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    Polyhydroxy fatty acid amides in soil release agent-containing detergent compositions
    2.
    发明授权
    Polyhydroxy fatty acid amides in soil release agent-containing detergent compositions 失效
    多羟基脂肪酸酰胺在含有去污剂的洗涤剂组合物中

    公开(公告)号：US5332528A

    公开(公告)日：1994-07-26

    申请号：US78493

    申请日：1993-06-17

    申请人： Robert Y. Pan ,  Eugene P. Gosselink

    发明人： Robert Y. Pan ,  Eugene P. Gosselink

    IPC分类号： C11D1/14 ,  C11D1/22 ,  C11D1/28 ,  C11D1/29 ,  C11D1/52 ,  C11D1/65 ,  C11D1/66 ,  C11D1/835 ,  C11D3/00 ,  C11D3/32 ,  C11D3/37 ,  C11D1/83

    CPC分类号： C11D3/3715 ,  C11D1/525 ,  C11D1/652 ,  C11D1/662 ,  C11D1/835 ,  C11D3/0036 ,  C11D1/14 ,  C11D1/22 ,  C11D1/28 ,  C11D1/29 ,  C11D1/66

    摘要： Disclosed is a detergent composition containing one or more anionic surfactants and one or more soil release agents characterized by the presence of an anionic surfactant-interactive nonionic hydrophile and/or an anionic surfactant-interactive hydrophobic moiety, or both, and a soil release agent-enhancing amount of a polyhydroxy fatty acid amide surfactant of the formula: ##STR1## wherein R.sup.1 is H, C.sub.1 -C.sub.4 hydrocarbyl, 2-hydroxy ethyl, 2-hydroxy propyl, or a mixture thereof, R.sub.2 is C.sub.5 -C.sub.31 hydrocarbyl, and Z is a polyhydroxylhydrocarbyl having a linear hydrocarbyl chain with at least 3 hydroxyls directly connected to the chain, or an alkoxylated derivative thereof.

    摘要翻译： 公开了一种含有一种或多种阴离子表面活性剂和一种或多种污垢释放剂的洗涤剂组合物，其特征在于存在阴离子表面活性剂相互作用的非离子亲水和/或阴离子表面活性剂相互作用的疏水部分或两者， 增加量的下式的多羟基脂肪酸酰胺表面活性剂：其中R 1是H，C 1 -C 4烃基，2-羟基乙基，2-羟基丙基或其混合物，R 2是C 5 -C 31烃基，Z 是具有至少3个与链连接的羟基的直链烃基链的多羟基烃基或其烷氧基化衍生物。

    Soil release agents for granular laundry detergents
    5.
    发明授权
    Soil release agents for granular laundry detergents 失效
    颗粒状衣物洗涤剂用土壤脱模剂

    公开(公告)号：US5599782A

    公开(公告)日：1997-02-04

    申请号：US576263

    申请日：1995-12-21

    申请人： Robert Y. L. Pan ,  Eugene P. Gosselink ,  Eugene J. Pancheri ,  Stephen W. Morrall

    发明人： Robert Y. L. Pan ,  Eugene P. Gosselink ,  Eugene J. Pancheri ,  Stephen W. Morrall

    IPC分类号： C08G63/688 ,  C11D3/00 ,  C11D3/37 ,  C11D17/06 ,  C11D1/02

    CPC分类号： C08G63/6884 ,  C11D3/0036 ,  C11D3/3715

    摘要： Improved soil release agents for granular laundry detergents, typically used at levels as low as about 1% of a fully-formulated anionic surfactant-containing granular detergent, are reaction products of transesterifying and oligomerizing mixtures of monomers having the functions MO.sub.3 SC.sub.6 H.sub.4 C(O)--, M'O.sub.3 SC.sub.6 H.sub.3 {C(O)O--}.sub.2, --(O)CC.sub.6 H.sub.4 C(O)-- and --OCH.sub.2 CH.sub.2 O-- wherein M and M' are independently selected from lithium, potassium and sodium, more preferably sodium; said mixtures having mole ratio of MO.sub.3 SC.sub.6 H.sub.4 C(O)-- to --(O)CC.sub.6 H.sub.4 C(O)-- of from about 0.2:1 to about 1.4:1, mole ratio of MO.sub.3 SC.sub.6 H.sub.4 C(O)-- to M'O.sub.3 SC.sub.6 H.sub.3 {C(O)O--}.sub.2 of from about 0.67:1 to about 20:1 and mole ratio of MO.sub.3 SC.sub.6 H.sub.4 C(O)-- to --OCH.sub.2 CH.sub.2 O-- of from about 0.007:1 to about 0.51:1 and being substantially free from monomers of formula HOROH wherein R is propylene or higher alkyl.

    摘要翻译： 用于粒状衣物洗涤剂的改进的去污剂通常以低至约1％的完全配制的含阴离子表面活性剂的颗粒洗涤剂的水平使用，是具有MO3SC6H4C（O） - ， M'O3SC6H3 {C（O）O-} 2， - （O）C16H4C（O） - 和-OCH2CH2O-，其中M和M'独立地选自锂，钾和钠，更优选钠; 所述混合物的MO 3 SC 6 H 4 C（O） - （O）C 6 H 4 C（O）的摩尔比为约0.2:1至约1.4:1摩尔比的MO 3 SC 6 H 4 C（O） - 与M'O 3 SC 6 H 3 {C（O） 约为0.67:1至约20:1的摩尔比和MO 3 SC 6 H 4 C（O） - 至-OCH 2 CH 2 O的摩尔比为约0.007:1至约0.51:1，并且基本上不含式HOROH的单体，其中R 是丙烯或高级烷基。

    Process for reducing the levels of fatty acid contaminants in polyhydroxy fatty acid amide surfactants
    7.
    发明授权
    Process for reducing the levels of fatty acid contaminants in polyhydroxy fatty acid amide surfactants 失效
    降低多羟基脂肪酸酰胺表面活性剂中脂肪酸污染物含量的方法

    公开(公告)号：US5188769A

    公开(公告)日：1993-02-23

    申请号：US857853

    申请日：1992-03-26

    申请人： Daniel S. Connor ,  Jeffrey J. Scheibel ,  Bruce P. Murch ,  Mark H. Mao ,  Eugene P. Gosselink ,  Roland G. Severson, Jr.

    发明人： Daniel S. Connor ,  Jeffrey J. Scheibel ,  Bruce P. Murch ,  Mark H. Mao ,  Eugene P. Gosselink ,  Roland G. Severson, Jr.

    IPC分类号： C07C231/02 ,  C11D1/52

    CPC分类号： C11D1/525 ,  C07C231/02 ,  Y10S516/07

    摘要： The synthesis of polyhydroxy fatty acid amide surfactants exemplified by the compound C.sub.11 H.sub.23 C(O)N(CH.sub.3)CH.sub.2 [CHOH].sub.4 CH.sub.2 OH by reacting a fatty acid ester with an N-alkyl sugar amine can result in contamination of the product surfactant by residual sources of fatty acids. These residual fatty acids may be unacceptable in high sudsing detergent compositions, such as dishwashing liquids, especially with Ca or Mg cations. The process of this invention reacts such contaminants with alkyl amines or, especially, ethanolamine, to convert them into fatty alkyl- or alkanolamides, which are quite acceptable in fully-formulated detergent compositions for home or industrial use.

    摘要翻译： 通过使脂肪酸酯与N-烷基糖胺反应，由化合物C11H23C（O）N（CH3）CH2 [CHOH] 4CH2OH表示的多羟基脂肪酸酰胺表面活性剂的合成可导致产物表面活性剂被残留的来源污染 脂肪酸。 这些残留脂肪酸在高泡沫洗涤剂组合物中是不可接受的，例如餐具洗涤液，特别是与Ca或Mg阳离子。 本发明的方法使这些污染物与烷基胺或特别是乙醇胺反应，将它们转化成脂肪烷基 - 或链烷醇酰胺，其在用于家庭或工业用途的完全配制的洗涤剂组合物中是完全可接受的。

    Detergent compositions containing cationic compounds having clay soil removal/anti-redeposition properties
    9.
    发明授权
    Detergent compositions containing cationic compounds having clay soil removal/anti-redeposition properties 失效
    含有具有粘土去除/抗再沉积性质的阳离子化合物的洗涤剂组合物

    公开(公告)号：US4664848A

    公开(公告)日：1987-05-12

    申请号：US553550

    申请日：1983-11-22

    申请人： Young S. Oh ,  Eugene P. Gosselink

    发明人： Young S. Oh ,  Eugene P. Gosselink

    IPC分类号： C08G65/26 ,  C11D1/40 ,  C11D1/62 ,  C11D3/37

    CPC分类号： C08G65/2624 ,  C11D1/40 ,  C11D1/62 ,  C11D3/3723

    摘要： Detergent compositions which comprise from about 0.05 to about 95% by weight of a water-soluble cationic compound having clay soil removal/anti-redeposition properties. These compounds are selected from ethoxylated cationic monoamines, ethoxylated cationic diamines, ethoxylated cationic polyamines, ethoxylated cationic polymers, and mixtures thereof. In addition to the cationic compounds, the detergent compositions further comprise from about 1 to about 75% by weight of a nonionic, anionic, ampholytic, zwitterionic, or cationic detergent surfactant or mixture thereof. In addition to these detergent surfactants, the detergent composition can optionally comprise from 0 to about 80% by weight of a detergent builder.

    摘要翻译： 洗涤剂组合物，其包含约0.05至约95重量％的具有粘土去除/抗再沉积性质的水溶性阳离子化合物。 这些化合物选自乙氧基化阳离子单胺，乙氧基化阳离子二胺，乙氧基化阳离子多胺，乙氧基化阳离子聚合物及其混合物。 除了阳离子化合物之外，洗涤剂组合物还包含约1至约75重量％的非离子，阴离子，两性，两性离子或阳离子洗涤剂表面活性剂或其混合物。 除了这些洗涤剂表面活性剂之外，洗涤剂组合物可以任选地包含0至约80重量％的洗涤剂助洗剂。

    Cationic polymers having clay soil removal/anti-redeposition properties useful in detergent compositions
    10.
    发明授权
    Cationic polymers having clay soil removal/anti-redeposition properties useful in detergent compositions 失效
    具有洗涤剂组合物中有用的粘土去除/抗再沉积性质的阳离子聚合物

    公开(公告)号：US4551506A

    公开(公告)日：1985-11-05

    申请号：US452655

    申请日：1982-12-23

    申请人： Eugene P. Gosselink

    发明人： Eugene P. Gosselink

    IPC分类号： C08G65/26 ,  C08G73/04 ,  C11D1/40 ,  C11D1/62 ,  C11D3/37 ,  C11D3/48

    CPC分类号： C11D3/3723 ,  C08G65/2624 ,  C11D1/40 ,  C11D1/62

    摘要： Water-soluble cationic polymers having clay soil removal/anti-redeposition properties, which comprise a polymer backbone, at least two M groups and at least one L-X group, wherein M is a cationic group attached to or integral with the backbone and contains an N+ positively charged center; X is a nonionic group selected from the group consisting of H, C.sub.1 -C.sub.4 alkyl or hydroxyalkyl ester or ether groups, or mixtures thereof; and L is a hydrophilic chain connecting groups M and X or connecting X to the polymer backbone. L also contains the polyoxyalkylene moiety --[(R'O).sub.m (CH.sub.2 CH.sub.2 O).sub.n ]--, wherein R' is C.sub.3 -C.sub.4 alkylene or hydroxyalkylene, m and n are numbers such that the moiety --(CH.sub.2 CH.sub.2 O).sub.n -- is at least about 50% by weight of said polyoxyalkylene moiety, and n is at least about 3. These cationic polymers are useful in detergent compositions.

    摘要翻译： 具有粘土去除/抗再沉积性质的水溶性阳离子聚合物，其包含聚合物主链，至少两个M基团和至少一个LX基团，其中M是与骨架连接或与骨架一体并含有N + 带正电的中心; X是选自H，C 1 -C 4烷基或羟烷基酯或醚基的非离子基团，或其混合物; L是连接基团M和X或将X连接到聚合物骨架的亲水链。 L还含有聚氧化烯部分 - [（R'O）m（CH 2 CH 2 O）n] - ，其中R'是C 3 -C 4亚烷基或羟基亚烷基，m和n是数个这样的数字，使得部分 - （CH 2 CH 2 O）n-至少 约50重量％的所述聚氧化烯部分，n为至少约3.这些阳离子聚合物可用于洗涤剂组合物中。