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    Polymeric nanocomposite materials with a functional matrix and method of reading and writing thereto
    1.
    发明授权
    Polymeric nanocomposite materials with a functional matrix and method of reading and writing thereto 失效
    具有功能矩阵的聚合纳米复合材料及其读取和写入方法

    公开(公告)号：US06785214B2

    公开(公告)日：2004-08-31

    申请号：US09726487

    申请日：2000-12-01

    申请人： Eugenia Kumacheva ,  Olga Kalinina

    发明人： Eugenia Kumacheva ,  Olga Kalinina

    IPC分类号： G11B700

    CPC分类号： B01J13/02 ,  B01J13/18 ,  G03F7/0005 ,  G03F7/002 ,  G11B7/00455 ,  G11B7/0052

    摘要： A nanocomposite material having a plurality of core particles formed of a core material. The core material has a first glass transition temperature. A shell encapsulates each core particle. The shell is formed of a shell material that has a second glass transition temperature less than the first glass transition temperature. When subjected to a temperature greater than the second glass transition temperature and less than the first glass transition temperature, the shells form a continuous matrix surrounding the core particles. The shell material includes a functional component that can be activated in response to an external excitation. This functional component can include either photosensitive, semiconductor, magnetic, piezoelectric or electro-active components just to mention a few. The different components may be chemically or physically bound to the shell or cores. These nanocomposite materials are used as storage media.

    摘要翻译： 一种纳米复合材料，其具有由核心材料形成的多个核心颗粒。 芯材料具有第一玻璃化转变温度。 壳体封装每个核心粒子。 外壳由壳材料形成，其具有小于第一玻璃化转变温度的第二玻璃化转变温度。 当受到大于第二玻璃化转变温度且小于第一玻璃化转变温度的温度时，壳形成围绕芯颗粒的连续基体。 外壳材料包括可以响应于外部激发而被激活的功能部件。 该功能组件可以包括光敏，半导体，磁性，压电或电活性组分，仅仅是提及一些。 不同的组分可以化学或物理地结合到壳或核。 这些纳米复合材料用作储存介质。

    Method of producing three dimensional assembly of particles in ordered arrays
    3.
    发明授权
    Method of producing three dimensional assembly of particles in ordered arrays 有权
    生产有序阵列的三维粒子组装的方法

    公开(公告)号：US06325957B1

    公开(公告)日：2001-12-04

    申请号：US09450781

    申请日：1999-11-30

    申请人： Eugenia Kumacheva ,  Olga Kalinina

    发明人： Eugenia Kumacheva ,  Olga Kalinina

    IPC分类号： B28B1087

    摘要： A method of producing three dimensional ordered arrays of particles. The method may be used for the preparation of nanocomposite materials with highly periodic structures. More particularly the invention provides a method of producing three dimensional arrays based on applying a controlled oscillatory motion to settling dispersions of colloid particles. The controlled oscillatory motion is characterized by G=A&ohgr;2/g, wherein g is the gravitational constant, A is the displacement and &ohgr; is angular frequency. G is maintained in the desired range by varying values of A within an effective range of displacements and &ugr; within an effective range of frequencies.

    摘要翻译： 一种生产三维有序排列阵列的方法。 该方法可用于制备具有高周期结构的纳米复合材料。 更具体地，本发明提供了一种基于施加受控振荡运动以沉降胶体颗粒的分散体来生产三维阵列的方法。 受控振荡运动的特征在于G = Aomega2 / g，其中g是重力常数，A是位移，ω是角频率。 通过在有效的位移范围内改变A的值，将G保持在期望的范围内 在有效的频率范围内。

    Method of producing hybrid polymer-inorganic materials
    7.
    发明申请
    Method of producing hybrid polymer-inorganic materials 有权
    混合聚合物 - 无机材料的制备方法

    公开(公告)号：US20060257485A1

    公开(公告)日：2006-11-16

    申请号：US10548414

    申请日：2004-03-10

    申请人： Eugenia Kumacheva

    发明人： Eugenia Kumacheva

    IPC分类号： A61K9/14 ,  C08K3/22

    CPC分类号： C08G83/001 ,  B82Y30/00 ,  C08J5/005

    摘要： The present invention describes a new approach to producing hybrid composite materials with multiscale morphologies. We doped polymer submicrometer spheres with semiconductor or metal (e.g. CdS or Ag, respectively) nanoparticles and used these doped microspheres as the functional building blocks in production of hybrid periodically structured materials. The preparation of hybrid polymer particles included the following stages: (i) synthesis of monodisperse polymer microspheres, (ii) in-situ synthesis of the inorganic nanoparticles either on the surface, or in the bulk of the polymer beads, and (iii) encapsulation of hybrid microspheres with a hydrophobic shell. We demonstrated that by changing the composition of the polymer beads good control could be achieved over the size of the nanoparticles.

    摘要翻译： 本发明描述了生产具有多尺度形态的混合复合材料的新方法。 我们用半导体或金属（例如分别为CdS或Ag）纳米颗粒掺杂聚合物亚微米球，并将这些掺杂的微球用作生产混合周期性结构材料的功能性结构单元。 混合聚合物颗粒的制备包括以下阶段：（i）合成单分散聚合物微球体，（ii）在表面或大部分聚合物珠粒中原位合成无机纳米颗粒，和（iii）包封 具有疏水壳的杂交微球。 我们证明通过改变聚合物珠粒的组成，可以在纳米粒子的尺寸上实现良好的控制。

    Method of producing hybrid polymer-inorganic materials
    10.
    发明授权
    Method of producing hybrid polymer-inorganic materials 有权

    公开(公告)号：US08236877B2

    公开(公告)日：2012-08-07

    申请号：US12911059

    申请日：2010-10-25

    申请人： Eugenia Kumacheva

    发明人： Eugenia Kumacheva

    IPC分类号： C08G83/00 ,  C08J3/05 ,  C08K3/22 ,  C08K9/10

    CPC分类号： C08G83/001 ,  B82Y30/00 ,  C08J5/005

    摘要： Hybrid composite materials with multiscale morphologies are formed by doping polymer submicrometer spheres with semiconductor or metal (e.g. CdS or Ag, respectively) nanoparticles and using these doped microspheres as functional building blocks in production of hybrid periodically structured materials. The preparation of hybrid polymer particles include the following stages: (i) synthesis of monodisperse polymer microspheres, (ii) in-situ synthesis of the inorganic nanoparticles either on the surface, or in the bulk with polymer beads, and (iii) encapsulation of hybrid microspheres with a hydrophobic shell.