摘要:
A polymer comprising polymerized N-alkyl substituted acrylamide and a polymerized crosslinking monomer wherein the polymer has a solubility parameter from about 13 to 16 at 25.degree. C., is useful as a temporary barrier layer between reactants in photographic products. The barrier layer is particularly useful as a process timing layer in color image transfer film units.
摘要:
A thermal dye transfer assemblage comprising:(a) a dye-donor dement comprising a support having thereon a dye layer comprising a dye dispersed in a polymeric binder, the dye being a deprotonated cationic dye which is capable of being reprotonated to a cationic dye having a N--H group which is part of a conjugated system, and(b) a dye-receiving element comprising a support having thereon a polymeric dye image-receiving layer, the dye-receiving element being in a superposed relationship with the dye-donor element so that the dye layer is in contact with the polymeric dye image-receiving layer, the polymeric dye image-receiving layer comprising a mixture of an organic polymeric or oligomeric acid which is capable of reprotonating the deprotonated cationic dye and a polymer having a Tg of less than about 19.degree. C. and having no or only slight acidity.
摘要:
A thermal dye transfer assemblage comprising:(a) a dye-donor element comprising a support having thereon a dye layer comprising a dye dispersed in a polymeric binder, the dye being a deprotonated cationic dye which is capable of being reprotonated to a cationic dye having a N--H group which is part of a conjugated system, and(b) a dye-receiving element comprising a support having thereon a polymeric dye image-receiving layer, the dye-receiving element being in a superposed relationship with the dye-donor element so that the dye layer is in contact with the polymeric dye image-receiving layer, the polymeric dye image-receiving layer containing an organic acid moiety as part of the polymer chain which is capable of reprotonating the deprotonated cationic dye, the polymeric dye image-receiving layer having a Tg of less than about 25.degree. C.
摘要:
Thermally processable imaging elements in which the image is formed by imagewise heating or by imagewise exposure to light followed by uniform heating include an adhesive interlayer interposed between the imaging layer and a protective overcoat layer. The adhesive interlayer, which is comprised of a polymer having pyrrolidone functionality, strongly bonds the overcoat layer to the imaging layer.
摘要:
In accordance with this invention a diffusion transfer process is provided for forming a color photographic image comprising the steps of: (a) using an integral element comprising one and only one dimensionally stable layer comprising a coating support, and coated thereon in reactive association a mordant layer comprising a material which binds a diffusible dye, an imaging layer comprising radiation sensitive silver halide, a diffusible dye forming layer comprising a diffusible dye forming compound, and a barrier layer overlaying said diffusible dye forming layer, wherein said support is selected from the group consisting of reflection base and transparent base materials, wherein said diffusible dye forming layer is the same or different than said imaging layer, wherein said barrier layer comprises a polymer that allows the passage of solutions for processing said element when said element is contacted with an external processing bath, and wherein said barrier layer impedes the diffusion out of said element of the diffusible dye formed from said diffusible dye forming compound; (b) exposing said element to actinic radiation; (c) processing said element by contacting said element to an external bath containing compounds selected from the group consisting of conventional color developer compounds of the primary amine type, compounds which activate the release of incorporated color developers, and compounds which activate development by incorporated dye developers; (d) washing said element to remove compounds imbibed in step (c). In a preferred embodiment said integral element further comprises a stripping layer coated intermediate the mordant layer and dye forming layer. In another preferred embodiment said process further comprises the step of stripping said mordant and support from said diffusible dye forming layer.
摘要:
A base for a photographic element is provided which comprises a support having disposed thereon a vanadium pentoxide antistatic layer and an overlying barrier layer of a heat-thickening polyacrylamide polymer having hydrophilic functionality, and a method for preparing it.
摘要:
A photographic element is disclosed comprised of a support and, coated on the support, at least one radiation-sensitive silver halide emulsion comprised of tabular silver halide grains and a dispersing medium. The emulsion includes as a vehicle methacrylate polymer latex capable of reducing pressure sensitivity having a glass transition temperature of less than 50.degree. C.
摘要:
Imaging elements, in particular image transfer assemblages and processes, are described wherein a stripping layer is employed to enable a layer containing a viewable image to be separated from other portions of the element. The stripping layer comprises certain N-alkyl substituted acylamide copolymers.
摘要:
A polymer composition of the formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, G, J, L, x, y, and z are as defined herein is useful as a temporary barrier between reactants in photographic materials. The barrier is particularly useful as a process timing layer in color image transfer film units.
摘要:
A dye-donor element for thermal dye transfer comprising a support having on one side thereof a dye layer and on the opposite side thereof a slipping layer comprising a lubricating material, and wherein a hydrophilic dye-barrier layer is located between the dye layer and the support, and a subbing layer is located between the dye-barrier layer and the support. The dye-barrier layer prevents wrong-way transfer of dye into the support which provides improved dye transfer densities. The subbing layer improves adhesion between the dye-barrier layer and the support.