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公开(公告)号：US20140228494A1
公开(公告)日：2014-08-14
申请号：US14254376
申请日：2014-04-16
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Karla S. Colle , Philippe L. Buess , Eddy T. Van Driessche , Allen D. Godwin , Ramzi Y. Saleh , Jon E. R. Stanat , Raphael F. Caers
CPC classification number: C08K5/11 , C07B41/12 , C07C45/50 , C07C51/235 , C07C67/08 , C07C69/30 , C08K5/0016 , C08K5/103 , C08K5/12 , C07C69/78 , C08L27/06 , C07C47/02
Abstract: Triglyceride and other polyol ester PVC plasticizers can be produced by recovery of branched C6 to C9 aldehydes from a hydroformylation product, optional hydrogenation to the alcohol, oxidation to the acid with oxygen and/or air, recovery of the resulting acid, and esterification with glycerol, ethylene glycol, propylene glycol or mixtures thereof. The branched alkyl chains comprise at least 10% methyl branching. Special triglycerides are derived from branched aliphatic acids having alkyl chains with average carbon numbers from 6 to 9 and at least 10% methyl branching. These triglycerides are fast fusing plasticisers if before esterification with glycerol, an aryl acid is introduced together with the aliphatic acids.
Abstract translation: 甘油三酯和其它多元醇酯类PVC增塑剂可以通过从加氢甲酰化产物回收支链C6至C9醛，任选的氢化成醇，用氧气和/或空气氧化成酸，回收所得酸，并用甘油酯化 ，乙二醇，丙二醇或其混合物。 支链烷基链包含至少10％的甲基支链。 特别的甘油三酸酯衍生自具有平均碳数为6至9和至少10％甲基支链的烷基链的支链脂族酸。 如果在用甘油酯化之前，这些甘油三酯是快速熔化增塑剂，芳基酸与脂肪酸一起引入。
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Patent Agency Ranking
公开(公告)号：US09815767B2
公开(公告)日：2017-11-14
申请号：US15138055
申请日：2016-04-25
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Jihad M. Dakka , Lorenzo C. DeCaul , Christine A. Costello , Edmund J. Mozeleski , Pierre Osterrieth , Stephen Zushma , Allen D. Godwin , Diana Smimova , Catherine A. Faler , Victor DeFlorio , Didier A. Naert
IPC: C08K5/00 , C07C69/76 , C08K5/101 , C08K5/12 , C09D127/06 , H01B3/44 , C08J5/18 , C08K5/10 , D21H27/20 , C07C67/08 , C07C67/39 , C07C69/78 , C08K3/10 , C08K5/103 , D06N7/00 , D06M13/224 , D06N3/00 , D06N5/00 , C07C2/68 , C07C2/76 , C07C51/285
CPC classification number: C07C69/76 , C07C2/68 , C07C2/76 , C07C51/285 , C07C67/08 , C07C67/39 , C07C69/78 , C07C2601/14 , C08J5/18 , C08J2327/06 , C08K3/10 , C08K5/10 , C08K5/101 , C08K5/103 , C08K5/12 , C08K2201/014 , C09D127/06 , D06M13/224 , D06N3/0059 , D06N5/00 , D06N7/0002 , D21H27/20 , H01B3/443 , Y10T428/2964 , Y10T428/31935 , C08K3/0033 , C08K5/0016 , C08L27/06 , C08K3/013
Abstract: Provided are compounds of the following: wherein R1 is a saturated or unsaturated cyclic hydrocarbon optionally substituted with an alkyl and/or an OXO-ester, and R2 is a C4 to C14 hydrocarbyl, preferably the residue of a C4 to C14 OXO-alcohol. Also provided are processes for making the compounds and plasticized polymer compositions containing said compounds.
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公开(公告)号：US09321898B2
公开(公告)日：2016-04-26
申请号：US14516239
申请日：2014-10-16
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Jihad M. Dakka , Lorenzo C. DeCaul , Christine A. Costello , Edmund J. Mozeleski , Pierre Osterrieth , Stephen Zushma , Allen D. Godwin , Diana Smirnova , Catherine A. Faler , Victor Deflorio , Didier Naert
IPC: C08K5/00 , C08K5/09 , C08K5/101 , C08K5/12 , C09D127/06 , H01B3/44 , C08J5/18 , C07C69/76 , C08K5/10 , D21H27/20 , C07C67/08 , C07C67/39 , C07C69/78 , C08K3/10 , C08K5/103 , D06N7/00 , D06M13/224 , D06N3/00 , D06N5/00
CPC classification number: C07C69/76 , C07C2/68 , C07C2/76 , C07C51/285 , C07C67/08 , C07C67/39 , C07C69/78 , C07C2601/14 , C08J5/18 , C08J2327/06 , C08K3/10 , C08K5/10 , C08K5/101 , C08K5/103 , C08K5/12 , C08K2201/014 , C09D127/06 , D06M13/224 , D06N3/0059 , D06N5/00 , D06N7/0002 , D21H27/20 , H01B3/443 , Y10T428/2964 , Y10T428/31935 , C08K3/0033 , C08K5/0016 , C08L27/06 , C08K3/013
Abstract: Provided are compounds of the following: wherein R1 is a saturated or unsaturated cyclic hydrocarbon optionally substituted with an alkyl and/or an OXO-ester, and R2 is a C4 to C14 hydrocarbyl, preferably the residue of a C4 to C14 OXO-alcohol. Also provided are processes for making the compounds and plasticized polymer compositions containing said compounds.
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公开(公告)号：US20150140350A1
公开(公告)日：2015-05-21
申请号：US14516239
申请日：2014-10-16
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Jihad M. Dakka , Lorenzo C. DeCaul , Christine A. Costello , Edmund J. Mozeleski , Pierre Osterrieth , Stephen Zushma , Allen D. Godwin , Diana Smirnova , Catherine A. Faler , Victor Deflorio , Didier Naert
CPC classification number: C07C69/76 , C07C2/68 , C07C2/76 , C07C51/285 , C07C67/08 , C07C67/39 , C07C69/78 , C07C2601/14 , C08J5/18 , C08J2327/06 , C08K3/10 , C08K5/10 , C08K5/101 , C08K5/103 , C08K5/12 , C08K2201/014 , C09D127/06 , D06M13/224 , D06N3/0059 , D06N5/00 , D06N7/0002 , D21H27/20 , H01B3/443 , Y10T428/2964 , Y10T428/31935 , C08K3/0033 , C08K5/0016 , C08L27/06 , C08K3/013
Abstract: Provided are compounds of the following: wherein R1 is a saturated or unsaturated cyclic hydrocarbon optionally substituted with an alkyl and/or an OXO-ester, and R2 is a C4 to C14 hydrocarbyl, preferably the residue of a C4 to C14 OXO-alcohol. Also provided are processes for making the compounds and plasticized polymer compositions containing said compounds.
Abstract translation: 提供以下化合物：其中R1是任选被烷基和/或OXO-酯取代的饱和或不饱和环烃，R 2是C 4至C 14烃基，优选C 4至C 14 O XO-醇的残基。 还提供了制备含有所述化合物的化合物和增塑聚合物组合物的方法。
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公开(公告)号：US09546259B2
公开(公告)日：2017-01-17
申请号：US14254376
申请日：2014-04-16
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Karla S. Colle , Philippe L. Buess , Eddy T. Van Driessche , Allen D. Godwin , Ramzi Y. Saleh , Jon E. R. Stanat , Raphael F. Caers
IPC: C08K5/103 , C08K5/11 , C07B41/12 , C07C45/50 , C07C51/235 , C07C67/08 , C07C69/30 , C08K5/00 , C08K5/12
CPC classification number: C08K5/11 , C07B41/12 , C07C45/50 , C07C51/235 , C07C67/08 , C07C69/30 , C08K5/0016 , C08K5/103 , C08K5/12 , C07C69/78 , C08L27/06 , C07C47/02
Abstract: Triglyceride and other polyol ester PVC plasticizers can be produced by recovery of branched C6 to C9 aldehydes from a hydroformylation product, optional hydrogenation to the alcohol, oxidation to the acid with oxygen and/or air, recovery of the resulting acid, and esterification with glycerol, ethylene glycol, propylene glycol or mixtures thereof. The branched alkyl chains comprise at least 10% methyl branching. Special triglycerides are derived from branched aliphatic acids having alkyl chains with average carbon numbers from 6 to 9 and at least 10% methyl branching. These triglycerides are fast fusing plasticizers if before esterification with glycerol, an aryl acid is introduced together with the aliphatic acids.
Abstract translation: 甘油三酯和其它多元醇酯PVC增塑剂可以通过从加氢甲酰化产物回收支链C6至C9醛，任选的氢化成醇，用氧气和/或空气氧化成酸，回收所得酸，并用甘油酯化 ，乙二醇，丙二醇或其混合物。 支链烷基链包含至少10％的甲基支链。 特别的甘油三酸酯衍生自具有平均碳数为6至9和至少10％甲基支链的烷基链的支链脂族酸。 如果在用甘油酯化之前，这些甘油三酯是快速熔融增塑剂，芳基酸与脂肪酸一起引入。
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公开(公告)号：US20160237022A1
公开(公告)日：2016-08-18
申请号：US15138055
申请日：2016-04-25
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Jihad M. Dakka , Lorenzo C. DeCaul , Christine A. Costello , Edmund J. Mozeleski , Pierre Osterrieth , Stephen Zushma , Allen D. Godwin , Diana Smirnova , Catherine A. Faler , Victor DeFlorio , Didier A. Naert
CPC classification number: C07C69/76 , C07C2/68 , C07C2/76 , C07C51/285 , C07C67/08 , C07C67/39 , C07C69/78 , C07C2601/14 , C08J5/18 , C08J2327/06 , C08K3/10 , C08K5/10 , C08K5/101 , C08K5/103 , C08K5/12 , C08K2201/014 , C09D127/06 , D06M13/224 , D06N3/0059 , D06N5/00 , D06N7/0002 , D21H27/20 , H01B3/443 , Y10T428/2964 , Y10T428/31935 , C08K3/0033 , C08K5/0016 , C08L27/06 , C08K3/013
Abstract: Provided are compounds of the following: wherein R1 is a saturated or unsaturated cyclic hydrocarbon optionally substituted with an alkyl and/or an OXO-ester, and R2 is a C4 to C14 hydrocarbyl, preferably the residue of a C4 to C14 OXO-alcohol. Also provided are processes for making the compounds and plasticized polymer compositions containing said compounds.
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