Oxygen-absorbing film
    2.
    发明授权

    公开(公告)号:US11939495B2

    公开(公告)日:2024-03-26

    申请号:US16986470

    申请日:2020-08-06

    摘要: An oxygen-absorbing film having an oxygen-absorbing adhesive agent layer including a cured oxygen-absorbing adhesive agent resin composition, wherein the oxygen-absorbing adhesive agent layer has at least two glass transition temperatures, and wherein the lowest glass transition temperature among the glass transition temperatures is lower than 0° C. The cured oxygen-absorbing adhesive agent resin composition preferably includes: (A) an oxygen-absorbing polyester resin having a glass transition temperature of −20 to 10° C. and (B) a saturated polyester resin having a glass transition temperature of −10° C. or lower. The oxygen-absorbing polyester-based resin (A) is made from a tetrahydrophthalic acid, a derivative thereof, a tetrahydrophthalic anhydride, or a derivative thereof, and the saturated polyester resin (B) containing a structural unit derived from a diol component and a structural unit derived from a dicarboxylic acid component is preferably selected from the group consisting of adipic acid, sebacic acid, isophthalic acid, and combinations thereof.

    Semi-crystalline mixture of polyester polyols, and the use thereof

    公开(公告)号:US11807714B2

    公开(公告)日:2023-11-07

    申请号:US16739324

    申请日:2020-01-10

    摘要: The present invention relates to a semi-crystalline mixture of polyester polyols which recrystallises upon melting and which can be obtained by polycondensing a reaction mixture comprising one or more dicarboxylic acids selected from saturated aliphatic dicarboxylic acids having an even number of at least 8 methylene groups, and one or more diols selected from aliphatic diols which have at least one ether function. The invention also relates to a polymeric material which is obtained from the chemical modification of the mixture of polyester polyols with organic compounds which contain at least one isocyonate group and/or epoxide group. The mixtures and materials according to the invention are characterised by relatively low melting enthalpies, while the melting temperature can be set in a range of −30 to 60° C., meaning that it is possible to obtain easily fusible formulations containing the mixtures and materials according to the invention. The mixtures and materials according to the invention also provide such formulations with a high elasticity and breaking resistance. The present invention therefore includes the use of the polyester polyols and polymeric materials according to the invention as deforming, fusing, and extrusion means in thermoplastic materials, and the use thereof for producing adhesives and sealants, in particular hot-melt adhesives and reactive adhesives.

    POLYESTER RESIN, AQUEOUS DISPERSION AND ADHESIVE COMPOSITION USING THE SAME

    公开(公告)号:US20230095125A1

    公开(公告)日:2023-03-30

    申请号:US17908327

    申请日:2021-03-26

    申请人: TOYOBO CO., LTD.

    摘要: The present inventors conducted intensive studies for solving the problems. As a result, they found a heat-sealable polyester resin which can be used for food application and which exhibits excellent adhesiveness to various containers made of polystylene, polyvinyl chloride, A-PET (amorphous polyethylene terephthalate) , or polypropylene, each having different property.
    The aim of the present invention is to provide a polyester resin which exhibits excellent adhesiveness to various substrates such as polystylene, polyvinyl chloride, or A-PET.
    According to the present invention, there is provided a polyester resin containing a polycarboxylic acid component and a polyhydric alcohol component as constitution units, wherein, when the total amount of the polyhydric alcohol component is taken as 100 mol%, the content of diethylene glycol component is 60 mol% or more, and wherein the glass transition temperature of the polyester resin is 20° C. or lower.