Ion exchange membrane through UV initiation polymetrization

    公开(公告)号:US20210340343A1

    公开(公告)日:2021-11-04

    申请号:US17280179

    申请日:2019-09-25

    Abstract: Methods of producing an ion exchange membrane support are disclosed. The methods include saturating a polymeric microporous substrate with a charged monomer solution comprising at least one functional monomer, a cross-linking agent, and an effective amount of at least one photopolymerization initiator and polymerizing the at least one functional monomer by exposing the saturated polymeric microporous substrate to ultraviolet light under conditions effective to cross-link the at least one functional monomer and produce the ion exchange membrane support. Methods of producing a monovalent selective ion exchange membrane are also disclosed. The methods include functionalizing an exterior surface of the ion exchange membrane support with a charged compound layer, drying the ion exchange membrane support and soaking the ion exchange membrane support in a solution comprising an acid or a base for an amount of time effective to produce the monovalent selective ion exchange membrane.

    Anion exchange membranes for redox flow batteries

    公开(公告)号:US11929533B2

    公开(公告)日:2024-03-12

    申请号:US16771278

    申请日:2018-12-13

    CPC classification number: H01M8/188 B01J41/13 H01M8/0245

    Abstract: A flow battery having at least one rechargeable cell is disclosed. The at least one rechargeable cell can include an anolyte compartment, a catholyte compartment, and an anion exchange membrane positioned between the anolyte and catholyte compartments. The anion exchange membrane can have a thickness of less than 100 μm and a steady state diffusivity of less than 0.4 ppm/hr/cm2 with respect to a cation species in an electrolyte of the rechargeable cell. A method of facilitating use of a flow battery including providing the anion exchange membrane is also disclosed. A method of facilitating storage of an electric charge comprising providing the flow battery is also disclosed. A method of producing an anion exchange membrane is also disclosed.

    Ion exchange membrane through UV initiation polymerization

    公开(公告)号:US12163001B2

    公开(公告)日:2024-12-10

    申请号:US17280179

    申请日:2019-09-25

    Abstract: Methods of producing an ion exchange membrane support are disclosed. The methods include saturating a polymeric microporous substrate with a charged monomer solution comprising at least one functional monomer, a cross-linking agent, and an effective amount of at least one photopolymerization initiator and polymerizing the at least one functional monomer by exposing the saturated polymeric microporous substrate to ultraviolet light under conditions effective to cross-link the at least one functional monomer and produce the ion exchange membrane support. Methods of producing a monovalent selective ion exchange membrane are also disclosed. The methods include functionalizing an exterior surface of the ion exchange membrane support with a charged compound layer, drying the ion exchange membrane support and soaking the ion exchange membrane support in a solution comprising an acid or a base for an amount of time effective to produce the monovalent selective ion exchange membrane.

    Anion Exchange Membranes for Redox Flow Batteries

    公开(公告)号:US20200381761A1

    公开(公告)日:2020-12-03

    申请号:US16771278

    申请日:2018-12-13

    Abstract: A flow battery having at least one rechargeable cell is disclosed. The at least one rechargeable cell can include an anolyte compartment, a catholyte compartment, and an anion exchange membrane positioned between the anolyte and catholyte compartments. The anion exchange membrane can have a thickness of less than 100 μm and a steady state diffusivity of less than 0.4 ppm/hr/cm2 with respect to a cation species in an electrolyte of the rechargeable cell. A method of facilitating use of a flow battery including providing the anion exchange membrane is also disclosed. A method of facilitating storage of an electric charge comprising providing the flow battery is also disclosed. A method of producing an anion exchange membrane is also disclosed.

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