Abstract:
A particulate mixture etc., which can be used as a precursor of lithium transition metal silicate-type compound of small particle size and low crystallinity, is provided. Further, a cathode active material that can undergo charge-and-discharge reaction in room temperature, and comprises lithium transition metal silicate-type compound, is provided.It is a mixture of silicon oxide particulates, transition metal oxide particulates, and lithium transition metal silicate particulates, and its powder X-ray diffraction measurement shows diffraction peaks near 2θ=33.1° and near 2θ=35.7°, and said silicon oxide particulates and said transition metal oxide particulates are amorphous, and said lithium transition metal silicate particulates are in a microcrystalline or amorphous state. Furthermore, a cathode active material obtained by grinding the active material aggregate obtained by heat-treating this particulate mixture is provided.
Abstract:
Porous silicon particles and complex porous silicon particles suitable for negative electrode materials etc. for lithium-ion batteries, which achieve high capacity and good cycling characteristics, are provided. Porous silicon particles formed by the joining of a plurality of silicon microparticles, and having an average particle diameter of 0.1 μm to 1000 μm, a three-dimensional network structure having continuous gaps, an average porosity of 15 to 93%, and a structure in which the particles of a whole particle are uniform. Complex porous silicon particles formed by the joining of a plurality of silicon microparticles and a plurality of silicon compound particles, and characterized by containing a compound of silicon and composite elements, having an average particle diameter of 0.1 μm to 1000 μm, and having a three-dimensional network structure having continuous gaps.
Abstract:
The purpose of the invention is to obtain a negative electrode for a large-capacity nonaqueous electrolyte rechargeable battery having good cycle characteristics. In the present invention, a negative electrode for a nonaqueous electrolyte rechargeable battery is used as a solution, said negative electrode being characterized by having an active material layer on a current collector, said active material layer containing at least granules, and one or more types of coating binder comprising any of a polyimide, polybenzimidazole, polyamide-imide and polyamide. The negative electrode is further characterized in that the granules contain at least active material particles containing: at least one type of element selected from a group comprising Si, Sn, Al, Pb, Sb, Bi, Ge, In and Zn; and a granulation binder.
Abstract:
A nanosized particle has a first phase that is a simple substance or a solid solution of element A, which is Si, Sn, Al, Pb, Sb, Bi, Ge, In or Zn, and a second phase that is a compound of element D, which is Fe, Co, Ni, Ca, Sc, Ti, V, Cr, Mn, Sr, Y, Zr, Nb, Mo, Ru, Rh, Ba, lanthanoid elements (not including Ce and Pm), Hf, Ta, W or Ir, and element A, or a compound of element A and element M, which is Cu, Ag, or Au. The first phase and second phase are bound via an interface, and are exposed to the outer surface. The surface of the first phase other than the interface is approximately spherical. Furthermore, a lithium ion secondary battery includes the nanosized particle as an anode active material.