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公开(公告)号：US08134019B2
公开(公告)日：2012-03-13
申请号：US12514782
申请日：2007-11-06
申请人： Eiichi Nakamura , Yutaka Matsuo , Akihiko Iwashita
发明人： Eiichi Nakamura , Yutaka Matsuo , Akihiko Iwashita
CPC分类号： C07C41/30 , B82Y30/00 , B82Y40/00 , C01B32/152 , C07C1/326 , C07C2604/00 , C07F7/0805 , C07F7/083 , C07F7/1876 , C07C13/62 , C07C43/21
摘要： The present invention provides a method for producing a fullerene derivative, comprising the organic group addition step B in which an organic group is further added by reacting at least a basic compound and a halogen compound with a fullerene derivative, which is obtained by addition of a hydrogen atom and an organic group in the organic group addition step A, in which an organic group is added by reacting at least a Grignard reagent and a polar substance with a fullerene or fullerene derivative.
摘要翻译： 本发明提供一种富勒烯衍生物的制造方法，其包括通过使至少碱性化合物与卤素化合物与富勒烯衍生物反应而进一步添加有机基团的有机基团添加工序B，所述富勒烯衍生物通过添加 氢原子和有机基团，其中通过至少使格利雅试剂和极性物质与富勒烯或富勒烯衍生物反应而加入有机基团。
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公开(公告)号：US20100048934A1
公开(公告)日：2010-02-25
申请号：US12514782
申请日：2007-11-06
申请人： Eiichi Nakamura , Yutaka Matsuo , Akihiko Iwashita
发明人： Eiichi Nakamura , Yutaka Matsuo , Akihiko Iwashita
CPC分类号： C07C41/30 , B82Y30/00 , B82Y40/00 , C01B32/152 , C07C1/326 , C07C2604/00 , C07F7/0805 , C07F7/083 , C07F7/1876 , C07C13/62 , C07C43/21
摘要： The present invention provides a method for producing a fullerene derivative, comprising the organic group addition step B in which an organic group is further added by reacting at least a basic compound and a halogen compound with a fullerene derivative, which is obtained by addition of a hydrogen atom and an organic group in the organic group addition step A, in which an organic group is added by reacting at least a Grignard reagent and a polar substance with a fullerene or fullerene derivative.
摘要翻译： 本发明提供一种富勒烯衍生物的制造方法，其包括通过使至少碱性化合物与卤素化合物与富勒烯衍生物反应而进一步添加有机基团的有机基团添加工序B，所述富勒烯衍生物通过添加 氢原子和有机基团，其中通过至少使格利雅试剂和极性物质与富勒烯或富勒烯衍生物反应而加入有机基团。
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公开(公告)号：US09039935B2
公开(公告)日：2015-05-26
申请号：US12299898
申请日：2007-05-02
IPC分类号： H01B1/00 , H01B1/12 , H01B1/04 , H01L31/00 , C07C63/49 , B82Y10/00 , H01L51/00 , H01L31/04 , H01L51/42
CPC分类号： C07C63/49 , B82Y10/00 , H01B1/04 , H01L31/04 , H01L51/0047 , H01L51/42 , Y02E10/50 , Y02E10/549 , Y10S977/738 , Y10S977/948
摘要： The present invention provides a photoelectric conversion material comprising a fullerene derivative represented by the formula C60(R1)5(R2), wherein each R1 independently represents an organic group having a substituent; and R2 represents a hydrogen atom or a substituted or unsubstituted C1-C30 hydrocarbon group. Further, the present invention also provides a photoelectric conversion device having a self-assembled monomolecular film of the photoelectric conversion material, and a solar cell having the photoelectric conversion device.
摘要翻译： 本发明提供一种光电转换材料，其包含由式C60（R1）5（R2）表示的富勒烯衍生物，其中每个R 1独立地表示具有取代基的有机基团。 并且R 2表示氢原子或取代或未取代的C 1 -C 30烃基。 此外，本发明还提供一种具有光电转换材料的自组装单分子膜的光电转换装置和具有光电转换装置的太阳能电池。
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公开(公告)号：US20110005597A1
公开(公告)日：2011-01-13
申请号：US12668141
申请日：2008-07-03
IPC分类号： H01L31/04
CPC分类号： H01L51/0094 , B82Y10/00 , C07F7/0805 , H01L51/0036 , H01L51/0037 , H01L51/0047 , H01L51/424 , Y02E10/549 , Y02P70/521 , Y10S977/734 , Y10S977/735
摘要： The present invention provides a photoelectric conversion device having at least a fullerene derivative as an electron acceptor and a compound as an electron donor between a pair of electrodes, wherein the fullerene derivative has 2 to 4 organic groups which each independently have 1 to 50 carbon atoms, and wherein when the fullerene derivative has two organic groups, these organic groups do not bind to each other to form a ring.
摘要翻译： 本发明提供了一种在一对电极之间至少具有富勒烯衍生物作为电子受体和作为电子给体的化合物的光电转换装置，其中富勒烯衍生物具有2至4个各自独立地具有1至50个碳原子的有机基团 ，并且其中当富勒烯衍生物具有两个有机基团时，这些有机基团彼此不结合形成环。
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公开(公告)号：US20090118527A1
公开(公告)日：2009-05-07
申请号：US12294002
申请日：2007-03-15
申请人： Eiichi Nakamura , Yutaka Matsuo , Takahiro Nakae
发明人： Eiichi Nakamura , Yutaka Matsuo , Takahiro Nakae
CPC分类号： C07C67/347 , C07C2604/00 , C07F17/00 , C07F17/02 , Y10S977/734 , Y10S977/74 , C07C69/65 , C07C69/76 , C07C69/608
摘要： The present invention provides a method for producing a fullerene derivative comprising reacting: a serene; an organometallic reagent (A) comprising B, Al, Zn, Sn, Pb, Te, Ti, Mn, Zr or Sm; and a copper compound (B).
摘要翻译： 本发明提供一种富勒烯衍生物的制造方法，其包括： 包含B，Al，Zn，Sn，Pb，Te，Ti，Mn，Zr或Sm的有机金属试剂（A） 和铜化合物（B）。
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公开(公告)号：US20090101200A1
公开(公告)日：2009-04-23
申请号：US12299894
申请日：2007-05-02
CPC分类号： C07F17/00 , B82Y10/00 , C07F17/02 , H01L51/0047 , H01L51/0077 , H01L51/0083 , H01L51/4253 , Y02E10/549
摘要： The present invention provides a photoelectric conversion material comprising a fullerene derivative represented by the formula C60(R1)5(MLn), wherein: each R1 independently represents an organic group having a substituent; M represents a metal atom; L is a ligand of M; and n is the number of Ls. Further, the present invention also provides a photoelectric conversion device having a self-assembled monomolecular film of the photoelectric conversion material, and a solar cell having the photoelectric conversion device.
摘要翻译： 本发明提供了包含式C60（R1）5（MLn）表示的富勒烯衍生物的光电转换材料，其中：各R1独立地表示具有取代基的有机基团; M表示金属原子; L是M的配体; 而n是Ls的数量。 此外，本发明还提供一种具有光电转换材料的自组装单分子膜的光电转换装置和具有光电转换装置的太阳能电池。
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公开(公告)号：US07790913B2
公开(公告)日：2010-09-07
申请号：US12294002
申请日：2007-03-15
申请人： Eiichi Nakamura , Yutaka Matsuo , Takahiro Nakae
发明人： Eiichi Nakamura , Yutaka Matsuo , Takahiro Nakae
CPC分类号： C07C67/347 , C07C2604/00 , C07F17/00 , C07F17/02 , Y10S977/734 , Y10S977/74 , C07C69/65 , C07C69/76 , C07C69/608
摘要： The present invention provides a method for producing a fullerene derivative comprising reacting: a fullerene; an organometallic reagent (A) comprising B, Al, Zn, Sn, Pb, Te, Ti, Mn, Zr or Sm; and a copper compound (B).
摘要翻译： 本发明提供一种富勒烯衍生物的制造方法，其特征在于：使富勒烯 包含B，Al，Zn，Sn，Pb，Te，Ti，Mn，Zr或Sm的有机金属试剂（A） 和铜化合物（B）。
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公开(公告)号：US08552289B2
公开(公告)日：2013-10-08
申请号：US12668141
申请日：2008-07-03
IPC分类号： H01L31/04
摘要： The present invention provides a photoelectric conversion device having at least a fullerene derivative as an electron acceptor and a compound as an electron donor between a pair of electrodes, wherein the fullerene derivative has 2 to 4 organic groups which each independently have 1 to 50 carbon atoms, and wherein when the fullerene derivative has two organic groups, these organic groups do not bind to each other to form a ring.
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公开(公告)号：US08153835B2
公开(公告)日：2012-04-10
申请号：US12281294
申请日：2006-11-02
申请人： Eiichi Nakamura , Yutaka Matsuo , Yu-Wu Zhong , Ayako Muramatsu
发明人： Eiichi Nakamura , Yutaka Matsuo , Yu-Wu Zhong , Ayako Muramatsu
CPC分类号： C07F17/02 , C07F7/0805 , C07F17/00
摘要： The present invention provides a fullerene derivative represented by the following formula (1):wherein in formula (1), R1 is a substituted or unsubstituted organic group or a hydrogen atom, and wherein in formulae (2) and (3): W is a single bond, C1-C11, alkylene, C2-C12 alkenylene, or C2-C12 alkynylene, wherein any —CH2— in the alkylene, alkenylene or alkynylene can be substituted with —O—, —S—, —COO—, or —OCO—; Z is an element belonging to group IVB; and R21 to R23 are each independently a substituted or unsubstituted C1-C20 alkyl group, a substituted or unsubstituted C2-C15 alkenyl group, or a substituted or unsubstituted C2-C15 alkynyl group.
摘要翻译： 本发明提供由下式（1）表示的富勒烯衍生物：式（1）中，R 1为取代或未取代的有机基团或氢原子，式（2）和（3）中，W为 单键，C1-C11，亚烷基，C2-C12亚烯基或C2-C12亚炔基，其中亚烷基，亚烯基或亚炔基中的任何-CH 2 - 可以被-O - ， - S - ， - COO-或 -OCO-; Z是属于IVB组的元素; 和R 21至R 23各自独立地为取代或未取代的C 1 -C 20烷基，取代或未取代的C 2 -C 15烯基或取代或未取代的C 2 -C 15炔基。
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公开(公告)号：US07547429B2
公开(公告)日：2009-06-16
申请号：US10854296
申请日：2004-05-27
申请人： Eiichi Nakamura , Yutaka Matsuo
发明人： Eiichi Nakamura , Yutaka Matsuo
CPC分类号： B82Y30/00 , B82Y40/00 , C01B32/15 , C01B32/152 , Y10S977/734 , Y10S977/735 , Y10S977/737
摘要： The present invention relates to a fullerene derivative having a partial structure represented by the general formula (I): wherein C1 to C8 are carbon atoms constituting a fullerene skeleton in which C6 to C8 are independently bonded to an organic group having 1 to 50 carbon atoms, and C1 is bonded to a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms.
摘要翻译： 本发明涉及具有由通式（I）表示的部分结构的富勒烯衍生物：其中C1至C8是构成富碳骨架的碳原子，其中C6至C8独立地键合到具有1至50个碳原子的有机基团 并且C1与取代或未取代的碳原子数1〜20的烷基结合。
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