PROCESS FOR MAKING NOVEL POLYCONDENSATION PRE-POLYESTERS, OTHER COPOLYESTER PRECURSORS, AND COPOLYESTERS

    公开(公告)号:US20220363816A1

    公开(公告)日:2022-11-17

    申请号:US17596690

    申请日:2020-06-26

    IPC分类号: C08G63/183

    摘要: This invention relates to a process for making a polycondensation pre-polyester, a polyester or both, comprising the following steps: A. Acylation of at least one diacid chloride with at least one alcohol to form at least one diester; B. Partial hydrolysis of the diester product of Step A to form at least one monoacid; C. Esterifying the monoacid of Step B with at least one diol to form a diester; D. Reacting the diester of Step C under acidic conditions to form a diacid; and subsequently, performing either Step E or Step F as follows: E. Bisalkylation of the diacid of Step D with at least one haloalcohol to form a pentamer, or F. Esterifiying the diacid of Step D under esterification conditions with at least one diol to form a pentamer, provided that the diol is not the same as the diol used in Step C.