公开(公告)号：US20210331146A1

公开(公告)日：2021-10-28

申请号：US17185290

申请日：2021-02-25

Applicant: ExxonMobil Research and Engineering Company

Inventor： Yi Du ,  Bradley D. Wooler ,  Stuart L. Soled ,  Sabato Miseo ,  Christine E. Kliewer

IPC: B01J27/22 ,  B01J21/08 ,  B01J35/00 ,  B01J37/02 ,  B01J37/08 ,  C10G45/08

Abstract: This application relates to preparation of mono and bimetallic group V, VI, and VII containing carbide catalysts and the methods of using the carbide catalysts in hydroprocessing applications. A method of producing a carbide catalyst comprising: depositing a precursor metal, an acid or an amine, and an organic compound on a support thereby forming an impregnated support, wherein the organic compound has a carbon number of 10 or greater; and carbonizing the impregnated support thereby forming a carbide phase on the support.

公开(公告)号：US10227539B2

公开(公告)日：2019-03-12

申请号：US15198346

申请日：2016-06-30

Applicant: ExxonMobil Research and Engineering Company

Inventor： Michael P. Lanci ,  Stuart L. Soled ,  Javier Guzman ,  Sabato Miseo ,  Thomas E. Green ,  Joseph E. Baumgartner ,  Lei Zhang ,  Christine E. Kliewer ,  Lukasz Koziol ,  Kanmi Mao ,  Tracie L. Owens ,  Gary P. Schleicher

IPC: C10G45/00 ,  C10M101/02 ,  B01J23/42 ,  B01J23/44 ,  B01J31/02 ,  B01J31/28 ,  B01J37/02 ,  C10G45/34 ,  C10G45/46 ,  C10G45/52 ,  C10G65/12 ,  B01J37/08 ,  B01J35/00 ,  B01J37/00 ,  B01J21/12 ,  B01J23/46

Abstract: Methods are provided for modifying hydrogenation catalysts having silica supports (or other non-alumina supports) with additional alumina, and using such catalysts to achieve unexpectedly superior hydrogenation of feedstocks. The modified hydrogenation catalysts can have a relatively low cracking activity while providing an increased activity for hydrogenation.

公开(公告)号：US10227535B2

公开(公告)日：2019-03-12

申请号：US15198397

申请日：2016-06-30

Applicant: ExxonMobil Research and Engineering Company

Inventor： Michael P. Lanci ,  Stuart L. Soled ,  Javier Guzman ,  Sabato Miseo ,  Thomas E. Green ,  Joseph E. Baumgartner ,  Lei Zhang ,  Christine E. Kliewer ,  Lukasz Koziol ,  Kanmi Mao ,  Tracie L. Owens ,  Gary P. Schleicher ,  Xiaochun Xu

IPC: C10G45/52 ,  C10G45/00 ,  B01J23/42 ,  B01J23/44 ,  B01J21/04 ,  B01J21/08 ,  B01J21/12 ,  B01J23/46 ,  B01J31/02 ,  B01J31/28 ,  B01J37/02 ,  C10G45/34 ,  C10G45/46 ,  C10G65/08

Abstract: Methods are provided for modifying hydrogenation catalysts having silica supports (or other non-alumina supports) with additional alumina, and using such catalysts to achieve unexpectedly superior hydrogenation of feedstocks. The modified hydrogenation catalysts can have a relatively low cracking activity while providing an increased activity for hydrogenation.

公开(公告)号：US20130261362A1

公开(公告)日：2013-10-03

申请号：US13851176

申请日：2013-03-27

Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY

Inventor： Bradley R. Fingland ,  Patrick Loring Hanks ,  Stuart Leon Soled ,  Sabato Miseo

IPC: C10G3/00

CPC classification number: C10G3/47 ,  B01J23/002 ,  B01J23/882 ,  B01J23/883 ,  B01J23/888 ,  B01J23/8885 ,  B01J35/1014 ,  B01J35/1019 ,  B01J37/20 ,  B01J2523/00 ,  C10G3/46 ,  C10G45/04 ,  C10G65/04 ,  C10G2300/202 ,  Y02P30/20 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/847

Abstract: This invention relates to methods for deoxygenation utilizing bulk metal catalysts feedstocks derived in part or whole from biological sources and alternatively, further hydrotreatment processing of such deoxygenated feedstocks. Feedstocks containing bio-derived feed components, and preferably additionally mineral oil feed components, are deoxygenated in a first stage or zone using a bulk metal catalyst. In additional embodiments, the deoxygenated feedstock effluent from the deoxygenation stage is further subjected to a hydrodesulfurization stage or zone.

Abstract translation: 本发明涉及利用来自生物源的部分或全部衍生的本体金属催化剂原料的脱氧方法，或者这种脱氧原料的进一步加氢处理。 含有生物衍生的进料组分的原料，优选另外的矿物油进料组分在使用块状金属催化剂的第一阶段或区域中脱氧。 在另外的实施方案中，来自脱氧阶段的脱氧原料流出物进一步经受加氢脱硫阶段或区域。

公开(公告)号：US20200270533A1

公开(公告)日：2020-08-27

申请号：US16783598

申请日：2020-02-06

Applicant: ExxonMobil Research and Engineering Company

Inventor： Xiaochun Xu ,  Gregory J. De Martin ,  Keith Wilson ,  Doron Levin ,  Stuart L. Soled ,  Sabato Miseo

IPC: C10G45/08 ,  B01J23/00 ,  B01J37/20

Abstract: The present disclosure provides processes for hydroprocessing hydrocarbon feedstocks comprising a silicon content of about 1 wppm or greater. In at least one embodiment, a process includes introducing, in a reactor or to the reactor, a hydrocarbon feedstock having a silicon content of at least about 1 wppm, based on the total weight of the hydrocarbon feedstock, to a treat gas to produce a hydrocarbon feedstock/treat gas mixture. The process includes introducing the hydrocarbon feedstock/treat gas mixture to a catalyst composition comprising at least one group 6 metal and at least one group 8-10 metal, wherein the molar ratio of group 6 metal to group 8-10 metal is from about 10:1 to about 1:10. The process includes obtaining a liquid product comprising a sulfur content of 5,000 wppm or less. Furthermore, processes of the present disclosure provide hydroprocessing of high Si content feeds using hydrocarbon feeds at high liquid hourly space velocities.

公开(公告)号：US09598645B2

公开(公告)日：2017-03-21

申请号：US13851247

申请日：2013-03-27

Applicant: ExxonMobil Research and Engineering Company

Inventor： Patrick L. Hanks ,  Bradley R. Fingland ,  Stuart L. Soled ,  Sabato Miseo

IPC: C10G3/00 ,  B01J23/30 ,  C10G45/04 ,  C10G65/04 ,  B01J23/882 ,  B01J23/883 ,  B01J23/887 ,  B01J23/888 ,  B01J37/02

CPC classification number: C10G3/50 ,  B01J23/30 ,  B01J23/882 ,  B01J23/883 ,  B01J23/8872 ,  B01J23/8873 ,  B01J23/888 ,  B01J37/0201 ,  B01J37/0238 ,  C10G3/46 ,  C10G45/04 ,  C10G65/04 ,  C10G2300/202 ,  Y02P30/20

Abstract: Feedstocks containing biocomponent materials are coprocessed with mineral feeds using a Group VI metal catalyst prior to hydrodesulfurization of the feedstocks. The Group VI metal catalyst is optionally a physically promoted Group VI metal catalyst.

公开(公告)号：US10022712B2

公开(公告)日：2018-07-17

申请号：US14269497

申请日：2014-05-05

Applicant: ExxonMobil Research and Engineering Company

Inventor： Stuart L. Soled ,  Sabato Miseo ,  Joseph E. Baumgartner ,  Iulian Nistor ,  Partha Nandi ,  Javier Guzman ,  Doron Levin ,  Keith Wilson ,  Jacob Arie Bergweff ,  Ronald Jan Huiberts ,  Arnold Van Loevezijn

IPC: B01J31/36 ,  B01J31/34 ,  C10G45/08 ,  B01J37/08 ,  B01J37/20 ,  B01J23/888 ,  B01J31/02 ,  B01J31/04 ,  B01J35/00 ,  B01J35/10 ,  B01J37/02 ,  C10G45/06 ,  C11B3/02 ,  A23D9/00 ,  B01J23/882 ,  B01J23/883 ,  B01J23/887

Abstract: The precursor of a hydroprocessing catalyst is made by impregnating a metal oxide component comprising at least one metal from Group 6 of the Periodic Table and at least one metal from Groups 8-10 of the Periodic Table with an amide formed from a first organic compound containing at least one amine group, and a second organic compound containing at least one carboxylic acid group. Following impregnation heat treatment follows to form in situ generated unsaturation additional to that in the two organic compounds. The catalyst precursor is sulfided to form an active, sulfide hydroprocessing catalyst.