公开(公告)号：US08282270B2

公开(公告)日：2012-10-09

申请号：US12603792

申请日：2009-10-22

申请人： Eric Grippo

发明人： Eric Grippo

IPC分类号： G04B37/00 ,  C23C14/35 ,  B32B3/00 ,  B32B7/00

CPC分类号： B44C3/02 ,  C04B41/52 ,  Y10T428/12382 ,  Y10T428/12611 ,  Y10T428/216 ,  Y10T428/24851 ,  Y10T428/24917 ,  Y10T428/24926 ,  Y10T428/31678

摘要： According to this process for manufacturing a ceramic element intended to be fitted onto a watch case, the visible surface of which has features, a soluble layer (2) is selectively deposited on said visible surface, the thickness of said soluble layer being at least equal to the height of said features, a first tie layer (3) of the Ti, Ta, Cr or Th type is vacuum-deposited by magnetron sputtering with a thickness of at least 100 nm by physical vapor deposition (PVD) on said surface thus selectively coated, followed, without venting atmosphere, by PVD deposition of said second layer (4) made of Au, Pt, Ag, Ni, Pd, TiN, CrN, ZrN or alloys thereof with a thickness of at least 100 nm, and then said soluble layer (2) is dissolved.

摘要翻译： 根据该制造用于装配在表壳上的陶瓷元件的方法，其可见表面具有特征，在所述可见表面上选择性地沉积可溶层（2），所述可溶层的厚度至少相等 到所述特征的高度，通过在所述表面上通过物理气相沉积（PVD）至少100nm的厚度通过磁控溅射将Ti，Ta，Cr或Th型的第一粘结层（3）真空沉积，因此 选择性地涂覆，然后通过PVD沉积由Au，Pt，Ag，Ni，Pd，TiN，CrN，ZrN或其合金制成的厚度至少为100nm的所述第二层（4），而不排放空气，然后 所述可溶层（2）溶解。

公开(公告)号：US20060011471A1

公开(公告)日：2006-01-19

申请号：US11061289

申请日：2005-02-18

申请人： Eric Grippo

发明人： Eric Grippo

IPC分类号： B32B5/00 ,  C23C14/32

CPC分类号： B44C3/02 ,  C04B41/52 ,  Y10T428/12382 ,  Y10T428/12611 ,  Y10T428/216 ,  Y10T428/24851 ,  Y10T428/24917 ,  Y10T428/24926 ,  Y10T428/31678

摘要： According to this process for manufacturing a ceramic element intended to be fitted onto a watch case, the visible surface of which has features, a soluble layer is selectively deposited on said visible surface, the thickness of said soluble layer being at least equal to the height of said features, a first tie layer of the Ti, Ta, Cr or Th type is vacuum-deposited by magnetron sputtering with a thickness of at least 100 nm by physical vapor deposition (PVD) on said surface thus selectively coated, followed, without venting atmosphere, by PVD deposition of said second layer made of Au, Pt, Ag, Ni, Pd, TiN, CrN, ZrN or alloys thereof with a thickness of at least 100 nm, and then said soluble layer is dissolved.

公开(公告)号：US20100110841A1

公开(公告)日：2010-05-06

申请号：US12603792

申请日：2009-10-22

申请人： Eric Grippo

发明人： Eric Grippo

IPC分类号： G04B37/00 ,  B32B15/04 ,  B32B18/00 ,  B32B3/14 ,  B32B3/02

CPC分类号： B44C3/02 ,  C04B41/52 ,  Y10T428/12382 ,  Y10T428/12611 ,  Y10T428/216 ,  Y10T428/24851 ,  Y10T428/24917 ,  Y10T428/24926 ,  Y10T428/31678

摘要： According to this process for manufacturing a ceramic element intended to be fitted onto a watch case, the visible surface of which has features, a soluble layer (2) is selectively deposited on said visible surface, the thickness of said soluble layer being at least equal to the height of said features, a first tie layer (3) of the Ti, Ta, Cr or Th type is vacuum-deposited by magnetron sputtering with a thickness of at least 100 nm by physical vapor deposition (PVD) on said surface thus selectively coated, followed, without venting atmosphere, by PVD deposition of said second layer (4) made of Au, Pt, Ag, Ni, Pd, TiN, CrN, ZrN or alloys thereof with a thickness of at least 100 nm, and then said soluble layer (2) is dissolved.

摘要翻译： 根据该制造用于装配在表壳上的陶瓷元件的方法，其可见表面具有特征，在所述可见表面上选择性地沉积可溶层（2），所述可溶层的厚度至少相等 到所述特征的高度，通过在所述表面上通过物理气相沉积（PVD）至少100nm的厚度通过磁控溅射将Ti，Ta，Cr或Th型的第一粘结层（3）真空沉积，因此 选择性地涂覆，然后通过PVD沉积由Au，Pt，Ag，Ni，Pd，TiN，CrN，ZrN或其合金制成的厚度至少为100nm的所述第二层（4），而不排放空气，然后 所述可溶层（2）溶解。

公开(公告)号：US20050136284A1

公开(公告)日：2005-06-23

申请号：US11011926

申请日：2004-12-14

申请人： Eric Grippo ,  William Passaquin

发明人： Eric Grippo ,  William Passaquin

IPC分类号： C04B41/52 ,  C04B41/90 ,  G04B37/22 ,  G04B45/00 ,  C23C14/32 ,  B32B19/00

CPC分类号： C04B41/009 ,  C04B41/52 ,  C04B41/90 ,  G04B37/22 ,  G04B45/0076 ,  Y10T428/24917 ,  Y10T428/24926 ,  Y10T428/31678 ,  C04B41/4533 ,  C04B41/4572 ,  C04B41/5133 ,  C04B41/5111 ,  C04B41/5062 ,  C04B41/522 ,  C04B41/4564 ,  C04B35/10 ,  C04B35/48

摘要： This ceramic element, the visible surface of which includes features, is intended to be fitted onto a watch case. This visible surface has, at each feature, a hollow having the shape of said feature, with a depth at least equal to 0.05 mm, the side walls of said hollow being essentially perpendicular to said visible surface, the bottom of said hollows having a first tie layer of Ti, Ta, Cr or Th type, with a thickness of at least 100 nm and at least a second layer from the group Au, Ag, CrN, Ni, Pt, TiN, ZrN, Pd or alloys thereof with a thickness of at least 100 nm.

摘要翻译： 该陶瓷元件的可见表面包括特征，旨在安装在表壳上。 该可见表面在每个特征处具有具有所述特征形状的中空部，其深度至少等于0.05mm，所述中空部分的侧壁基本上垂直于所述可见表面，所述中空部分的底部具有第一 具有厚度至少为100nm的Ti，Ta，Cr或Th型结合层，以及至少具有厚度为Au，Ag，CrN，Ni，Pt，TiN，ZrN，Pd或其合金的第二层 至少100nm。

公开(公告)号：US07628894B2

公开(公告)日：2009-12-08

申请号：US11061289

申请日：2005-02-18

申请人： Eric Grippo

发明人： Eric Grippo

IPC分类号： C23C14/35

CPC分类号： B44C3/02 ,  C04B41/52 ,  Y10T428/12382 ,  Y10T428/12611 ,  Y10T428/216 ,  Y10T428/24851 ,  Y10T428/24917 ,  Y10T428/24926 ,  Y10T428/31678

摘要： According to this process for manufacturing a ceramic element intended to be fitted onto a watch case, the visible surface of which has features, a soluble layer is selectively deposited on said visible surface, the thickness of said soluble layer being at least equal to the height of said features, a first tie layer of the Ti, Ta, Cr or Th type is vacuum-deposited by magnetron sputtering with a thickness of at least 100 nm by physical vapor deposition (PVD) on said surface thus selectively coated, followed, without venting atmosphere, by PVD deposition of said second layer made of Au, Pt, Ag, Ni, Pd, TiN, CrN, ZrN or alloys thereof with a thickness of at least 100 nm, and then said soluble layer is dissolved.

摘要翻译： 根据该制造用于装配在手表壳体上的陶瓷元件的方法，其可见表面具有特征，可溶层被选择性地沉积在所述可见表面上，所述可溶层的厚度至少等于高度 的所述特征，通过在所述表面上的物理气相沉积（PVD）通过磁控溅射将厚度至少为100nm的Ti，Ta，Cr或Th型的第一粘结层真空沉积，从而选择性地涂覆，随后，没有 通过PVD沉积由Au，Pt，Ag，Ni，Pd，TiN，CrN，ZrN或其合金制成的厚度为至少100nm的所述第二层，然后溶解所述可溶层。

公开(公告)号：US07121717B2

公开(公告)日：2006-10-17

申请号：US11011926

申请日：2004-12-14

申请人： Eric Grippo ,  William Passaquin

发明人： Eric Grippo ,  William Passaquin

IPC分类号： G04B37/00 ,  B32B3/00 ,  B32B7/00

CPC分类号： C04B41/009 ,  C04B41/52 ,  C04B41/90 ,  G04B37/22 ,  G04B45/0076 ,  Y10T428/24917 ,  Y10T428/24926 ,  Y10T428/31678 ,  C04B41/4533 ,  C04B41/4572 ,  C04B41/5133 ,  C04B41/5111 ,  C04B41/5062 ,  C04B41/522 ,  C04B41/4564 ,  C04B35/10 ,  C04B35/48

摘要： This ceramic element, the visible surface of which includes features, is intended to be fitted onto a watch case. This visible surface has, at each feature, a hollow having the shape of said feature, with a depth at least equal to 0.05 mm, the side walls of said hollow being essentially perpendicular to said visible surface, the bottom of said hollows having a first tie layer of Ti, Ta, Cr or Th type, with a thickness of at least 100 nm and at least a second layer from the group Au, Ag, CrN, Ni, Pt, TiN, ZrN, Pd or alloys thereof with a thickness of at least 100 nm.

摘要翻译： 该陶瓷元件的可见表面包括特征，旨在安装在表壳上。 该可见表面在每个特征处具有具有所述特征形状的中空部，其深度至少等于0.05mm，所述中空部分的侧壁基本上垂直于所述可见表面，所述中空部分的底部具有第一 具有厚度至少为100nm的Ti，Ta，Cr或Th型结合层，以及至少具有厚度为Au，Ag，CrN，Ni，Pt，TiN，ZrN，Pd或其合金的第二层 至少100nm。