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1.发明授权Process for the modification of aromatic polymers via phase transfer catalysis to produce polyarylene polymers and the use thereof 失效通过相转移催化改性芳族聚合物以制备聚亚芳基聚合物的方法及其用途
公开(公告)号：US4699634A
公开(公告)日：1987-10-13
申请号：US753020
申请日：1985-07-08
申请人： Elena S. Percec , George S. Li
发明人： Elena S. Percec , George S. Li
CPC分类号： C08G75/029 , C08G64/06 , Y10S525/933
摘要： A process for the modification of alkyl halogenated polyarylenes with a derivative compound comprising the steps of forming a mixture of the derivative compound with a phase transfer catalyst, wherein the derivative compound has the formulaH--Z or M--Tand Z is derived from a compound selected from the group consisting of water or alcohols, thiols, amines, iminos and imides containing at least one O, N or S atom bonded to the H, M is Na or K and T is derived from a compound selected from the group consisting of cyanides, iminos, imides, carboxyls and hydroxyl; combining the mixture with the alkyl halogenated polyarylene in an organic solvent to form a second mixture; agitating the second mixture until the desired degree of substitution has taken place and thereafter separating the modified polyarylene which contains a Z or a T group.
摘要翻译： 一种用衍生化合物改性烷基卤化聚亚芳基的方法，包括以下步骤：形成衍生化合物与相转移催化剂的混合物，其中衍生化合物具有式HZ或MT，Z衍生自选自 含有至少一个与H键合的O，N或S原子的水或醇，硫醇，胺，亚胺和酰亚胺的组分是Na或K，T衍生自选自氰化物，亚胺的化合物 ，酰亚胺，羧基和羟基; 将混合物与烷基卤代聚亚芳基在有机溶剂中混合以形成第二混合物; 搅拌第二混合物直到发生所需的取代度，然后分离出含有Z或T基团的改性聚亚芳基。
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2.发明授权Process for the modification of aromatic polymers via Friedel-Crafts reactions to produce novel polymers and the use thereof 失效通过Friedel-Crafts反应改性芳族聚合物以制备新型聚合物的方法及其用途
公开(公告)号：US4673717A
公开(公告)日：1987-06-16
申请号：US824129
申请日：1986-01-30
申请人： Elena S. Percec , George S. Li
发明人： Elena S. Percec , George S. Li
CPC分类号： B01D71/50 , B01D71/52 , B01D71/66 , C08G65/485 , C08G75/0286 , Y10S525/905
摘要： A process for the addition of pendant groups to polyarylenes comprises the steps of charging a reaction vessel with a solution of a polyarylene and a Friedel-Crafts catalysts; said polyarylene having the formula ##STR1## adding to the reaction vessel a pendant forming group G, wherein G is selected from the group consisting of sulfonyl halides, sulfonamide halides, alkylhalides, acylhalides and phosphorus acid halides; heating the contents of the reaction vessel to form a substituted polyarylene having the formula ##STR2## and thereafter recovering the substituted polyarylene. The substituted polyarylenes are novel and have utility as a semipermeable membrane and a process for the separation of gases therewith is also provided.
摘要翻译： 将侧基添加到聚亚芳基的方法包括以下步骤：用聚亚芳基和Friedel-Crafts催化剂的溶液装入反应容器; 所述具有式“IMAGE”的聚亚芳基向反应容器中加入侧基形成基团G，其中G选自磺酰卤，磺酰胺卤化物，烷基卤，酰卤和磷酰卤; 加热反应容器的内容物以形成具有式“IMAGE”的取代聚亚芳基，然后回收取代的聚亚芳基。 取代的聚亚芳基是新颖的并且可用作半透膜，并且还提供了用于分离气体的方法。
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公开(公告)号：US4596860A
公开(公告)日：1986-06-24
申请号：US657137
申请日：1984-10-03
申请人： Elena S. Percec , George S. Li
发明人： Elena S. Percec , George S. Li
CPC分类号： B01D71/52 , B01D71/50 , B01D71/66 , C08G65/485 , C08G75/0286 , Y10S525/905 , Y10T428/2975
摘要： A process for the addition of pendant groups to polyarylenes comprises the steps of charging a reaction vessel with a solution of a polyarylene and a Friedel-Crafts catalysts; said polyarylene having the formula ##STR1## adding to the reaction vessel a pendant forming group G, wherein G is selected from the group consisting of sulfonyl halides, sulfonamide halides, alkylhalides, acylhalides and phosphorus acid halides; heating the contents of the reaction vessel to form a substituted polyarylene having the formula ##STR2## and thereafter recovering the substituted polyarylene. The substituted polyarylenes are novel and have utility as a semipermeable membrane and a process for the separation of gases therewith is also provided.
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4.发明授权Process for the modification of aromatic polymers via Friedel-Crafts reactions to produce novel polymers and the use thereof 失效通过Friedel-Crafts反应改性芳族聚合物以制备新型聚合物的方法及其用途
公开(公告)号：US4684376A
公开(公告)日：1987-08-04
申请号：US824128
申请日：1986-01-30
申请人： Elena S. Percec , George S. Li
发明人： Elena S. Percec , George S. Li
CPC分类号： C08G75/0286 , B01D71/50 , B01D71/52 , B01D71/66 , C08G65/485 , Y10S525/905
摘要： A process for the addition of pendant groups to polyarylenes comprises the steps of charging a reaction vessel with a solution of a polyarylene and a Friedel-Crafts catalyst; said polyarylene having the formula ##STR1## adding to the reaction vessel a pendant forming group G, wherein G is selected from the group consisting of sulfonyl halides, sulfonamide halides, alkylhalides, acylhalides and phosphorus acid halides; heating the contents of the reaction vessel to form a substituted polyarylene having the formula ##STR2## and thereafter recovering the substituted polyarylene. The substituted polyarylenes are novel and have utility as a semipermeable membrane and a process for the separation of gases therewith is also provided.
摘要翻译： 将侧基添加到聚亚芳基的方法包括以下步骤：用聚亚芳基和Friedel-Crafts催化剂的溶液装入反应容器; 所述具有式“IMAGE”的聚亚芳基向反应容器中加入侧基形成基团G，其中G选自磺酰卤，磺酰胺卤化物，烷基卤，酰卤和磷酰卤; 加热反应容器的内容物以形成具有式“IMAGE”的取代聚亚芳基，然后回收取代的聚亚芳基。 取代的聚亚芳基是新颖的并且可用作半透膜，并且还提供了用于分离气体的方法。
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公开(公告)号：US4677164A
公开(公告)日：1987-06-30
申请号：US859519
申请日：1986-05-05
申请人： George S. Li , Muyen M. Wu , Elmer J. DeWitt
发明人： George S. Li , Muyen M. Wu , Elmer J. DeWitt
CPC分类号： C08L27/24
摘要： A composition comprising an intimate admixture of(a) 50 to 98 parts by weight of chlorinated poly(vinyl chloride) and(b) 50 to 2 parts by weight of an addition tetrapolymer containing the following monomers combined in the polymer structure in the following weight percentages:______________________________________ Weight Percent______________________________________Acrylonitrile 15-35Methyl methacrylate 5-45Indene 5-45.alpha.-methylstyrene or 5-45styrene or amixture of both______________________________________Where (a) plus (b) total 100 parts by weight, and the total parts by weight of combined indene plus .alpha.-methyl styrene plus styrene in the tetrapolymer (b) is 38-70 parts by weight.
摘要翻译： 一种组合物，其包含（a）50至98重量份的氯化聚（氯乙烯）和（b）50至2重量份的加成四聚物的混合物，所述四元共聚物包含以下列重量组合在聚合物结构中的以下单体 百分比：重量百分比 - 丙烯腈15-35-甲基丙烯酸甲酯5-45-内酯5-45-α-甲基苯乙烯或5-45-苯乙烯或二者的混合物 - 其中（a）加（b）总共100份 并且在四元共聚物（b）中的组合茚和α-甲基苯乙烯加苯乙烯的总重量份数为38-70重量份。
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公开(公告)号：US4596856A
公开(公告)日：1986-06-24
申请号：US789542
申请日：1985-10-21
申请人： Muyen M. Wu , Elmer J. DeWitt , George S. Li
发明人： Muyen M. Wu , Elmer J. DeWitt , George S. Li
摘要： A composition comprising an intimate admixture of(a) 50 to 98 parts by weight of a vinyl chloride polymer having an inherent viscosity of at least 0.4 and(b) 50 to 2 parts by weight of a random addition tetrapolymer containing the following monomers combined in the polymer structure in the following weight percentages:______________________________________ Weight Percent______________________________________Acrylonitrile 15-35Methyl methacrylate 5-45Indene 5-45.alpha.-methylstyrene or 5-45styrene or amixture of both______________________________________where (a) plus (b) total 100 parts by weight, and the total parts by weight of combined indene plus .alpha.-methyl styrene plus styrene in the tetrapolymer (b) is 38-70 parts by weight.
摘要翻译： 一种组合物，其包含（a）50至98重量份的特性粘度为至少0.4的氯乙烯聚合物和（b）50至2重量份的包含以下单体的无规加成四元共聚物的紧密混合物 以下重量百分比的聚合物结构： - 重量百分比 - 丙烯腈15-35-甲基丙烯酸甲酯5-45-内酯5-45-α-甲基苯乙烯或5-45-苯乙烯或二者的混合物 - 其中（a）加 （b）总共100重量份，并且四元共聚物（b）中的组合茚和α-甲基苯乙烯加苯乙烯的总重量份数为38-70重量份。
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7.发明授权
公开(公告)号：US4508787A
公开(公告)日：1985-04-02
申请号：US217482
申请日：1980-12-17
CPC分类号： C08J7/047 , C08J7/12 , C08J2335/00 , C08J2435/00 , Y10T428/31721
摘要： A protective coating which is resistant to attack by basic solutions is formed from interpolymers containing maleic anhydride (MAH). An article is coated with a solution of the dissolved ammonium or amine salts of the MAH interpolymer, or if the article itself contains MAH the salts may alternatively be formed on the surface of the article by applying a basic solution containing the ammonium or amine ions. The article is then dried and heated at a temperature sufficient to form the cyclic imide structure from the ammonium or amine salt of the MAH, typically about 160 to 200.degree. C.
摘要翻译： 耐碱性溶液侵蚀的保护涂层由含有马来酸酐（MAH）的互聚物形成。 用MAH互聚物的溶解的铵盐或胺盐的溶液涂覆制品，或者如果制品本身含有MAH，则可以通过施加含有铵或胺离子的碱性溶液在制品的表面上形成盐。 然后将制品干燥并在足以从MAH的铵盐或胺盐形成环状酰亚胺结构的温度下加热，通常约160至200℃。
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公开(公告)号：US4289668A
公开(公告)日：1981-09-15
申请号：US196885
申请日：1980-10-14
申请人： George S. Li
发明人： George S. Li
CPC分类号： C08K5/09
摘要： A plasticized resin system is described, and the system comprises an intimate mixture of(a) an interpolymer derived from at least one vinyl monomer and an .alpha.,.beta.- unsaturated dicarboxylic acid, anhydride or the lower alkyl esters thereof, and(b) a plasticizing amount of a hydroxy substituted fatty acid containing at least about eight carbon atoms.The plasticized resin system also may contain at least one additional polar resin such as polycarbonates, polysulfones, polyesters, etc. The use of the hydroxy substituted fatty acid in this manner improves the processability of the interpolymers.
摘要翻译： 描述了增塑树脂体系，并且该体系包含（a）衍生自至少一种乙烯基单体的互聚物和α，β-不饱和二羧酸，酸酐或其低级烷基酯的紧密混合物，和（b） 含有至少约8个碳原子的羟基取代的脂肪酸的增塑量。 增塑树脂体系还可以含有至少一种额外的极性树脂，例如聚碳酸酯，聚砜，聚酯等。以这种方式使用羟基取代的脂肪酸改善了互聚物的加工性能。
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公开(公告)号：US4162277A
公开(公告)日：1979-07-24
申请号：US909323
申请日：1978-05-24
申请人： George S. Li , Irving Rosen
发明人： George S. Li , Irving Rosen
IPC分类号： C08L45/00 , C08L101/00 , C08L69/00
CPC分类号： C08L101/00 , C08L45/00
摘要： Certain physical properties, such as heat-distortion temperature and flexural modulus, of certain commercially available thermoplastic resins are improved by blending with polyindene or coumarone-indene resins.
摘要翻译： 某些商业上可获得的热塑性树脂的某些物理性能如热变形温度和挠曲模量通过与多茚或香豆酮 - 茚树脂共混来提高。
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公开(公告)号：US4100226A
公开(公告)日：1978-07-11
申请号：US753919
申请日：1976-12-23
申请人： George S. Li
发明人： George S. Li
IPC分类号： C08F289/00 , C08F255/10 , C08F279/02
CPC分类号： C08F255/10 , Y10S525/905
摘要： Graft polymers of indene onto chlorobutyl rubber which have good impact resistance and high heat-distortion temperatures and blends of these graft polymers with commercially available thermoplastic resins are described.
摘要翻译： 描述了具有良好抗冲击性和高热变形温度的茚对氯丁基橡胶的接枝聚合物，以及这些接枝聚合物与市售热塑性树脂的共混物。
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