions, comprising a boehmite precipitation step a) under specific temperature and pH conditions, at least one basic mixing shaping step, wherein the method also comprises a final hydrothermal treatment step, all to increase the lithium adsorption capacity and the kinetics of adsorption of the materials obtained, compared with the materials of the prior art when it is used in a method for lithium extraction from saline solutions.

公开(公告)号：US20160317998A1

公开(公告)日：2016-11-03

申请号：US15107453

申请日：2014-12-23

申请人： ERAMET ,  IFP ENERGIES NOUVELLES

发明人： Malika BOUALLEG ,  Olivier LAFON ,  Fabien André Pierre BURDET ,  Romain Charles Joseph René SOULAIROL

IPC分类号： B01J20/08 ,  C02F1/28 ,  C01D15/04 ,  B01D15/36 ,  B01J20/04 ,  B01J20/30

CPC分类号： B01J20/08 ,  B01D15/36 ,  B01J20/046 ,  B01J20/3007 ,  B01J20/3078 ,  B01J20/3085 ,  B01J2220/58 ,  C01D15/04 ,  C01F7/043 ,  C01P2002/72 ,  C01P2006/12 ,  C02F1/281

摘要： A method for preparing a crystallized solid material of formula LiCl.2Al(OH)3,nH2O with n being comprised between 0.01 and 10, includes mixing in an aqueous medium, at least one source of alumina and at least one source of lithium in order to obtain a suspension, filtering the resulting suspension obtained for obtaining a slurry, followed by drying the obtained slurry at a temperature between 20 and 80° C. for a period between 1 h and 12 h, then shaping by extrusion the resulting dried slurry, directly after the drying to obtain extrudates, where the shaping was carried out without any binder, and then the drying of the obtained extrudates at a temperature comprised between 20 and 200° C. for a period between 1 hour and 20 hours, in order to obtain the crystallized solid material of formula LiCl.2Al(OH)3,nH2O as extrudates. A method for extracting lithium from saline solutions uses the thereby prepared material.

摘要翻译： 制备结晶固体物质的方法，其中n包含在0.01至10之间的式LiCl 2 Al（OH）3，nH 2 O，其包括在水性介质中，至少一种氧化铝源和至少一种锂源，按顺序混合 得到悬浮液，过滤获得的悬浮液得到的悬浮液，然后在20〜80℃的温度下干燥所获得的浆料1小时至12小时之间的时间，然后挤出所得干浆料， 在干燥后直接获得挤出物，其中在没有任何粘合剂的情况下进行成型，然后将所得挤出物在20-200℃的温度下干燥1小时至20小时，以便 得到结晶的式LiCl 2 Al（OH）3，nH 2 O的固体物质作为挤出物。 从盐溶液中提取锂的方法使用由此制备的材料。

公开(公告)号：US20190314784A1

公开(公告)日：2019-10-17

申请号：US16314107

申请日：2017-06-30

申请人： ERAMET ,  IFP ENERGIES NOUVELLES

发明人： Vincent LECOCQ ,  Fabien André Pierre BURDET ,  Yohan Florent OUDART ,  Guillaume Patrick André MAILLET

IPC分类号： B01J20/08 ,  B01J20/04 ,  B01J20/30 ,  C01F7/14 ,  C01D15/00 ,  C22B26/12

摘要： The present invention relates to the field of solid materials for the adsorption of lithium. In particular, the present invention relates to a new method for the preparation of a crystallized and shaped solid material, preferably in extruded form, of the formula (LiCl)x.2Al(OH)3,nH2O, wherein n is between 0.01 and 10, x is between 0.4 and 1, wherein it comprises a step a) of precipitation of boehmite under specific temperature and pH conditions, a step of bringing into contact the precipitate obtained with LiCl, at least one acid extrusion-kneading shaping step, wherein the method also comprises a final hydrothermal treatment step, all of which makes it possible to increase the lithium adsorption capacity, the adsorption kinetics, as well as the lithium/boron selectivity of the materials obtained with respect to the materials of the prior art, when it is used in a lithium extraction method of saline solutions.

公开(公告)号：US20170043317A1

公开(公告)日：2017-02-16

申请号：US15306026

申请日：2015-04-24

申请人： ERAMET ,  IFP ENERGIES NOUVELLES

发明人： Malika BOUALLEG ,  Fabien André Pierre BURDET ,  Romain Charles Joseph René SOULAIROL

IPC分类号： B01J20/04 ,  C01D15/04 ,  C01F7/00 ,  B01J20/30 ,  B01J39/10

CPC分类号： B01J20/046 ,  B01J20/041 ,  B01J20/08 ,  B01J20/3007 ,  B01J20/3078 ,  B01J20/3085 ,  B01J39/10 ,  B01J41/10 ,  C01D15/04 ,  C01F7/002 ,  C01F7/021 ,  C01P2002/72 ,  C01P2006/12

摘要： A method for preparing a crystallized solid material of formula LiCl.2Al(OH)3.nH2O with n being comprised between 0.01 and 10, includes mixing in an aqueous medium, at least one source of alumina and at least one source of lithium in order to obtain a suspension, filtering the resulting suspension obtained for obtaining a slurry, followed by drying the obtained slurry and shaping the dried slurry after the drying to obtain a shaped solid material. The shaping is carried out in absence of a binder followed by drying and a hydrothermal treatment to obtain the shaped crystallized solid material of formula LiCl.2Al(OH)3.nH2O. A method for extracting lithium from saline solutions uses the thereby prepared material.

摘要翻译： 制备结晶固体物质的方法，其中n为0.01-10，其包括在水介质中，至少一种氧化铝源和至少一种锂源，按顺序混合，其结构为：LiCl 2 Al（OH）3·nH 2 O固体物质 得到悬浮液，过滤获得的悬浮液得到的悬浮液，然后干燥得到的浆料，干燥后使干燥的浆料成形，得到成形的固体材料。 成型在不存在粘合剂的情况下进行，然后进行干燥和水热处理，以获得结构式LiCl.2Al（OH）3·nH 2 O的结晶固体物质。 从盐溶液中提取锂的方法使用由此制备的材料。