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公开(公告)号:US20240392063A1
公开(公告)日:2024-11-28
申请号:US18694729
申请日:2022-09-26
Applicant: EXXONMOBIL CHEMICAL PATENTS INC.
Inventor: Agostino Pietrangelo , Carlos R. Lopez-Barron , Timothy D. Shaffer , Pamela J. Wright
Abstract: Embodiments described herein relate to polyhdroxyalkanoate (PHA) copolymers and methods for their preparation utilizing ring-opening polymerization of lactones. Variations of the monomer composition, % of alternation, tacticity, and/or microstructure allow for tailoring of mechanical properties that fall into the elastomer, plastomer, and thermoplastic range.
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2.
公开(公告)号:US11952480B2
公开(公告)日:2024-04-09
申请号:US16763909
申请日:2019-02-05
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Johannes M. Soulages , Arnold Lustiger , Thomas T. Sun , Pamela J. Wright , Madhavi Vadlamudi , Alexander I. Norman , Adriana S. Silva , David M. Fiscus , Timothy D. Shaffer
CPC classification number: C08L23/0815 , B29C48/022 , B29C48/10 , C08J5/18 , B29K2023/0625 , B29K2023/0683 , B29K2105/0088 , B29K2995/0063 , B29K2995/0077 , C08J2323/08 , C08J2423/08 , C08L2205/025 , C08L2207/066 , C08L2207/068
Abstract: In some embodiments, the present disclosure provides a composition comprising 1) about 97.5 wt % to about 99.9 wt % of a first polyethylene having a density of about 0.91 g/cm3 to about 0.94 g/cm3, and a melt strength of about 10 mN or greater; and 2) about 0.1 wt % to about 2.5 wt % of a second polyethylene having an Mw of about 500,000 g/mol or more. In some embodiments, the composition is a film. In some embodiments, the present disclosure provides a method of making a composition comprising blending a first polyethylene of any embodiment described herein and a second polyethylene of any embodiment described herein.
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公开(公告)号:US10947375B2
公开(公告)日:2021-03-16
申请号:US15774302
申请日:2016-12-09
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Yu Feng Wang , Richard D. Hembree , Michael F. McDonald, Jr. , Joseph A. Maier , Richard C. M. Yeh , Leming Gu , Timothy D. Shaffer , Pamela J. Wright
Abstract: A system for producing a functionalized olefinic-based polymer, the system comprising a polymerization zone for producing an olefinic-based polymer comprising a mixing section, a deliquifying section, and a quenching section, wherein at least one section of the polymerization zone has a defined cross-sectional area that continually decreases from a first end to a second end of said section; a devolatilization zone comprising a kneader or extruder, wherein said devolatilization zone is downstream of said polymerization zone and in fluid communication with said polymerization zone; and a functionalization zone downstream of said devolatilization zone and in fluid communication with said devolatilization zone.
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公开(公告)号:US20200255643A1
公开(公告)日:2020-08-13
申请号:US15774302
申请日:2016-12-09
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Yu Feng Wang , Richard D. Hembree , Michael F. McDonald, JR. , Joseph A. Maier , Richard C.M. Yeh , Leming Gu , Timothy D. Shaffer , Pamela J. Wright
Abstract: A system for producing a functionalized olefinic-based polymer, the system comprising a polymerization zone for producing an olefinic-based polymer comprising a mixing section, a deliquifying section, and a quenching section, wherein at least one section of the polymerization zone has a defined cross-sectional area that continually decreases from a first end to a second end of said section; a devolatilization zone comprising a kneader or extruder, wherein said devolatilization zone is downstream of said polymerization zone and in fluid communication with said polymerization zone; and a functionalization zone downstream of said devolatilization zone and in fluid communication with said devolatilization zone.
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5.
公开(公告)号:US20210371632A1
公开(公告)日:2021-12-02
申请号:US16763909
申请日:2019-02-05
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Johannes M. Soulages , Arnold Lustiger , Thomas T. Sun , Pamela J. Wright , Madhavi Vadlamudi , Alexander I. Norman , Adriana S. Silva , David M. Fiscus , Timothy D. Shaffer
Abstract: In some embodiments, the present disclosure provides a composition comprising 1) about 97.5 wt % to about 99.9 wt % of a first polyethylene having a density of about 0.91 g/cm3 to about 0.94 g/cm3, and a melt strength of about 10 mN or greater; and 2) about 0.1 wt % to about 2.5 wt % of a second polyethylene having an Mw of about 500,000 g/mol or more. In some embodiments, the composition is a film. In some embodiments, the present disclosure provides a method of making a composition comprising blending a first polyethylene of any embodiment described herein and a second polyethylene of any embodiment described herein.
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