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公开(公告)号:US10195600B2
公开(公告)日:2019-02-05
申请号:US15179032
申请日:2016-06-10
Applicant: ExxonMobil Research and Engineering Company
Inventor: Paul Podsiadlo , Quanchang Li , David C. Calabro , Kiara M. Benitez , Machteld M. W. Mertens , Scott J. Weigel , Doron Levin , Randall D. Partridge
IPC: B01J31/26 , B01J29/70 , B01J31/12 , B01J35/00 , B01J37/00 , C10G45/54 , C10G45/64 , C10G47/16 , B01J29/40 , B01J29/44 , B01J29/74 , C07C5/10
Abstract: Catalysts including at least one microporous material (e.g., zeolite), an organosilica material binder, and at least one catalyst metal are provided herein. Methods of making the catalysts, preferably without surfactants and processes of using the catalysts, e.g., for aromatic hydrogenation, are also provided herein.
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公开(公告)号:US20210040014A1
公开(公告)日:2021-02-11
申请号:US16928877
申请日:2020-07-14
Applicant: ExxonMobil Research and Engineering Company
Inventor: Vinit Choudhary , Doron Levin , Matthew S. Mettler , Joshua W. Allen
Abstract: The present disclosure relates to processes for the alkylation of isoparaffins. A process may include introducing, in a multistage reactor, a solid acid catalyst to an isoparaffin feed and an olefin feed at a pressure of about 300 psig to about 1500 psig to form a alkylation product mixture. A process may also include solid acid catalyst that includes a crystalline microporous material of the MWW framework type. In yet other embodiments, the present disclosure provides for processes for the alkylation of an isoparaffin. A process may include introducing, in a multistage reactor, a solid acid catalyst to an isoparaffin feed and an olefin feed at a temperature of from about 100° C. to about 200° C. to form an alkylation product mixture. A process may further include a solid acid catalyst that includes a crystalline microporous material of the MWW framework type.
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公开(公告)号:US20210040013A1
公开(公告)日:2021-02-11
申请号:US16928850
申请日:2020-07-14
Applicant: ExxonMobil Research and Engineering Company
Inventor: Doron Levin , Vinit Choudhary , Matthew S. Mettler , Joshua W. Allen
Abstract: The present disclosure is related to processes for the alkylation of an isoparaffin. The process may include introducing, in a multistage reactor, a solid acid catalyst including a zeolite to an isoparaffin feed and an olefin feed to form an alkylation product mixture including C5+ olefins. The processes may further include separating at least a portion of the C5+ olefins from the alkylation product mixture to form an oligomer light stream. The present disclosure further relates to multistage reactors for the alkylation of an isoparaffin with an olefin. The multistage reactors may include a plurality of stages, and a plurality of separation systems. The multistage reactors may also include an outlet space coupling each stage to a separation system and an inlet space coupling a separation system to a subsequent stage.
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公开(公告)号:US10022712B2
公开(公告)日:2018-07-17
申请号:US14269497
申请日:2014-05-05
Applicant: ExxonMobil Research and Engineering Company
Inventor: Stuart L. Soled , Sabato Miseo , Joseph E. Baumgartner , Iulian Nistor , Partha Nandi , Javier Guzman , Doron Levin , Keith Wilson , Jacob Arie Bergweff , Ronald Jan Huiberts , Arnold Van Loevezijn
IPC: B01J31/36 , B01J31/34 , C10G45/08 , B01J37/08 , B01J37/20 , B01J23/888 , B01J31/02 , B01J31/04 , B01J35/00 , B01J35/10 , B01J37/02 , C10G45/06 , C11B3/02 , A23D9/00 , B01J23/882 , B01J23/883 , B01J23/887
Abstract: The precursor of a hydroprocessing catalyst is made by impregnating a metal oxide component comprising at least one metal from Group 6 of the Periodic Table and at least one metal from Groups 8-10 of the Periodic Table with an amide formed from a first organic compound containing at least one amine group, and a second organic compound containing at least one carboxylic acid group. Following impregnation heat treatment follows to form in situ generated unsaturation additional to that in the two organic compounds. The catalyst precursor is sulfided to form an active, sulfide hydroprocessing catalyst.
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公开(公告)号:US20180187102A1
公开(公告)日:2018-07-05
申请号:US15631540
申请日:2017-06-23
Applicant: ExxonMobil Research and Engineering Company
Inventor: Kendall S. Fruchey , Michael B. Carroll , Timothy L. Hilbert , Sara K. Green , Doron Levin
IPC: C10G65/12 , C10G67/04 , C10M101/02 , C10M171/02 , C10M175/00
Abstract: Systems and methods are provided for block operation during lubricant and/or fuels production from deasphalted oil. During “block” operation, a deasphalted oil and/or the hydroprocessed effluent from an initial processing stage can be split into a plurality of fractions. The fractions can correspond, for example, to feed fractions suitable for forming a light neutral fraction, a heavy neutral fraction, and a bright stock fraction, or the plurality of fractions can correspond to any other convenient split into separate fractions. The plurality of separate fractions can then be processed separately in the process train (or in the sweet portion of the process train) for forming fuels and/or lubricant base stocks. The initial stage can optionally include a bulk hydrotreating catalyst to assist with increasing the space velocity in the initial stage.
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公开(公告)号:US20170354961A1
公开(公告)日:2017-12-14
申请号:US15179032
申请日:2016-06-10
Applicant: ExxonMobil Research and Engineering Company
Inventor: Paul Podsiadlo , Quanchang Li , David C. Calabro , Kiara M. Benitez , Machteld M.W. Mertens , Scott J. Weigel , Doron Levin , Randall D. Partridge
CPC classification number: B01J31/26 , B01J29/40 , B01J29/44 , B01J29/70 , B01J29/703 , B01J29/7038 , B01J29/7461 , B01J29/7476 , B01J31/125 , B01J31/127 , B01J35/0006 , B01J37/0009 , B01J2229/32 , B01J2229/36 , B01J2229/42 , B01J2231/641 , B01J2231/646 , C10G45/54 , C10G45/64 , C10G47/16
Abstract: Catalysts including at least one microporous material (e.g., zeolite), an organosilica material binder, and at least one catalyst metal are provided herein. Methods of making the catalysts, preferably without surfactants and processes of using the catalysts, e.g., for aromatic hydrogenation, are also provided herein.
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公开(公告)号:US20190105647A1
公开(公告)日:2019-04-11
申请号:US16212922
申请日:2018-12-07
Applicant: ExxonMobil Research and Engineering Company
Inventor: Paul Podsiadlo , Quanchang Li , David C. Calabro , Kiara M. Benitez , Machteld M.W. Mertens , Scott J. Weigel , Doron Levin , Randall D. Partridge
IPC: B01J31/26 , B01J29/70 , C07C5/10 , B01J31/12 , B01J29/74 , B01J29/44 , B01J29/40 , B01J35/00 , C10G47/16 , B01J37/00 , C10G45/54 , C10G45/64
Abstract: Catalysts including at least one microporous material (e.g., zeolite), an organosilica material binder, and at least one catalyst metal are provided herein. Methods of making the catalysts, preferably without surfactants and processes of using the catalysts, e.g., for aromatic hydrogenation, are also provided herein.
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公开(公告)号:US20170183580A1
公开(公告)日:2017-06-29
申请号:US15390896
申请日:2016-12-27
Applicant: ExxonMobil Research and Engineering Company
Inventor: Mohsen N. Harandi , Doron Levin , Himanshu Gupta , James R. Lattner , Glenn C. Wood , Keith K. Aldous , Timothy L. Hilbert , Michael B. Carroll , Ajit B. Dandekar , Sara L. Yohe , Stephen H. Brown , Tracie L. Owens , April D. Ross , Eric B. Senzer , Steven Pyl
IPC: C10G67/04 , C10M101/02
Abstract: Methods are provided for producing lubricant base stocks from deasphalted oils formed by sequential deasphalting. The deasphalted oil can be exposed a first deasphalting process using a first solvent that can provide a lower severity of deasphalting and a second deasphalting process using a second solvent that can provide a higher severity of deasphalting. This can result in formation of at least a deasphalted oil and a resin fraction. The resin fraction can represent a fraction that traditionally would have been included as part of a deasphalter rock fraction.
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公开(公告)号:US11325111B2
公开(公告)日:2022-05-10
申请号:US16212922
申请日:2018-12-07
Applicant: ExxonMobil Research and Engineering Company
Inventor: Paul Podsiadlo , Quanchang Li , David C. Calabro , Kiara M. Benitez , Machteld M. W. Mertens , Scott J. Weigel , Doron Levin , Randall D. Partridge
IPC: B01J31/00 , B01J31/26 , B01J29/40 , B01J29/44 , B01J29/70 , B01J29/74 , B01J31/12 , C07C5/10 , B01J35/00 , B01J37/00 , C10G45/54 , C10G45/64 , C10G47/16
Abstract: Catalysts including at least one microporous material (e.g., zeolite), an organosilica material binder, and at least one catalyst metal are provided herein. Methods of making the catalysts, preferably without surfactants and processes of using the catalysts, e.g., for aromatic hydrogenation, are also provided herein.
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公开(公告)号:US20200270533A1
公开(公告)日:2020-08-27
申请号:US16783598
申请日:2020-02-06
Applicant: ExxonMobil Research and Engineering Company
Inventor: Xiaochun Xu , Gregory J. De Martin , Keith Wilson , Doron Levin , Stuart L. Soled , Sabato Miseo
Abstract: The present disclosure provides processes for hydroprocessing hydrocarbon feedstocks comprising a silicon content of about 1 wppm or greater. In at least one embodiment, a process includes introducing, in a reactor or to the reactor, a hydrocarbon feedstock having a silicon content of at least about 1 wppm, based on the total weight of the hydrocarbon feedstock, to a treat gas to produce a hydrocarbon feedstock/treat gas mixture. The process includes introducing the hydrocarbon feedstock/treat gas mixture to a catalyst composition comprising at least one group 6 metal and at least one group 8-10 metal, wherein the molar ratio of group 6 metal to group 8-10 metal is from about 10:1 to about 1:10. The process includes obtaining a liquid product comprising a sulfur content of 5,000 wppm or less. Furthermore, processes of the present disclosure provide hydroprocessing of high Si content feeds using hydrocarbon feeds at high liquid hourly space velocities.
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