Optical Article Comprising an Abrasion- and/or Scratch-Resistant Coating Having a Low Sensitivity to Cracks

    公开(公告)号:US20200096674A1

    公开(公告)日:2020-03-26

    申请号:US16498695

    申请日:2018-03-27

    Abstract: The present invention relates to an optical article comprising a substrate having at least one main surface successively coated with an impact-resistant primer coating and an abrasion- and/or scratch-resistant coating, which is formed from a composition comprising at least one epoxy compound bearing at least one silicon atom having at least one hydrolyzable group directly linked to the silicon atom and at least one group comprising an epoxy function, and/or a hydrolysate thereof, at least one alkylene glycol diglycidyl ether or poly(alkylene glycol) diglycidyl ether, colloidal particles of at least one metal oxide or metalloid oxide, at least one catalyst, the composition being devoid of comprise Si(X)4 compounds, or hydrolysates thereof, in which the X groups independently represent C1-C6 alkoxy groups.

    OPTICAL ARTICLE COMPRISING A DOUBLE-LAYER ABRASION AND SCRATCH RESISTANT COATING AND METHOD FOR PRODUCTION THEREOF
    6.
    发明申请
    OPTICAL ARTICLE COMPRISING A DOUBLE-LAYER ABRASION AND SCRATCH RESISTANT COATING AND METHOD FOR PRODUCTION THEREOF 审中-公开
    包含双层磨损和耐刮擦涂层的光学制品及其生产方法

    公开(公告)号:US20170003420A1

    公开(公告)日:2017-01-05

    申请号:US15264290

    申请日:2016-09-13

    Abstract: The invention relates to an optical article comprising a substrate coated with an abrasion and scratch resistant coating composed of a lower layer and an upper layer that do adhere to each other, the upper layer and the lower layer being layers of cured upper and lower layer compositions, said upper layer composition comprising at least one organosilane, or a hydrolyzate thereof, of formula RnYmSi(X)4−n−m and at least one compound, or a hydrolyzate thereof, of formula M(Z)x, the following ratio being lower than 2.3: Rs =  theoretical   dry   matter   weight   of compounds   I   in   the   upper   layer   composition theoretical   dry   matter   weight   of compounds   II   in   the   upper   layer   composition said lower layer composition comprising at least one organosilane, or a hydrolyzate thereof, of formula R′n′Y′m′Si(X′)4−n′−m′ and, optionally, at least one compound, or a hydrolyzate thereof, of formula M′(Z′)y, the following ratio being higher than 2.3: Ri =  theoretical   dry   matter   weight   of compounds   III   in   the   lower   layer   composition theoretical   dry   matter   extract   of compounds   IV   in   the   lower   layer   composition In the hereabove formulas, M and M′ are metals or metalloids of valences x and y, at least equal to 4, R and R′ groups are monovalent organic groups that are bound to silicon through a carbon atom and that contain at least one epoxy function, X, X′, Z and Z′ groups are hydrolyzable groups, Y and Y′ are monovalent organic groups that are bound to silicon through a carbon atom, n, m, n′ and m′ being integers such that n and n′=1 or 2 with n+m and n′+m′=1 or 2.

    Abstract translation: 在上述式中,M和M'是化合价x和y的金属或准金属,至少等于4,R和R'基团是通过碳原子与硅结合且含有至少一个环氧基的单价有机基团 功能X,X',Z和Z'基团是可水解基团,Y和Y'是通过碳原子与硅结合的一价有机基团,n,m,n'和m'是整数,使得n和n '= 1或2,其中n + m和n'+ m'= 1或2。

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