公开(公告)号：US4042609A

公开(公告)日：1977-08-16

申请号：US654350

申请日：1976-02-02

申请人： Emilio Perrotti ,  Mario Clerici

发明人： Emilio Perrotti ,  Mario Clerici

IPC分类号： B01J31/22 ,  B01J31/24 ,  C07C5/03 ,  C07F9/00 ,  C07F15/00 ,  C07F13/00

CPC分类号： B01J31/2291 ,  B01J31/2295 ,  B01J31/24 ,  B01J31/2404 ,  C07C5/03 ,  C07F15/0033 ,  C07F9/00 ,  B01J2231/641 ,  B01J2231/70 ,  B01J2531/74 ,  B01J2531/827 ,  C07C2531/22

摘要： A compound having catalytic properties which is a .sigma. or .pi. organic complex of a transition metal represented by the general formula: M (A).sub.n (L-C) (L).sub.m, wherein M is Ir or Re; L is a member of the group consisting of alkyl and aryl phosphines; (L-C) is (a) an alkyl or aryl phosphine ligand wherein a C-H bond is reacted with the central M atom to which the ligand is coordinated, and a metal-carbon bond is formed, or (b) a .pi.-allyl radical; A is a linear monoolefin having from 2 to 5 carbon atoms or a cyclic monoolefin having from 6 to 8 carbon atoms; n is a number in the range of 0 to 2 and is always zero when L-C is a .pi.-allyl radical; and m is a number from 1 to 3 which satisfies the valence of M, is prepared by reacting a hydride complex represented by the general formula: MHLn.sub.1 wherein M and L have the meaning given above, x is in the range from 5 to 7 and n.sub.1 is a number from 2 to 3 which satisfies the valence of M, with a linear monoolefin having from 2 to 5 carbon atoms or a cyclic monoolefin having from 6 to 8 carbon atoms.

摘要翻译： 具有催化性质的化合物，其为由通式M（A）n（L-C）（L）m表示的过渡金属的σ或π有机络合物，其中M为Ir或Re; L是由烷基和芳基膦组成的组的成员; （L-C）是（a）烷基或芳基膦配体，其中C-H键与配位体配位的中心M原子反应，形成金属 - 碳键，或（b）吡咯烷基; A是具有2至5个碳原子的直链单烯烃或具有6至8个碳原子的环状单烯烃; n为0〜2的数，当L-C为吡啶基时，该数为0。 m为1〜3的数，其满足M的化合价，通过使由通式MHLn1表示的氢化物配合物反应制备，其中M和L具有上述含义，x在5至7的范围内， n1是2至3的数，其满足M的价数，具有2至5个碳原子的直链单烯烃或具有6至8个碳原子的环状单烯烃。

公开(公告)号：US3962250A

公开(公告)日：1976-06-08

申请号：US459125

申请日：1974-04-08

申请人： Carlo Neri ,  Emilio Perrotti

发明人： Carlo Neri ,  Emilio Perrotti

IPC分类号： C07F15/06 ,  C07F15/00 ,  C07D213/02 ,  C07D215/02

CPC分类号： C07F15/06 ,  C07F15/065

摘要： Processes are disclosed for preparing trivalent cobalt complexes having the formulas[Co.sup.III (L.sub.1 L.sub.2 L.sub.3 L.sub. 4)].sub.2 CR.sub.1 CR.sub.2 O.2CR.sub.1 R.sub.2 OH (1)and[Co.sup.III (L.sub.1 L.sub.2 L.sub.3 L.sub.4)] CR.sub.1 R.sub.2 0.CR.sub.1 R.sub.2 OH.B (2)wherein (L.sub.1 L.sub.2 L.sub.3 L.sub.4) is a planar tetradentate ligand selected from bis-(diacetylmonoximeimino)-propane, bis-(salicylaldehyde)-ethylenediamine and bis-(acetylacetone)-ethylenediamine; CR.sub.1 R.sub.2 O is an alcohol radical selected from CH.sub.3 O, ClCH.sub.2 CH.sub.2 O, .phi.CH.sub.2 O and CH.sub.2 =CH--CH.sub.2 O; CR.sub.1 R.sub.2 OH is the corresponding alcohol; and B is an amine base by reacting cobalt complex Co(L.sub.1 L.sub.2 L.sub.3 L.sub.4), alcohol CR.sub.1 R.sub.2 OH and amine base B with molecular oxygen at a temperature from 0.degree. to 70.degree.C.

公开(公告)号：US4562266A

公开(公告)日：1985-12-31

申请号：US602214

申请日：1984-04-19

申请人： Carlo Neri ,  Villiam Giroldini ,  Mario Traversoni ,  Guido Guizzi ,  Emilio Perrotti ,  Antonio Rinaldi

发明人： Carlo Neri ,  Villiam Giroldini ,  Mario Traversoni ,  Guido Guizzi ,  Emilio Perrotti ,  Antonio Rinaldi

IPC分类号： C07D307/79 ,  C07C37/20 ,  C07D307/86

CPC分类号： C07C37/20 ,  C07C37/52 ,  C07D307/86

摘要： Process for the preparation of 2,3-dihydro-2,2-dimethyl-7-benzofuranol, comprising the reaction between catechol or 4-tert.butyl catechol and isobutyraldehyde in the presence of catalytic amounts of at least one compound selected from the group consisting of the oxides, hydroxides, alcoholates and carboxylates of metals belonging to the Groups IA, IIA, IIB and VIIB of the Periodic System of the Elements and the subsequent reaction of rearrangement of the products which have been obtained, optionally previously removing one or more low-boiling components, in the presence of a compound having acidic properties, of an organic or a mineral nature. The product is useful in the synthesis of pesticides.

摘要翻译： 制备2,3-二氢-2,2-二甲基-7-苯并呋喃醇的方法，包括在催化量的至少一种选自下组的化合物的存在下，在儿茶酚或4-叔丁基邻苯二酚与异丁醛之间的反应 由属于元素周期系统的IA，IIA，IIB和VIIB族的金属的氧化物，氢氧化物，醇化物和羧酸盐组成，以及随后的已经获得的产物的重排反应，任选地预先除去一个或多个 在具有酸性的化合物的存在下，有机或矿物性质的低沸点成分。 该产品可用于合成农药。

公开(公告)号：US3980690A

公开(公告)日：1976-09-14

申请号：US491862

申请日：1974-07-25

申请人： Gioacchino Cipriani ,  Emilio Perrotti

发明人： Gioacchino Cipriani ,  Emilio Perrotti

IPC分类号： C07C69/96 ,  B01J23/00 ,  B01J31/16 ,  B01J31/18 ,  C07B61/00 ,  C07C68/00

CPC分类号： B01J31/181 ,  B01J31/1805 ,  C07C68/005 ,  B01J2531/16

摘要： An alcohol is carboxylated into the corresponding carbonate by reacting the alcohol with oxygen and carbon dioxide in the presence of a catalyst system in the heterogeneous phase by introducing the reactants into a reactor charged with a catalyst, such as the complex system formed by copper and 4-vinylpyridine, causing the reactants to flow over the catalyst, and then withdrawing the products of the reaction and unconsumed reactants from the reactor.

摘要翻译： 通过将反应物引入装有催化剂的反应器，例如铜和4形成的复合体系中，通过在非均相阶段的催化剂体系存在下，使醇与氧和二氧化碳反应，将醇羧化成相应的碳酸酯 - 乙烯基吡啶，使反应物流过催化剂，然后从反应器中取出反应产物和未消耗的反应物。

公开(公告)号：USRE29338E

公开(公告)日：1977-08-02

申请号：US727348

申请日：1976-09-28

申请人： Emilio Perrotti ,  Gioacchino Cipriani

发明人： Emilio Perrotti ,  Gioacchino Cipriani

IPC分类号： C07C68/00

CPC分类号： C07C68/005

摘要： A process is described whereby carbonic acid esters, i.e., alkyl, aryl and cycloalkyl carbonates, are prepared by reacting an alcohol with oxygen and carbon monoxide in the presence of a catalyst selected from copper complexed with an organic molecule.

公开(公告)号：US3975430A

公开(公告)日：1976-08-17

申请号：US551609

申请日：1975-02-21

申请人： Carlo Neri ,  Emilio Perrotti

发明人： Carlo Neri ,  Emilio Perrotti

IPC分类号： C07C303/20 ,  C07C143/02

CPC分类号： C07C303/20

摘要： Long chain alkyl sulphonates, adapted for use as detergents, are prepared by adding alkali metal bisulphite to a stoichiometric excess of alpha-olefines having from 10 to 20 carbon atoms, in a liquid solvent mixture of alcohol and water having a weight ratio in the range from 1.2 to 2.5, in the presence of oxygen and an oxide or salt of manganese at a temperature not in excess of the boiling point of the solvent mixture, and a pH in the range of 8.5 to 2, wherein the ratio of solvent to olefines is between 6/1 and 2/1.

摘要翻译： 适用于洗涤剂的长链烷基磺酸盐是通过在醇和水的液体溶剂混合物中加入碱金属亚硫酸氢盐至化学计量过量的具有10至20个碳原子的α-烯烃而制备的，重量比范围为 1.2至2.5，在氧气和锰的氧化物或盐的存在下，在不超过溶剂混合物的沸点的温度下，pH在8.5至2的范围内，其中溶剂与烯烃的比例 在6/1和2/1之间。

公开(公告)号：US3966782A

公开(公告)日：1976-06-29

申请号：US524311

申请日：1974-11-15

申请人： Gioacchino Cipriani ,  Emilio Perrotti

发明人： Gioacchino Cipriani ,  Emilio Perrotti

IPC分类号： C07C231/00 ,  C07B61/00 ,  C07C67/00 ,  C07C231/06 ,  C07C257/04 ,  C07F1/08

CPC分类号： C07F1/08

摘要： A copper compound having the general formula: ##EQU1## wherein the copper is in the .sup.+1 oxidation state; R, the same or different, is hydrogen, methyl or phenyl; and R' is ethyl or methyl, is prepared by reacting a monovalent copper salt such as CuBr with an alkali metal alkoxide in the presence of a mixture of an alcohol and a nitrile under anhydrous conditions and in an atmosphere of an inert gas.

摘要翻译： 一种具有以下通式的铜化合物：R | Cu1-C-C = NH，|| ROR'，其中铜处于+ 1氧化态; R，相同或不同，是氢，甲基或苯基; 和R'是乙基或甲基，是通过在无水条件下和惰性气体气氛下，在醇和腈的混合物存在下，使一价铜盐如CuBr与碱金属醇盐反应制备的。

公开(公告)号：US4100208A

公开(公告)日：1978-07-11

申请号：US460222

申请日：1974-04-11

申请人： Federico Maspero ,  Emilio Perrotti

发明人： Federico Maspero ,  Emilio Perrotti

IPC分类号： C07C29/00

CPC分类号： C07C29/00

摘要： Process for production of ethylenic compounds by hydrogenating the corresponding alkynol with isopropyl alcohol in the presence of a metal complex such as IrH.sub.3 CO(P.phi..sub.3).sub.2 and IrH.sub.3 (P.phi..sub.3).sub.2.

摘要翻译： 在金属络合物如IrH 3 CO 3（P ph 3）2和IrH 3（P 3））2的存在下，用异丙醇氢化相应的炔醇来制备烯属化合物的方法。

公开(公告)号：US4064146A

公开(公告)日：1977-12-20

申请号：US616630

申请日：1975-09-25

申请人： Carlo Neri ,  Emilio Perrotti

发明人： Carlo Neri ,  Emilio Perrotti

IPC分类号： C07D303/32 ,  C07D301/22

CPC分类号： C07D303/32

摘要： An alpha-substituted epoxide, represented by the formula: ##STR1## wherein R, R' and R"' are alkyl having up to 12 C atoms and R" is hydrogen, is prepared by oxidizing, with molecular oxygen, the corresponding alcohol, represented by the formula: ##STR2## wherein R, R', R" and R"' have the meaning given above, in the presence of a catalyst consisting of a monovalent copper complex.

摘要翻译： 由下式表示的α-取代的环氧化物：其中R，R'和R“'是具有至多12个C原子的烷基和R”是氢的烷基，其通过用分子氧氧化相应的 醇，由下式表示：其中R，R'，R“和R”'具有上述含义，在由一价铜络合物组成的催化剂存在下。

公开(公告)号：US4042595A

公开(公告)日：1977-08-16

申请号：US655052

申请日：1976-02-04

申请人： Paolo Koch ,  Emilio Perrotti

发明人： Paolo Koch ,  Emilio Perrotti

IPC分类号： C07D263/22 ,  C07D277/14 ,  C07D339/06

CPC分类号： C07D277/14 ,  C07D263/22

摘要： A ketonic heterocyclic compound having at least two heteroatoms in the ring is prepared by reacting a difunctional compound having the general formula ##STR1## in which R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are members of the group consisting of aliphatic, aromatic, cycloaliphatic and heterocyclic hydrocarbons which may contain functional groups selected from --OH, --OR.sub.5, --COOH, --COOR.sub.5, --CN, --Cl, --Br, --I, --F, and --CO--R.sub.5, wherein R.sub.5 is an aliphatic, aromatic, cycloaliphatic or heterocyclic hydrocarbon; X is oxygen or sulphur; Y is sulphur or nitrogen; n is an integer ranging from 1 to 3, or zero; R.sub.6 is a hydrogen or a hydrocarbon radical included in the above definition of R.sub.1 R.sub.2 R.sub.3 and R.sub.4 ; and m is the valence of Y, with carbon monoxide and oxygen in the presence of a catalyst selected from selenium, selenium compounds and complexes of copper, in the temperature range of from room temperature to 80.degree. C and in the pressure range of from 1 to 10 atmospheres.

摘要翻译： 在环中具有至少两个杂原子的酮类杂环化合物通过使具有通式“IMAGE”的二官能化合物与其中R 1，R 2，R 3和R 4为脂族，芳族，脂环族和杂环烃 其可以包含选自-OH，-OR 5，-COOH，-COOR 5，-CN，-Cl，-Br，-I，-F和-CO-R 5的官能团，其中R 5是脂族，芳族，脂环族或 杂环烃; X是氧或硫; Y是硫或氮; n是1至3的整数，或为零; R6是上述R1R2 R3和R4定义中包含的氢或烃基; 在选自硒，硒化合物和铜络合物的催化剂存在下，在室温至80℃的温度范围内，并且在1的压力范围内，m是Y的化合价与一氧化碳和氧气 至10个大气压。