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    Preparation of indanes
    1.
    发明授权
    Preparation of indanes 失效
    制备茚满

    公开(公告)号：US4740646A

    公开(公告)日：1988-04-26

    申请号：US76592

    申请日：1987-07-23

    申请人： Erhard Henkes ,  Klaus Halbritter ,  Herbert Mayr ,  Wilhelm Striepe ,  Rudolf Pock

    发明人： Erhard Henkes ,  Klaus Halbritter ,  Herbert Mayr ,  Wilhelm Striepe ,  Rudolf Pock

    IPC分类号： C07C2/86

    CPC分类号： C07C2/861 ,  C07C2102/08 ,  C07C2527/135

    摘要： Indanes are prepared by reacting substituted or unsubstituted benzyl halides with olefins in the presence of a Lewis acid as catalyst by reacting benzyl halides I ##STR1## (where R.sup.1 and R.sup.2 =hydrogen, alkyl, alkoxy, cycloalkyl, aryl, aryloxy, aralkylR.sup.3 =R.sup.1, halogen or an ortho-fused ring systemX=halogen)with olefins II ##STR2## (where R.sup.4 to R.sup.7 =hydrogen or alkyl unbranched at alpha) in the presence of catalytic amounts of titanium tetrachloride.

    摘要翻译： 通过使苄基卤化物I I（其中R 1和R 2 =氢，烷基，烷氧基，环烷基，芳基，芳氧基，芳烷基R 3）的路易斯酸作为催化剂存在下，使取代或未取代的苄基卤与烯烃反应制备 = R1，卤素或邻位稠合的环体系X =卤素）与烯烃II（其中R 4至R 7 =氢或在α下未分支的烷基）在催化量的四氯化钛存在下反应。

    Method for the continuous separation by distillation of mixtures that contain morphonline (MO), monoaminodiglycol (ADG), ammonia and water by means of distillation
    2.
    发明授权
    Method for the continuous separation by distillation of mixtures that contain morphonline (MO), monoaminodiglycol (ADG), ammonia and water by means of distillation 有权
    通过蒸馏连续分离含有吗啉（MO），单氨基二甘醇（ADG），氨和水的混合物的方法

    公开(公告)号：US08293075B2

    公开(公告)日：2012-10-23

    申请号：US12443581

    申请日：2007-09-12

    申请人： Helmut Schmidtke ,  Oliver Buβmann ,  Ralph Versch ,  Udo Rheude ,  Uwe Leyk ,  Manfred Julius ,  Martin Rudloff ,  Erhard Henkes

    发明人： Helmut Schmidtke ,  Oliver Buβmann ,  Ralph Versch ,  Udo Rheude ,  Uwe Leyk ,  Manfred Julius ,  Martin Rudloff ,  Erhard Henkes

    IPC分类号： B01D3/14 ,  C07D295/02

    CPC分类号： C07C213/10 ,  C07D295/023 ,  C07C217/08

    摘要： Processes for the continuous fractional distillation of a mixture containing morpholine (MO), monoaminodiglycol (ADG), ammonia and water from a reaction of diethylene glycol (DEG) with ammonia, the process including: (i) separating off ammonia from the mixture at a top of a first distillation column K10; (ii) feeding a bottom fraction from K10 to a second distillation column K20, in which water and an organic product are separated off at the top at a temperature at the top in the range from 45 to 198° C. and a pressure in the range from 0.1 to 15 bar; (iii) feeding a bottom fraction from K20 to a third distillation column K30, wherein the column K30 is a dividing wall column (DWC)which preferably has a dividing wall (DW) in the longitudinal direction of the column to form an upper combined column region (1), a lower combined column region (6), an inflow part (2,4) having an enrichment section (2) and a stripping section (4), and also an offtake part (3,5) having an enrichment section (3) and a stripping section (5), with the bottoms from K20 being fed in in the upper or middle third of the inflow part (2,4), based on the number of theoretical plates of the inflow part, ADG and organic products having a boiling point of >190° C. (1.013 bar) being discharge at the bottom, organic products having a boiling point of ≦128° C. (1.013 bar) being discharge at a top and MO being discharge from the middle or lower third of the offtake part (3,5) (side offtake), based on the number of theoretical plates of the offtake part.

    摘要翻译： 从二甘醇（DEG）与氨的反应中连续分馏含有吗啉（MO），单胺二甘醇（ADG），氨和水的混合物的方法，该方法包括：（i）在 第一蒸馏塔K10顶部; （ii）将底部馏分从K10进料到第二蒸馏塔K20，在第二蒸馏塔K20中，水和有机产物在顶部分离出，顶部温度为45-98℃，压力为 范围为0.1至15巴; （iii）从K20向第三蒸馏塔K30供给底部馏分，其中塔K30是分隔壁塔（DWC），其在塔的纵向方向上优选具有分隔壁（DW），以形成上部混合塔 区域（1），下部组合柱区域（6），具有浓缩部分（2）和汽提部分（4）的流入部分（2,4），以及具有富集部分 （3）和汽提部分（5），其中来自K20的底部基于流入部分的理论塔板的数量，ADG和 沸点为> 190℃（1.013巴）的有机产物在底部排出，沸点为＆amp; NlE的有机产物; 128℃（1.013巴）在顶部排出，MO从 基于出料部分的理论塔板的数量，出口部分（3,5）（侧面）的中下三分之一。

    METHOD FOR THE CONTINUOUS SEPARATION OF MIXTURES COMPRISING MORPHOLINE (MO), MONOAMINODIGLYCOL (ADG), AMMONIA AND WATER BY MEANS OF DISTILLATION
    4.
    发明申请
    METHOD FOR THE CONTINUOUS SEPARATION OF MIXTURES COMPRISING MORPHOLINE (MO), MONOAMINODIGLYCOL (ADG), AMMONIA AND WATER BY MEANS OF DISTILLATION 有权
    通过蒸馏法连续分离包含摩尔（MO），单胺基（ADG），氨和水的混合物的方法

    公开(公告)号：US20100084257A1

    公开(公告)日：2010-04-08

    申请号：US12443563

    申请日：2007-09-12

    申请人： Helmut Schmidtke ,  Oliver Bussmann ,  Ralph Versch ,  Udo Rheude ,  Uwe Leyk ,  Manfred Julius ,  Martin Rudloff ,  Erhard Henkes

    发明人： Helmut Schmidtke ,  Oliver Bussmann ,  Ralph Versch ,  Udo Rheude ,  Uwe Leyk ,  Manfred Julius ,  Martin Rudloff ,  Erhard Henkes

    IPC分类号： C07C213/10 ,  C07D295/02 ,  B01D3/14 ,  C07C217/08

    CPC分类号： C07D295/027

    摘要： Processes for the continuous fractional distillation of a mixture comprising morpholine (MO), monoaminodiglycol (ADG), ammonia and water from a reaction of diethylene glycol (DEG) with ammonia, the process comprising: (i) separating off ammonia from the mixture at a top of a first distillation column K10; (ii) feeding a bottom fraction from K10 to a second distillation column K20 in which water and organic products are separated off at the top at a temperature at the top in the range from 45 to 198° C. and a pressure in the range from 0.1 to 15 bar, (iii) feeding a bottom fraction from K20 to a third distillation column K30, wherein the column K30 is a dividing wall column (DWC) which preferably has a dividing wall (DW) in the longitudinal direction of the column to form an upper combined column region (1), a lower combined column region (6), an inflow part (2, 4) having an enrichment section (2) and a stripping section (4), and also an offtake part (3, 5) having an enrichment section (3) and a stripping section (5), with the bottoms from K20 being fed in in the upper or middle third of the inflow part (2, 4), based on the number of theoretical plates of the inflow part, ADG and organic products having a boiling point of >190° C. (1.013 bar) being discharged at the bottom, organic products having a boiling point of ≦128° C. (1.013 bar) being discharged at the top and MO being discharged from the middle or lower third of the offtake part (3, 5) (side offtake), based on the number of theoretical plates of the offtake part.

    摘要翻译： 用于从二甘醇（DEG）与氨的反应连续分馏含有吗啉（MO），单氨基二甘醇（ADG），氨和水的混合物的方法，该方法包括：（i）在 第一蒸馏塔K10顶部; （ii）将底部馏分从K10进料至第二蒸馏塔K20，其中水和有机产物在顶部分离出，顶部温度为45-98℃，压力范围为 0.1至15巴，（iii）从K20向第三蒸馏塔K30供给底部馏分，其中塔K30是分隔壁塔（DWC），其优选在塔的纵向方向上具有分隔壁（DW）至 形成上部组合列区域（1），下部组合列区域（6），具有浓缩部分（2）和剥离部分（4）的流入部分（2,4），以及出口部分（3， 5）具有富集部分（3）和汽提部分（5），其中来自K20的底部在流入部分（2,4）的上部或中部三分之一中被输入，基于理论塔板的数量 流入部件，ADG和沸点> 190℃（1.013巴）的有机产物在底部排出，有机原料 沸点为＆nlE; 128℃（1.013巴）在顶部排出，MO从出料部（3,5）的中部或下部三分之一（出口侧）排出，基于 理论板的出口部分。

    Preparation of pyrrole and pyridine
    8.
    发明授权
    Preparation of pyrrole and pyridine 有权
    制备吡咯和吡啶

    公开(公告)号：US06538139B1

    公开(公告)日：2003-03-25

    申请号：US10234169

    申请日：2002-09-05

    申请人： Martin Schäfer ,  Arnd Böttcher ,  Andreas Kramer ,  Arthur Höhn ,  Reinhard Kaczmarek ,  Erhard Henkes

    发明人： Martin Schäfer ,  Arnd Böttcher ,  Andreas Kramer ,  Arthur Höhn ,  Reinhard Kaczmarek ,  Erhard Henkes

    IPC分类号： C07D213133

    CPC分类号： C07D207/323 ,  B01J23/42 ,  B01J23/44 ,  B01J23/63 ,  C07D213/06

    摘要： Pyrroles of the formula (I) are prepared by dehydrogenating pyrrolidines of the formula (II) where R1 and R2, independently of one another, are hydrogen or an aliphatic radical of 1 to 6 carbon atoms, or pyridines of the formula (III) are prepared by dehydrogenating piperidines of the formula (IV) where R3, R4 and R5, independently of one another, are hydrogen or an aliphatic radical of 1 to 6 carbon atoms, in the presence of a supported noble metal catalyst, by a process in which the dehydrogenation is carried out in the presence of from 1 to 50% by weight, based on the pyrrolidine or piperidine and water, of water.

    摘要翻译： 式（I）的吡咯通过使式（II）的吡咯烷脱氢制备，其中R1和R2彼此独立地是氢或具有1至6个碳原子的脂肪族基团，或者制备式（III）的吡啶 通过使负载型贵金属催化剂存在下，式（IV）的哌啶脱氢，其中R 3，R 4和R 5彼此独立地是氢或1-6个碳原子的脂族基团，其中脱氢 在1至50重量％的存在下，基于吡咯烷或哌啶和水的水进行。