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公开(公告)号:US20240248419A1
公开(公告)日:2024-07-25
申请号:US18362566
申请日:2023-07-31
发明人: Ryosuke FUJII , Tomoya Sasaki , Hiroko Kobayashi , Yuto Okazaki , Kosuke Narita
CPC分类号: G03G5/056 , C08G63/54 , C08G64/06 , G03G5/0564
摘要: An electrophotographic photoreceptor contains a conductive substrate, and a lamination type photosensitive layer disposed on the conductive substrate and including a charge generation layer and a charge transport layer, in which the charge transport layer contains a charge transport material, at least one of a polyester resin or a polycarbonate resin that has a constitutional unit containing biphenyl represented by Formula (1), and an aromatic dicarboxylic acid represented by Formula (2),
in Formula (1), j represents an integer of 0 or greater and 4 or less, j pieces of R11's each independently represent a methyl group or an ethyl group, k represents an integer of 0 or greater and 4 or less, and k pieces of R12's each independently represent a methyl group or an ethyl group,
in Formula (2), p represents an integer of 0 or greater and 4 or less, p pieces of R21's each independently represent a methyl group or an ethyl group, q represents an integer of 0 or greater and 4 or less, q pieces of R22's each independently represent a methyl group or an ethyl group, r represents an integer of 0 or greater and 4 or less, r pieces of R23's each independently represent a methyl group or an ethyl group, and n represents 0 or 1.-
公开(公告)号:US12018128B2
公开(公告)日:2024-06-25
申请号:US17380016
申请日:2021-07-20
发明人: Tomoya Sasaki , Hidekazu Hirose , Kosaku Yoshimura , Yasunobu Kashima , Hajime Sugahara , Kosuke Nakada , Tomoyo Okubo
CPC分类号: C08G73/1067 , C08G73/1021 , C08G73/1032 , C08G73/1042 , C08J5/18 , C08J9/26 , C08J2201/046 , C08J2379/08
摘要: A particle-dispersed polyimide precursor solution contains a polyimide precursor having a unit represented by the following formula (I), particles, and a solvent, in which the particle-dispersed polyimide precursor solution satisfies both the following conditions (1) and (2),
(in the formula (I), A represents a tetravalent organic group, and B represents a divalent organic group represented by any of the following formulas (B1) to (B4)),
(in the formulas (B1) to (B4), Ar1, Ar10, and Ar11 each independently represent a trivalent aromatic group which may have a substituent, Ar2, Ar4, Ar5, Ar7 and Ar8 each independently represent a divalent aromatic group which may have a substituent, Ar3 and Ar6 each independently represent a tetravalent aromatic group which may have a substituent or a group represented by the following formula (II), Ar9 represents a divalent aromatic group which may have a substituent or a group represented by the following formula (III), X1 to X7 each independently represent NRa, O, or S, Ra represents a hydrogen atom, an alkyl group which may have a substituent, or an aryl group, and * represents a bonding site with an adjacent linking group), and
(in the formulas (II) and (III), Ar12 and Ar13 each independently represent a trivalent aromatic group which may have a substituent, Ar14 and Ar15 each independently represent a divalent aromatic group which may have a substituent, Y and Z each independently represent O, S, S(═O)2, or CRbRc, Rb and Rc each independently represent a hydrogen atom, an alkyl group which may have a substituent, or an aryl group, and * represents a bonding site with an adjacent linking group),
Condition (1): a total content of the groups represented by the formulas (B1) to (B4) is 1% by mass or more and 40% by mass or less with respect to a total amount of the polyimide precursor, and
Condition (2): a content of the particles is 5% by mass or more and 90% by mass or less with respect to a total content of the polyimide precursor and the particles.-
公开(公告)号:US20230266683A1
公开(公告)日:2023-08-24
申请号:US18171367
申请日:2023-02-19
发明人: Ryosuke Fujii , Tomoya Sasaki , Hiroko Kobayashi , Kohei Hashimoto , Yuto OKazaki , Kosuke Narita
CPC分类号: G03G5/0517 , G03G5/061443 , G03G5/06147 , G03G5/056 , G03G5/0564 , G03G15/75
摘要: An electrophotographic photoreceptor includes a conductive substrate, and a lamination type photosensitive layer disposed on the conductive substrate and including a charge generation layer and a charge transport layer, in which the charge transport layer contains a charge transport material, at least one of a polyester resin that has a constitutional unit having an aromatic ring or a polycarbonate resin that has a constitutional unit having an aromatic ring, and a compound (1) represented by Formula (1) and having a melting point of 40° C. or higher,
in Formula (1), Ar represents an aromatic ring that may have a substituent, L represents a single bond, an oxygen atom, or a sulfur atom, R represents an alkyl group having 1 or more and 10 or less carbon atoms, an aryl group having 6 or more and 20 or less carbon atoms, or an aralkyl group having 7 or more and 20 or less carbon atoms, and n represents an integer of 1 or greater.-
公开(公告)号:US20240036488A1
公开(公告)日:2024-02-01
申请号:US18304352
申请日:2023-04-21
发明人: Hiroko Kobayashi , Tomoya Sasaki , Yuto Okazaki , Ryosuke Fujii , Kosuke Narita
CPC分类号: G03G5/056 , G03G5/0564 , G03G21/1814
摘要: An electrophotographic photoreceptor includes a conductive substrate, and a lamination type photosensitive layer disposed on the conductive substrate and including a charge generation layer and a charge transport layer, in which the charge transport layer contains a charge transport material, a polyester resin, and a polycarbonate resin, and the polyester resin includes the following polyester resin (1),
polyester resin (1): a polyester resin having at least one selected from the group including a diol unit (B3) represented by Formula (B3), a diol unit (B5) represented by Formula (B5), a diol unit (B6) represented by Formula (B6), a diol unit (B7) represented by Formula (B7), a diol unit (B8) represented by Formula (B8), a diol unit (B9) represented by Formula (B9), a diol unit (B10) represented by Formula (B10), and a diol unit (B11) represented by Formula (B11),
in Formula (B3), Rb113 and Rb213 each independently represent a hydrogen atom, a linear alkyl group having 1 or more and 3 or less carbon atoms, an alkoxy group having 1 or more and 4 or less carbon atoms, or a halogen atom, d represents an integer of 7 or greater and 15 or less, and Rb403, Rb503, Rb803, and Rb903 each independently represent a hydrogen atom, an alkyl group having 1 or more and 4 or less carbon atoms, an alkoxy group having 1 or more and 6 or less carbon atoms, or a halogen atom,
in Formula (B5), Ar105 represents an aryl group having 6 or more and 12 or less carbon atoms or an aralkyl group having 7 or more and 20 or less carbon atoms, Rb205 represents a hydrogen atom or an alkyl group having 1 or more and 3 or less carbon atoms, and Rb405, Rb505, Rb805, and Rb905 each independently represent a hydrogen atom, an alkyl group having 1 or more and 4 or less carbon atoms, an alkoxy group having 1 or more and 6 or less carbon atoms, or a halogen atom,
in Formula (B6), Rb116 and Rb216 each independently represent a hydrogen atom, a linear alkyl group having 1 or more and 3 or less carbon atoms, an alkoxy group having 1 or more and 4 or less carbon atoms, or a halogen atom, e represents an integer of 4 or greater and 6 or less, and Rb406, Rb506, Rb806, and Rb906 each independently represent a hydrogen atom, an alkyl group having 1 or more and 4 or less carbon atoms, an alkoxy group having 1 or more and 6 or less carbon atoms, or a halogen atom,
in Formula (B7), Rb407, Rb507, Rb807, and Rb907 each independently represent a hydrogen atom, an alkyl group having 1 or more and 4 or less carbon atoms, an alkoxy group having 1 or more and 6 or less carbon atoms, or a halogen atom,
in Formula (B8), Rb408, Rb508, Rb808, and Rb908 each independently represent a hydrogen atom, an alkyl group having 1 or more and 4 or less carbon atoms, an alkoxy group having 1 or more and 6 or less carbon atoms, or a halogen atom,
in Formula (B9), Rb109 represents an alkyl group having 1 or more and 8 or less carbon atoms, Rb209 represents an alkyl group having 1 or more and 3 or less carbon atoms, and Rb409, Rb509, Rb809, and Rb909 each independently represent a hydrogen atom, an alkyl group having 1 or more and 4 or less carbon atoms, an alkoxy group having 1 or more and 6 or less carbon atoms, or a halogen atom,
in Formula (B10), Rb110 represents an alkyl group having 9 or more and 20 or less carbon atoms, Rb210 represents a hydrogen atom or an alkyl group having 1 or more and 3 or less carbon atoms, and Rb410, Rb510, Rb810, and Rb910 each independently represent a hydrogen atom, an alkyl group having 1 or more and 4 or less carbon atoms, an alkoxy group having 1 or more and 6 or less carbon atoms, or a halogen atom,
in Formula (B11), Rb411, Rb511, Rb811, and Rb911 each independently represent a hydrogen atom, an alkyl group having 1 or more and 4 or less carbon atoms, an alkoxy group having 1 or more and 6 or less carbon atoms, or a halogen atom.-
公开(公告)号:US20230266684A1
公开(公告)日:2023-08-24
申请号:US18171369
申请日:2023-02-19
发明人: Kosuke NARITA , Tomoya Sasaki , Ryosuke Fujii , Kohei Hashimoto , Hiroko Kobayashi , Yuto Okazaki
CPC分类号: G03G5/056 , G03G5/0564 , G03G5/061443 , G03G5/06147 , G03G5/144 , G03G15/0233 , G03G15/75
摘要: An image forming unit includes a photoreceptor and a charging member that comes into contact with a surface of the photoreceptor and charges the photoreceptor, in which the photoreceptor includes a conductive substrate, and a lamination type photosensitive layer disposed on the conductive substrate and including a charge generation layer and a charge transport layer, the charge transport layer contains at least one of a polyester resin that has a constitutional unit having an aromatic ring or a polycarbonate resin that has a constitutional unit having an aromatic ring, the charging member includes a support member and an elastic layer disposed on the support member, and the elastic layer has a storage elastic modulus G′ of 5.0 MPa or less at a frequency of 100 Hz in dynamic viscoelasticity measurement under a temperature condition of 24° C.
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公开(公告)号:US11427692B2
公开(公告)日:2022-08-30
申请号:US16787311
申请日:2020-02-11
发明人: Katsumi Nukada , Tomoya Sasaki , Takashi Imai
IPC分类号: C08J9/26 , C09D179/08 , C08F220/14 , C08F212/08 , C08J5/18 , C09D125/14 , C08G73/10
摘要: A polyimide precursor solution contains resin particles and a polyimide precursor. The resin particles in the polyimide precursor solution have a volume particle size distribution with one or more peaks. The volume frequency of a peak having the highest volume frequency of the one or more peaks accounts for 90% to 100% of the total volume frequency of all peaks of the volume particle size distribution.
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公开(公告)号:US12117741B1
公开(公告)日:2024-10-15
申请号:US18357793
申请日:2023-07-24
发明人: Hiroko Kobayashi , Tomoya Sasaki , Ryosuke Fujii , Yuto Okazaki , Kosuke Narita
CPC分类号: G03G15/0233 , G03G5/056 , G03G5/075 , G03G15/0194 , G03G21/0011 , G03G21/1814 , G03G5/043 , G03G2215/066 , G03G2221/183
摘要: An electrophotographic photoreceptor includes a conductive base body and a multilayered photosensitive layer disposed on the conductive base body and including a charge generation layer and a charge transport layer, wherein the charge transport layer is an uppermost surface layer and contains a charge transport material, a polyester resin, and a compound (T) represented by Formula (T) below, the polyester resin includes a polyester resin (1) including at least one selected from the group consisting of a diol unit (P1) represented by Formula (P1), a diol unit (P2) represented by Formula (P2), a diol unit (P3) represented by Formula (P3), a diol unit (P5) represented by Formula (P5), and a diol unit (P6) represented by Formula (P6), the polyester resin (1) further includes a unit including a biphenyl skeleton, and end groups of the polyester resin (1) do not include fluorine atoms.
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公开(公告)号:US11892780B1
公开(公告)日:2024-02-06
申请号:US18155032
申请日:2023-01-16
CPC分类号: G03G15/0233 , G03G5/0567 , G03G5/0605 , G03G5/061473 , G03G15/0806 , G03G15/752 , G03G21/0011 , G03G2215/00518
摘要: An image forming apparatus includes an electrophotographic photoreceptor that has a photosensitive layer constituting a surface of the electrophotographic photoreceptor, a charging device that charges the surface of the electrophotographic photoreceptor, an electrostatic charge image forming device that forms an electrostatic charge image on the charged surface of the electrophotographic photoreceptor, a developing device that accommodates a developer containing a toner which contains toner particles and an external additive, and develops the electrostatic charge image formed on the surface of the electrophotographic photoreceptor by the developer as a toner image, a transfer device that transfers the toner image formed on the surface of the electrophotographic photoreceptor to a surface of a recording medium, and a cleaning device that includes a cleaning blade coming into contact with the surface of the electrophotographic photoreceptor and cleaning at least residual toner particles on the surface of the electrophotographic photoreceptor.
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公开(公告)号:US11680156B2
公开(公告)日:2023-06-20
申请号:US17149724
申请日:2021-01-15
CPC分类号: C08L1/10 , C08J5/18 , C08J9/26 , C08L71/02 , C08J2301/10 , C08J2371/02 , C08J2425/06 , C08J2433/12 , C08J2479/08 , C08L2205/03
摘要: A polyimide precursor-containing aqueous composition contains at least one polymer material selected from the group consisting of a water-insoluble fibrous organic substance and a polyalkylene oxide having a viscosity-average molecular weight of 5 million or more, a polyimide precursor, particles, and water.
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公开(公告)号:US11680140B2
公开(公告)日:2023-06-20
申请号:US17146436
申请日:2021-01-11
发明人: Hajime Sugahara , Hidekazu Hirose , Kosaku Yoshimura , Tomoya Sasaki , Yasunobu Kashima , Kosuke Nakada , Tomoyo Okubo
CPC分类号: C08G73/1032 , C08J9/26 , C08J2379/08
摘要: A particle-dispersed polyimide precursor solution contains: a polyimide precursor consisting of a polymer of a tetracarboxylic dianhydride and a diamine containing a fluorene-based diamine having a fluorene skeleton; particles; and an aqueous solvent containing water.
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