公开(公告)号：US5098521A

公开(公告)日：1992-03-24

申请号：US639097

申请日：1991-01-09

申请人： Enrique Freudenberg ,  Friedrich Linhart ,  Rainer Tresch ,  Heinrich Hartmann ,  Walter Denzinger ,  Michael Kroener ,  Norbert Sendhoff

发明人： Enrique Freudenberg ,  Friedrich Linhart ,  Rainer Tresch ,  Heinrich Hartmann ,  Walter Denzinger ,  Michael Kroener ,  Norbert Sendhoff

IPC分类号： D21H21/04 ,  D21H17/34 ,  D21H17/37 ,  D21H17/41 ,  D21H21/10 ,  D21H27/00

CPC分类号： D21H17/34

摘要： Paper, board and cardboard are produced from paper stocks containing foreign substances by drainage in the presence of a polymer which contains, as typical polymerized constituents, units of the formulae ##STR1## where R.sup.1 and R.sup.2 are each H, C.sub.1 -C.sub.3 -alkyl, and which have K values of not less than 130, the polymers containing less than 10 mol % of units of the formula II.

摘要翻译： 纸，纸板和纸板由含有外来物质的纸料在含有作为典型聚合成分的聚合物存在下通过排水生产，所述聚合物包含式（I）和（IMA）（II）的单元，其中R 1和R 2 各自为H，C 1 -C 3 - 烷基，并且其K值不小于130，所述聚合物含有小于10摩尔％的式II的单元。

公开(公告)号：US5126395A

公开(公告)日：1992-06-30

申请号：US662622

申请日：1990-02-28

申请人： Lutz End ,  Walter Denzinger ,  Michael Kroener ,  Norbert Sendhoff ,  Enrique Freudenberg ,  Friedrich Linhart ,  Rolf Fikentscher ,  Heinrich Hartmann

发明人： Lutz End ,  Walter Denzinger ,  Michael Kroener ,  Norbert Sendhoff ,  Enrique Freudenberg ,  Friedrich Linhart ,  Rolf Fikentscher ,  Heinrich Hartmann

IPC分类号： C08F2/32 ,  C08F2/44 ,  C08F4/28 ,  C08F4/34 ,  C08F8/12 ,  C08F26/00 ,  C08F26/02 ,  C08K3/30 ,  C08K5/21 ,  D21H17/34 ,  D21H21/10

CPC分类号： D21H21/10 ,  C08F26/02 ,  C08F8/44 ,  C08K3/30 ,  C08K5/21 ,  D21H17/34

摘要： Stable water-in-oil emulsions of a hydrolyzed polymer of an N-vinylamide of the formula ##STR1## where R and R.sup.1 are each H or C.sub.1 -C.sub.6 -alkyl, are prepared by polymerizing a compound of the formula I, alone or as a mixture with other monoethylenically unsaturated monomers, in the form of a water-in-oil emulsion to give a water-in-oil polymer emulsion, and then hydrolyzing the polymer, hydrolysis of the polymer in the form of the water-in-oil polymer emulsion being carried out in the presence of an acid or base, and additives in the form of antioxidants, reducing agents or aldehyde acceptors being added for stabilization.

摘要翻译： 式（Ⅰ）的N-乙烯基酰胺的水解聚合物的稳定的油包水乳液，其中R和R 1各自为H或C 1 -C 6 - 烷基，是通过将式I化合物， 单独或作为与其它单烯键式不饱和单体的混合物，以油包水乳液的形式提供油包水聚合物乳液，然后水解聚合物，水解形式的聚合物， 在酸或碱的存在下进行油包水聚合物乳液，以及为了稳定而加入抗氧化剂，还原剂或醛受体形式的添加剂。

公开(公告)号：US5145559A

公开(公告)日：1992-09-08

申请号：US641852

申请日：1991-01-16

申请人： Werner Auhorn ,  Friedrich Linhart ,  Primoz Lorencak ,  Michael Kroener ,  Norbert Sendhoff ,  Walter Denzinger ,  Heinrich Hartmann

发明人： Werner Auhorn ,  Friedrich Linhart ,  Primoz Lorencak ,  Michael Kroener ,  Norbert Sendhoff ,  Walter Denzinger ,  Heinrich Hartmann

IPC分类号： C08F8/12 ,  D21H17/34 ,  D21H17/36

CPC分类号： D21H17/34

摘要： Paper, board and cardboard are produced by draining a paper stock, containing undesirable substances, in the presence of hydrolyzed homo- and/or copolymers of N-vinylformamide having a degree of hydrolysis of not less than 60% and a cationic retention aid. According to the invention, faster drainage and improved retention are obtained compared with the use of known fixing agents.

摘要翻译： 在水解度不低于60％的N-乙烯基甲酰胺和阳离子助留剂的水解均聚物和/或共聚物的存在下，通过排出含有不需要的物质的纸料来制造纸，纸板和纸板。 根据本发明，与使用已知的固定剂相比，获得了更快的排水和改进的保留。

公开(公告)号：US5008321A

公开(公告)日：1991-04-16

申请号：US438034

申请日：1989-11-20

申请人： Heinrich Hartmann ,  Walter Denzinger ,  Michael Kroener ,  Norbert Sendhoff ,  Enrique Freudenberg

发明人： Heinrich Hartmann ,  Walter Denzinger ,  Michael Kroener ,  Norbert Sendhoff ,  Enrique Freudenberg

IPC分类号： B01F17/42 ,  C08F2/32 ,  C08F8/12 ,  C08F26/00 ,  C08F26/02 ,  D21F1/66 ,  D21H17/34

CPC分类号： C08F8/12 ,  D21H17/55 ,  D21H21/10 ,  C08F2800/20 ,  C08F2810/50

摘要： Stable water-in-oil emulsions of hydrolyzed polymers of N-vinylamides of the formula ##STR1## where R and R.sup.1 are each H or C.sub.1 -C.sub.6 -alkyl are prepared by polymerization of a compound of the formula I alone or as a mixture with other monoethylenically unsaturated monomers, in the form of a water-in-oil emulsion, to give a water-in-oil polymer emulsion, and subsequent hydrolysis of the polymer, by a process in which hydrolysis of the polymer in the form of the water-in-oil polymer emulsion is carried out in the presence of an acid or base and of from 1 to 30% by weight, based on the polymer, of an emulsifier which is obtainable by(A) reacting a C.sub.10 -C.sub.22 -fatty alcohol with epichlorohydrin in a molar ratio of from 1:0.5 to 1:1.5 to give a glycidyl ether,(B) reacting the glycidyl ether with (1) a saturated C.sub.2 -C.sub.6 -alcohol containing from 2 to 6 OH groups or (2) its monoether with a C.sub.10 -C.sub.22 -fatty alcohol, in a molar ratio of glycidyl ether to (1) or (2) of from 1:0.5 to 1:6, in the presence of an acid or base, and(C) alkoxylating the reaction product from (B) with one or more C.sub.2 -C.sub.4 -alkylene oxides in a molar ratio of from 1:1 to 1:6.The polymer emulsions obtainable in this manner are used as drainage aids, retention aids and flocculants in the making of paper and paper products.

摘要翻译： 式（I）的N-乙烯基酰胺的水解聚合物的稳定的油包水乳液，其中R和R 1各自为H或C 1 -C 6 - 烷基，其通过将式I化合物单独或作为 与油包水乳液形式的其它单烯键式不饱和单体的混合物，通过以下形式的水解方法得到油包水聚合物乳液，并随后水解聚合物 的油包水聚合物乳液在酸或碱的存在下进行，并且以聚合物为基础计，为1至30重量％的乳化剂，其可通过（A）使C10-C22 - 醇与摩尔比为1:0.5至1:1.5的醇，得到缩水甘油醚，（B）使缩水甘油醚与（1）含有2-6个OH基团的饱和C 2 -C 6醇反应，或 （2）其单醚与C 10 -C 22脂肪醇，其缩水甘油醚与（1）或（2）的摩尔比为1:0.5至1:6，在存在o （C）将（B）的反应产物与一种或多种摩尔比为1:1至1:6的C 2 -C 4 - 氧化烯烷氧基化。 以这种方式获得的聚合物乳液可用作造纸和纸制品中的助滤剂，助留剂和絮凝剂。

公开(公告)号：US5290880A

公开(公告)日：1994-03-01

申请号：US661180

申请日：1991-02-27

申请人： Dietmar Moench ,  Michael Kroener ,  Enrique Freudenberg ,  Heinrich Hartmann ,  Norbert Sendhoff

发明人： Dietmar Moench ,  Michael Kroener ,  Enrique Freudenberg ,  Heinrich Hartmann ,  Norbert Sendhoff

IPC分类号： C08F2/10 ,  C08F8/12 ,  C08F26/00 ,  C08F26/02

CPC分类号： C08F26/02 ,  C08F8/44

摘要： N-vinylformamide is polymerized with or without other water-soluble monoethylenically unsaturated monomers and with or without water-insoluble monoethylenically unsaturated monomers in not less than 30% strength by weight aqueous monomer solutions in the presence of a polymerization initiator at not more than 150.degree. C. in a kneader by a method in which the polymerization is carried out to such an extent that the initially formed water-containing polymer gel disintegrates into fine particles and the finely divided polymer obtainable in this manner is hydrolyzed, preferably in the kneader, so that not less than 0.1 mol % of the N-vinylformamide units present in the polymer are converted into vinylamine units. The polymers obtainable in this manner dissolve readily in water. The aqueous solutions are used, for example, in papermaking and tertiary oil production.

摘要翻译： N-乙烯基甲酰胺与或不与其它水溶性单烯键式不饱和单体聚合，并且在不超过150度的聚合引发剂存在下，在不低于30重量％的重量比单体水溶液中含有或不含水不溶性单烯属不饱和单体 在捏合机中，通过聚合进行到最初形成的含水聚合物凝胶分解成细颗粒的程度，并且以这种方式获得的细碎聚合物优选在捏合机中水解， 存在于聚合物中的不少于0.1mol％的N-乙烯基甲酰胺单元转化为乙烯胺单元。 以这种方式获得的聚合物容易溶于水。 水溶液用于例如造纸和三次油生产。

公开(公告)号：US5334287A

公开(公告)日：1994-08-02

申请号：US914926

申请日：1992-07-17

申请人： Heinrich Hartmann ,  Walter Denzinger ,  Michael Kroener ,  Claudia Nilz ,  Friedrich Linhart ,  Andreas Stange

发明人： Heinrich Hartmann ,  Walter Denzinger ,  Michael Kroener ,  Claudia Nilz ,  Friedrich Linhart ,  Andreas Stange

IPC分类号： C08F251/02 ,  C08F251/00 ,  D21H17/34 ,  D21H17/35 ,  D21H17/37 ,  D21H21/18 ,  D21H21/06 ,  D21H21/10

CPC分类号： C08F251/00 ,  D21H17/35 ,  D21H17/375 ,  D21H21/18

摘要： Graft polymers are obtainable by free radical polymerization of(A) monomers or monomer mixtures of(a) from 10 to 100% by weight of open-chain N-vinylcarboxamides(b) from 0 to 90% by weight of other, carboxyl-free monoethylenically unsaturated monomers which are copolymerizable with the monomers (a) and(c) from 0 to 5% by weight of monomers containing two or more ethylenically unsaturated, non-conjugated double bonds in the molecule, in the presence of(B) natural substances containing saccharide structures, such as mono-, oligo- and polysaccharides,in a weight ratio (A):(B) of from 95:5 to 20:80 and, if required, subsequent hydrolysis of the amido groups of the polymerized monomers (a) of the graft polymer with formation of amino groups, and said polymers are used as dry and wet strength agents for paper, board and cardboard.

摘要翻译： 接枝聚合物可以通过（A）单体或单体混合物（a）的自由基聚合获得，所述单体或单体混合物为（a）10至100重量％的开链N-乙烯基酰胺（b），0至90重量％的其它无羧基 在（B）天然物质的存在下，可以与单体（a）和（c）共聚合的单烯属不饱和单体0-5重量％的分子中含有两个或更多个烯属不饱和的非共轭双键的单体 含有糖结构，例如单糖，寡糖和多糖，重量比（A）：（B）为95:5至20:80，如果需要，随后水解聚合单体的酰胺基 a）形成氨基的接枝聚合物，并且所述聚合物用作纸，纸板和纸板的干和湿强度剂。

公开(公告)号：US5630907A

公开(公告)日：1997-05-20

申请号：US651655

申请日：1996-05-21

申请人： Claudia Nilz ,  Walter Denzinger ,  Heinrich Hartmann ,  Michael Kroener ,  Friedrich Linhart ,  Rudolf Schuhmacher ,  Dietmar Moench ,  Andreas Stange

发明人： Claudia Nilz ,  Walter Denzinger ,  Heinrich Hartmann ,  Michael Kroener ,  Friedrich Linhart ,  Rudolf Schuhmacher ,  Dietmar Moench ,  Andreas Stange

IPC分类号： C08F8/12 ,  D21H21/10

CPC分类号： C08F8/12 ,  C08J5/18 ,  C08F2810/50

摘要： Copolymers which are obtained by copolymerization ofa) from 5 to 99 mol % of N-vinylcarboxamides,b) from 95 to 1 mol % of monoethylenically unsaturated carboxylic acids and/or the alkali metal, alkaline earth metal, ammonium or amine salts thereof, and if required,c) up to 30 mol % of other monoethylenically unsaturated compounds, and if required,d) up to 2 mol % of crosslinking agents,and subsequent partial or complete elimination of the acyl groups from the N-vinylcarboxamides polymerized in the copolymer, with formation of amino or ammonium groups, are used as additives to paper stock for increasing the drainage rate and the retention in papermaking, and the dry and wet strength of the paper.

摘要翻译： 通过a）5〜99摩尔％的N-乙烯基酰胺共聚得到的共聚物，b）95〜1摩尔％的单烯属不饱和羧酸和/或其碱金属，碱土金属，铵或胺盐， 并且如果需要，c）至多30mol％的其它单烯键式不饱和化合物，如果需要，d）最多达2mol％的交联剂，随后部分或完全消除由乙烯基酰胺聚合的N-乙烯基酰胺 共聚物，形成氨基或铵基，被用作纸浆的添加剂，以增加造纸中的排水速率和保留性，以及纸的干和湿强度。

公开(公告)号：US5578678A

公开(公告)日：1996-11-26

申请号：US229636

申请日：1994-04-19

申请人： Heinrich Hartmann ,  Walter Denzinger ,  Michael Kroener ,  Claudia Nilz ,  Friedrich Linhart ,  Andreas Stange

发明人： Heinrich Hartmann ,  Walter Denzinger ,  Michael Kroener ,  Claudia Nilz ,  Friedrich Linhart ,  Andreas Stange

IPC分类号： C08F251/02 ,  C08F251/00 ,  D21H17/34 ,  D21H17/35 ,  D21H17/37 ,  D21H21/18 ,  D21H21/06 ,  D21H21/10

CPC分类号： C08F251/00 ,  D21H17/35 ,  D21H17/375 ,  D21H21/18

摘要： Graft polymers are obtainable by free radical polymerization of(A) monomers or monomer mixtures of(a) from 10 to 100% by weight of open-chain N-vinylcarboxamides(b) from 0 to 90% by weight of other, carboxyl-free monoethylenically unsaturated monomers which are copolymerizable with the monomers (a) and(c) from 0 to 5% by weight of monomers containing two or more ethylenically unsaturated, non-conjugated double bonds in the molecule,in the presence of(B) natural substances containing saccharide structures, such as mono-, oligo- and polysaccharides,in a weight ratio (A):(B) of from 95:5 to 20:80 and, if required, subsequent hydrolysis of the amido groups of the polymerized monomers (a) of the graft polymer with formation of amino groups, and said polymers are used as dry and wet strength agents for paper, board and cardboard.

摘要翻译： 接枝聚合物可以通过（A）单体或单体混合物（a）的自由基聚合获得，所述单体或单体混合物为（a）10至100重量％的开链N-乙烯基酰胺（b），0至90重量％的其它无羧基 在（B）天然物质的存在下，可以与单体（a）和（c）共聚合的单烯属不饱和单体0-5重量％的分子中含有两个或更多个烯属不饱和的非共轭双键的单体 含有糖结构，例如单糖，寡糖和多糖，重量比（A）：（B）为95:5至20:80，如果需要，随后水解聚合单体的酰胺基 a）形成氨基的接枝聚合物，并且所述聚合物用作纸，纸板和纸板的干和湿强度剂。

公开(公告)号：US5543459A

公开(公告)日：1996-08-06

申请号：US401617

申请日：1995-03-09

申请人： Heinrich Hartmann ,  Walter Denzinger ,  Michael Kroener ,  Claudia Nilz ,  Friedrich Linhart ,  Andreas Stange

发明人： Heinrich Hartmann ,  Walter Denzinger ,  Michael Kroener ,  Claudia Nilz ,  Friedrich Linhart ,  Andreas Stange

IPC分类号： C08F251/02 ,  C08F251/00 ,  D21H17/34 ,  D21H17/35 ,  D21H17/37 ,  D21H21/18 ,  D21H21/06 ,  D21H21/10

CPC分类号： C08F251/00 ,  D21H17/35 ,  D21H17/375 ,  D21H21/18

摘要： Graft polymers are obtainable by free radical polymerization of(A) monomers or monomer mixtures of(a) from 10 to 100% by weight of open-chain N-vinylcarboxamides(b) from 0 to 90% by weight of other, carboxyl-free moneothylenically unsaturated monomers which are copolymerizable with the monomers (a) and(c) from 0 to 5% by weight of monomers containing two or more ethylenically unsaturated, non-conjugated double bonds in the molecule, in the presence of(B) natural substances containing saccharide structures, such as mono-, oligo- and polysaccharides,in a weight ratio (A):(B) of from 95:5 to 20:80 and, if required, subsequent hydrolysis of the amido groups of the polymerized monomers (a) of the graft polymer with formation of amino groups, and said polymers are used as dry and wet strength agents for paper, board and cardboard.

摘要翻译： 接枝聚合物可以通过（A）单体或单体混合物（a）的自由基聚合获得，所述单体或单体混合物为（a）10至100重量％的开链N-乙烯基酰胺（b），0至90重量％的其它无羧基 在（B）天然物质的存在下，可以与单体（a）和（c）共聚合的0〜5重量％的分子中含有2个以上烯属不饱和的非共轭双键的单体的单体不饱和单体 含有糖结构，例如单糖，寡糖和多糖，重量比（A）：（B）为95:5至20:80，如果需要，随后水解聚合单体的酰胺基 a）形成氨基的接枝聚合物，并且所述聚合物用作纸，纸板和纸板的干和湿强度剂。

公开(公告)号：US5851300A

公开(公告)日：1998-12-22

申请号：US817644

申请日：1997-04-29

申请人： Friedrich Linhart ,  Andreas Stange ,  Rudolf Schuhmacher ,  Heinrich Hartmann ,  Walter Denzinger ,  Manfred Niessner ,  Claudia Nilz ,  Wolfgang Reuther ,  Hubert Meixner

发明人： Friedrich Linhart ,  Andreas Stange ,  Rudolf Schuhmacher ,  Heinrich Hartmann ,  Walter Denzinger ,  Manfred Niessner ,  Claudia Nilz ,  Wolfgang Reuther ,  Hubert Meixner

IPC分类号： C08B31/12 ,  C08B31/00 ,  C08G73/02 ,  C08G81/00 ,  D21H17/29 ,  D21H21/18 ,  C08B30/12 ,  C08B30/00 ,  D21H11/00

CPC分类号： C08G73/0213 ,  C08B31/00 ,  C08G81/00 ,  D21H17/29 ,  D21H21/18

摘要： In a cationic modification process for starch, starch is reacted with polymers that contain amino and/or ammonium groups in an aqueous medium at temperatures from 115.degree. C. to 180.degree. C. under an increased pressure and in the absence of oxidizers, polymerization initiators and alkali. The reaction is conducted so that maximum 10% by weight starch has its molar weight reduced. Also disclosed is the use of the thus obtained reaction products as dry strength agents for paper.

摘要翻译： PCT No.PCT / EP95 / 04075第 371日期1997年04月29日 102（e）1997年4月29日PCT PCT 1995年10月17日PCT公布。 第WO96 / 13525号公报 日期1996年5月9日在淀粉的阳离子改性方法中，淀粉与含水氨基和/或铵基团的聚合物在115℃至180℃的温度下在升高的压力下和在不存在 氧化剂，聚合引发剂和碱。 进行反应使得最大10重量％的淀粉具有降低的摩尔重量。 还公开了由此获得的反应产物作为纸的干强度剂的用途。