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公开(公告)号：US5376743A
公开(公告)日：1994-12-27
申请号：US29821
申请日：1993-03-11
IPC分类号： C08F4/64 , C08F2/34 , C08F4/60 , C08F4/659 , C08F210/16 , C08F210/18 , C08F210/06
CPC分类号： C08F210/16 , C08F210/18 , Y10S526/901 , Y10S526/904
摘要： A process for the production of EPM or EPDM comprising contacting ethylene, propylene, and, optionally, one or more dienes, in a fluidized bed, at a temperature at or above the sticking temperature of the product resin, under polymerization conditions, with(i) a prepolymer containing a transition metal catalyst precursor with the proviso that the prepolymer is not sticky at the process temperature;(ii) a hydrocarbyl aluminum and/or a hydrocarbyl aluminum halide cocatalyst,; and, optionally,(iii) a halocarbon promoter; and, optionally,(iv) an inert particulate material having a mean particle size in the range of about 0.01 to about 150 microns wherein the particulate material is either contained in the prepolymer or is independent of the prepolymer,wherein the amount of prepolymer or the combined amount of prepolymer and inert particulate material is sufficient to essentially prevent agglomeration of the fluidized bed and the product resin.
摘要翻译： 一种生产EPM或EPDM的方法，包括在聚合条件下，在聚合条件下，在等温或高于产物树脂的粘着温度的温度下，在流化床中使乙烯，丙烯和任选的一种或多种二烯与（i ）含有过渡金属催化剂前体的预聚物，条件是预聚物在工艺温度下不粘; （ii）烃基铝和/或烃基卤化铝助催化剂; 和（iii）卤代烃促进剂; 和（iv）平均粒度在约0.01至约150微米范围内的惰性颗粒材料，其中颗粒材料包含在预聚物中或独立于预聚物，其中预聚物或 预聚物和惰性颗粒材料的组合量足以基本上防止流化床和产物树脂的团聚。
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公开(公告)号：US5510433A
公开(公告)日：1996-04-23
申请号：US311138
申请日：1994-09-23
IPC分类号： C08F4/64 , C08F2/34 , C08F4/60 , C08F4/659 , C08F210/16 , C08F210/18
CPC分类号： C08F210/16 , C08F210/18 , Y10S526/901 , Y10S526/904
摘要： A process for the production of EPM or EPDM comprising contacting ethylene, propylene, and, optionally, one or more dienes, in a fluidized bed, at a temperature at or above the sticking temperature of the product resin, under polymerization conditions, with(i) a prepolymer containing a transition metal catalyst precursor with the proviso that the prepolymer is not sticky at the process temperature;(ii) a hydrocarbyl aluminum and/or a hydrocarbyl aluminum halide cocatalyst,; and, optionally,(iii) a halocarbon promoter; and, optionally,(iv) an inert particulate material having a mean particle size in the range of about 0.01 to about 150 microns wherein the particulate material is either contained in the prepolymer or is independent of the prepolymer,wherein the amount of prepolymer or the combined amount of prepolymer and inert particulate material is sufficient to essentially prevent agglomeration of the fluidized bed and the product resin.
摘要翻译： 一种生产EPM或EPDM的方法，包括在聚合条件下，在聚合条件下，在等温或高于产物树脂的粘着温度的温度下，在流化床中使乙烯，丙烯和任选的一种或多种二烯与（i ）含有过渡金属催化剂前体的预聚物，条件是预聚物在工艺温度下不粘; （ii）烃基铝和/或烃基卤化铝助催化剂; 和（iii）卤代烃促进剂; 和（iv）平均粒度在约0.01至约150微米范围内的惰性颗粒材料，其中颗粒材料包含在预聚物中或独立于预聚物，其中预聚物或 预聚物和惰性颗粒材料的组合量足以基本上防止流化床和产物树脂的团聚。
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公开(公告)号：US5585184A
公开(公告)日：1996-12-17
申请号：US314704
申请日：1994-09-29
IPC分类号： C08F2/34 , C08F4/60 , C08F4/631 , C08F4/64 , C08F4/658 , C08F4/659 , C08F4/6592 , C08F4/685 , C08F8/00 , C08F10/00 , C08F210/02 , C08F210/16 , C08F210/18 , C08F255/00 , C08F255/02 , B32B5/16 , B32B9/00 , B32B15/02 , B32B17/02
CPC分类号： C08F255/02 , C08F10/00 , C08F210/16 , C08F255/00 , C08F210/18 , Y10S525/902 , Y10S526/901 , Y10S526/904 , Y10S526/905 , Y10T428/2982 , Y10T428/2991 , Y10T428/2998
摘要： A colorable resin particle having an outer shell of a non-sticky olefinic polymer having a flow index of less than 20 decigrams/minute and an inner core of at least 90 wt % of a sticky polymer, the resin particle being made in a gas phase fluidized bed reactor at or above the sticking temperature of the sticky polymer in the absence of an inert particulate material fluidization aid.
摘要翻译： 一种可着色树脂颗粒，其具有流动指数小于20分克/分钟的非粘性烯烃聚合物的外壳和粘性聚合物的至少90重量％的内核，所述树脂颗粒以气相 在不存在惰性颗粒物质流化助剂的情况下，粘度聚合物的粘附温度以上或高于流化床反应器。
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公开(公告)号：US5187246A
公开(公告)日：1993-02-16
申请号：US544547
申请日：1990-06-26
CPC分类号： C08F10/02 , Y10S526/901
摘要： An improved polymerization process for making essentially non-agglomerated ethylene polymers, especially EPR polymers, based on the use of a high activity vanadium catalyst, which utilizes an alkylated metal chain transfer agent to moderate the kinetics of the polymerization reaction so as to avoid formation of an undesirable amount of agglomerated polymer.
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5.发明授权Process for making elastomeric ethylene-alpha-olefin polymers with stage-modified vanadium catalyst 失效制备具有阶段改性钒催化剂的弹性体乙烯-α-烯烃聚合物的方法
公开(公告)号：US5187247A
公开(公告)日：1993-02-16
申请号：US543392
申请日：1990-06-26
申请人： Edgar C. Baker , John H. Moorhouse , Allen Noshay
发明人： Edgar C. Baker , John H. Moorhouse , Allen Noshay
IPC分类号： C08F10/02 , C08F210/16 , C08F210/18
CPC分类号： C08F210/18 , C08F10/02 , C08F210/16 , Y10S526/901 , Y10S526/907
摘要： An improved polymerization process for making essentially nonagglomerated ethylene polymers, especially EPR polymers, based on the use of a stage-modified high activity vanadium catalyst, under polymerization conditions that normally would yield an undesirable amount of agglomerated polymer.
摘要翻译： 在通常会产生不期望量的附聚聚合物的聚合条件下，基于使用阶段改性的高活性钒催化剂制备基本上非团聚的乙烯聚合物，特别是EPR聚合物的改进的聚合方法。
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公开(公告)号：US4994534A
公开(公告)日：1991-02-19
申请号：US413704
申请日：1989-09-28
申请人： Seung J. Rhee , Edgar C. Baker , David N. Edwards , Kiu H. Lee , John H. Moorhouse , Leonard S. Scarola , Frederick J. Karol
发明人： Seung J. Rhee , Edgar C. Baker , David N. Edwards , Kiu H. Lee , John H. Moorhouse , Leonard S. Scarola , Frederick J. Karol
IPC分类号： C08F2/34 , C08F2/44 , C08F32/00 , C08F36/00 , C08F136/06 , C08F210/16 , C08F210/18 , C08F232/08 , C08F293/00 , C08F297/08
CPC分类号： C08F2/44 , C08F210/18 , B29K2019/00 , B29K2021/00 , B29K2023/16 , B29K2105/16 , Y10S526/901
摘要： A process for producing sticky polymers at polymerization reaction temperatures in excess of the softening temperature of the sticky polymers in a fluidized bed reactor catalyzed by a transition metal catalyst, which comprises conducting the polymerization reaction above the softening temperatures of the sticky polymers in the presence of about 0.3 to about 60 weight percent, based on the weight of the final product of an inlet particulate material having a mean particle size of from about 0.01 to about 10 micron meters whereby polymer agglomeration of the sticky polymers is maintained at a size suitable for continuously producing the sticky polymers.
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公开(公告)号：US5324798A
公开(公告)日：1994-06-28
申请号：US997527
申请日：1992-12-28
摘要： A finishing process for a polymer containing an active catalyst residue. Starting polymer has a crystallinity of less than 10 percent by weight and is maintained in an essentially oxygen free reaction zone at a temperature less than polymer sticking temperature. The polymer is stabilized and acids neutralized by adding 2, 6-di-tert-butyl-4-alkyl phenol and/or alkyl -3-(3-5 -di-tert-butyl-4-hydroxy phenyl)- propionate and zinc oxide, hydrotalcite, or a zeolite. Resulting polymer is then treated with catalyst deactivators including water, and then mixed with photo-oxidative stabilizers.
摘要翻译： 含有活性催化剂残余物的聚合物的精整方法。 起始聚合物的结晶度小于10重量％，并且在低于聚合物粘着温度的温度下保持在基本上不含氧的反应区。 聚合物稳定，通过加入2,6-二叔丁基-4-烷基苯酚和/或-3-（3-5-二叔丁基-4-羟基苯基） - 丙酸烷基酯和锌 氧化物，水滑石或沸石。 然后将所得聚合物用包括水在内的催化剂失活剂处理，然后与光氧化稳定剂混合。
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公开(公告)号：US5026903A
公开(公告)日：1991-06-25
申请号：US843920
申请日：1986-03-21
申请人： Edgar C. Baker
发明人： Edgar C. Baker
IPC分类号： C07C67/37
CPC分类号： C07C67/37
摘要： A process for the production of ethylidene diacetate by the catalytic reaction of dimethyl acetal, methyl acetate and carbon monoxide in contact with a homogeneous catalyst system containing rhodium metal atom and lithium iodide.
摘要翻译： 通过二甲基缩醛，乙酸甲酯和一氧化碳与含有铑金属原子和碘化锂的均相催化剂体系的接触的催化反应生产亚乙基二乙酸酯的方法。
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9.发明授权Flame spray system with splatter blocking and automated rod delivery apparatuses 失效火焰喷雾系统具有飞溅阻塞和自动送丝装置公开(公告)号：US06168090A
公开(公告)日：2001-01-02
申请号：US09224179
申请日：1998-12-31
申请人： Edgar C. Baker
发明人： Edgar C. Baker
IPC分类号： B05B718
CPC分类号： B05B7/224
摘要： A flame spray system employs splatter blocking and automated rod delivery apparatuses. The splatter blocking apparatus includes a barrier member and an actuation mechanism. The barrier member is adapted to be moved between a blocking position in which the barrier member is extended across a spray path from a flame spray gun of a flame spray system preventing travel of particles of fusible material from the flame spray gun to a product being coated and an unblocking position in which the barrier member is displaced from the spray path of the flame spray gun permitting travel of particles fusible material from the flame spray gun to the product being coated. The actuation mechanism is connected to the barrier member and adapted to be selectively actuated to move the barrier member between the blocking and unblocking positions. The automated rod delivery apparatus includes a magazine having a chamber for holding a plurality of the rods of heat fusible material in a stacked relationship with one another and a feed mechanism adjacent to the magazine and adapted to be selectively actuated to successively engage and transfer a lowermost one of the rods from the stack thereof in the chamber of the magazine out through a front opening of the magazine and into a feed passage of the flame spray gun.
摘要翻译： 火焰喷射系统采用喷雾阻塞和自动送丝装置。 飞溅阻挡装置包括阻挡构件和致动机构。 阻挡构件适于在阻挡构件在阻挡构件从火焰喷射系统的火焰喷枪的喷射路径延伸的阻挡位置之间移动，防止可熔材料颗粒从火焰喷枪移动到被涂覆的产品 以及阻挡构件从火焰喷枪的喷射路径移开的解锁位置，允许颗粒易熔材料从火焰喷枪移动到被涂覆的产品。 致动机构连接到阻挡构件并且适于被选择性地致动以在阻挡位置和解除阻挡位置之间移动阻挡构件。 自动杆传送装置包括一个盒子，该盒子具有用于将彼此堆叠的多个热熔材料杆保持在一起的腔室和一个邻近该盒体的进给机构，并且适于被选择性地致动以连续地接合和传送最下面的 其中一个杆从仓库中的堆叠中的一个通过弹匣的前开口穿过火焰喷枪的进料通道。
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10.发明授权Apparatus for controlling the rate of feeding of a rod of heat fusible material 失效用于控制热熔材料棒的供给速率的装置
公开(公告)号：US5449118A
公开(公告)日：1995-09-12
申请号：US259729
申请日：1994-06-14
申请人： Edgar C. Baker
发明人： Edgar C. Baker
CPC分类号： B05B7/203
摘要： A control apparatus is coupled to a flame spray gun for controlling the rate of feeding of a rod of heat fusible material through the gun. The control apparatus includes an electric motor adapted to be drivingly coupled to a flame spray gun and being operable in response to application of a D.C. voltage thereto to generate rotary motion to produce and control feeding of a rod of heat fusible material through the flame spray gun, an A.C. to D.C. converter and regulator device for generating and applying the D.C. voltage to the electric motor, a manually adjustable potentiometer connected to the converter and regulator to vary the quantity of D.C. voltage output applied to the electric motor and thereby control the rate of rotary motion produced by the electric motor, a tachometer coupled to the electric motor for sensing the rotary motion produced by the electric motor and, in response thereto, generating a feedback voltage signal representing the rate of rotary motion produced by the electric motor and thereby the rate of feeding of the rod of heat fusible material through the flame spray gun, and a digital display coupled to the tachometer and receiving the feedback signal therefrom, the digital display being adapted to produce a readout of the feed rate in response to the feedback signal.
摘要翻译： 控制装置连接到火焰喷枪上，用于控制通过枪的热熔材料棒的供给速率。 控制装置包括电动机，其适于驱动地连接到火焰喷枪，并且响应于施加直流电压而可操作以产生旋转运动，以产生并控制通过火焰喷枪的热熔材料棒的供给 ，用于产生和施加直流电压到电动机的AC到DC转换器和调节器装置，连接到转换器和调节器的手动可调电位器，以改变施加到电动机的直流电压输出的量，从而控制 由电动机产生的旋转运动，耦合到电动机的转速计，用于感测由电动机产生的旋转运动，并响应于此产生表示由电动机产生的旋转运动速率的反馈电压信号， 通过火焰喷枪对热熔材料棒进给的速率，以及数字显示器 d到转速计并从其接收反馈信号，数字显示器适于响应于反馈信号产生进给速率的读出。
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