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公开(公告)号：US09255227B2
公开(公告)日：2016-02-09
申请号：US12518616
申请日：2007-11-20
申请人： Finn Joensen , Poul Erik Højlund Nielsen , Niels Christian Schiødt , Ton V. W. Janssens , Bodil Voss
发明人： Finn Joensen , Poul Erik Højlund Nielsen , Niels Christian Schiødt , Ton V. W. Janssens , Bodil Voss
CPC分类号： C10G3/49 , C10G2300/1011 , C10G2300/1022 , C10G2300/805 , C10G2400/02 , C10G2400/20 , Y02P30/20
摘要： Process for the synthesis of hydrocarbon constituents of gasoline comprising catalytic conversion in a gasoline synthesis step of an oxygenate-containing feed comprising methanol and/or dimethyl ether and a mixture of at least on a total oxygenate basis 0.05 wt % C3+ higher alcohols and/or their oxygenate equivalents to hydrocarbon constituents of gasoline.
摘要翻译： 在包含甲醇和/或二甲醚的含氧化合物进料的汽油合成步骤和至少在总含氧化合物基础上的混合物，基于0.05重量％的C3 +高级醇和/或 它们的含氧化合物等同于汽油的烃成分。
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公开(公告)号：US08202413B2
公开(公告)日：2012-06-19
申请号：US12209499
申请日：2008-09-12
CPC分类号： C10G3/49 , C10G2300/4081 , C10G2400/02 , Y02P30/20
摘要： A process for the preparation of hydrocarbon products including the steps of (a) providing a stream containing oxygenates; (b) mixing the stream with a recycle stream to form a gasoline feed stream; (c) contacting the gasoline feed stream with one or more gasoline synthesis catalysts to obtain an effluent stream with higher hydrocarbons boiling in the gasoline range; (d) withdrawing from step (c) the effluent stream; and (e) splitting a part of the effluent stream to form the recycle stream which is optionally further reduced in content of water or enriched in hydrogen, then pressurized and recycled to step (b).
摘要翻译： 一种制备烃产物的方法，包括以下步骤：（a）提供含有氧化物的料流; （b）将料流与再循环料流混合以形成汽油进料流; （c）使汽油进料流与一种或多种汽油合成催化剂接触以获得在汽油范围内沸腾的高级烃的流出物流; （d）从步骤（c）退出流出物流; 和（e）分离一部分流出物流以形成循环物流，其任选地进一步减少水的含量或富含氢气，然后加压并再循环至步骤（b）。
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3.发明授权公开(公告)号：US08471060B2
公开(公告)日：2013-06-25
申请号：US12624019
申请日：2009-11-23
IPC分类号： C07C51/00
CPC分类号： C07C45/38 , B01J8/04 , C07C51/235 , C07C47/06 , C07C53/08
摘要： A process and reactor for the production of acetic acid comprising the steps of: passing a feed stream containing ethanol and water together with a predetermined feed rate of an oxygen containing atmosphere in presence of one or more catalysts being active in simultaneous non-oxidative and oxidative conversion of ethanol to a product stream with acetic acid; recovering from the product stream a stream of acetic acid; optionally recovering reactive derivatives of acetic acid and recycling these to step (a).
摘要翻译： 一种用于生产乙酸的方法和反应器，包括以下步骤：在一种或多种催化剂的存在下，使含有乙醇和水的进料流与预定的含氧气氛的进料速率一起通过同时进行的非氧化和氧化 用乙酸将乙醇转化成产物流; 从产物流中回收乙酸流; 任选地回收乙酸的活性衍生物并将其再循环到步骤（a）。
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4.发明申请公开(公告)号：US20100130776A1
公开(公告)日：2010-05-27
申请号：US12624019
申请日：2009-11-23
IPC分类号： C07C51/235 , B01J8/04
CPC分类号： C07C45/38 , B01J8/04 , C07C51/235 , C07C47/06 , C07C53/08
摘要： A process and reactor for the production of acetic acid comprising the steps of: passing a feed stream containing ethanol and water together with a predetermined feed rate of an oxygen containing atmosphere in presence of one or more catalysts being active in simultaneous non-oxidative and oxidative conversion of ethanol to a product stream with acetic acid; recovering from the product stream a stream of acetic acid; optionally recovering reactive derivatives of acetic acid and recycling these to step (a).
摘要翻译： 一种用于生产乙酸的方法和反应器，包括以下步骤：在一种或多种催化剂的存在下，使含有乙醇和水的进料流与预定的含氧气氛的进料速率一起通过同时进行的非氧化和氧化 用乙酸将乙醇转化成产物流; 从产物流中回收乙酸流; 任选地回收乙酸的活性衍生物并将其再循环到步骤（a）。
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公开(公告)号：US20100130775A1
公开(公告)日：2010-05-27
申请号：US12622820
申请日：2009-11-20
IPC分类号： C07C53/08
摘要： Process for the preparation of acetic acid comprising the steps of: providing a feed stream of water and ethanol; adding the feed stream to a recycle stream comprising unconverted ethanol and water; heating the admixture to a predetermined reaction temperature and passing the thus heated admixture over a catalyst being active in non-oxidative conversion of ethanol to acetic acid to obtain an effluent being rich in acetic acid; optionally cooling the effluent; separating the effluent into a stream rich in acetic acid being essentially free of water, a hydrogen containing stream, and a stream with unconverted amounts of ethanol, water and reactive derivates of acetic acid and optionally ethyl acetate; recycling the stream with unconverted amounts of ethanol and water to step (a); determining the amount of water in the recycle stream and adjusting the composition of the ethanol and water feed stream in step (a) to a water/ethanol mole ratio of between 0.3/0.7 to 0.6/0.4.
摘要翻译： 制备乙酸的方法，包括以下步骤：提供水和乙醇的进料流; 将进料流加入到包含未转化的乙醇和水的再循环流中; 将混合物加热到预定的反应温度，并将如此加热的混合物通过催化剂，在乙醇非氧化转化成乙酸中有活性的催化剂，得到富含乙酸的流出液; 任选地冷却流出物; 将流出物分离成富含乙酸的物流，其基本上不含水，含氢气流，以及具有未转化量的乙醇，水和乙酸和任选的乙酸乙酯的反应性衍生物的物流; 将未转化量的乙醇和水回收到步骤（a）; 确定再循环流中的水量，并将步骤（a）中的乙醇和水进料流的组成调节至0.3 / 0.7-0.6 / 0.4之间的水/乙醇摩尔比。
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公开(公告)号：US08677762B2
公开(公告)日：2014-03-25
申请号：US12674272
申请日：2008-08-13
IPC分类号： F02C6/18
CPC分类号： C07C29/1518 , C07C41/01 , C10G3/42 , C10G2300/1022 , C10G2400/02 , Y02E20/14 , Y02P30/20 , C07C31/04 , C07C43/043
摘要： A process for the preparation of hydrocarbon products and for the generation of power that includes the steps of (a) providing a synthesis gas having a hydrogen to carbon monoxide ratio of between 0.1 and 1; (b) contacting the synthesis gas with one or more catalysts which together catalyse a reaction of hydrogen and carbon monoxide to oxygenates comprising methanol and dimethyl ether with a dimethyl ether to methanol ratio of higher than 2 and a carbon dioxide content of above 20 mole %; (c) contacting the carbon dioxide containing oxygenate mixture at an inlet temperature of between 240° and 4000° C. with a catalyst being active in the conversion of oxygenate to higher hydrocarbons and a tail gas being rich in carbon dioxide; (d) combusting the carbon dioxide rich tail gas in a gas turbine combustion chamber to flue gas; and (e) expanding the flue gas stream through a gas turbine for the generation of power.
摘要翻译： 一种用于制备烃产物和产生动力的方法，包括以下步骤：（a）提供氢与一氧化碳比为0.1至1的合成气; （b）使合成气与一种或多种催化剂接触，这些催化剂一起催化氢和一氧化碳与包含甲醇和二甲醚的含氧化合物的反应，甲醚与甲醇的比例高于2，二氧化碳含量高于20摩尔％ ; （c）在240℃和4000℃之间的入口温度下与含氧化合物混合物的接触与在含氧化合物转化为高级烃和富含二氧化碳的尾气中具有活性的催化剂接触; （d）将燃气轮机燃烧室中的富含二氧化碳的尾气燃烧成烟道气; 和（e）通过用于发电的燃气轮机扩大烟气流。
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公开(公告)号：US20100036186A1
公开(公告)日：2010-02-11
申请号：US12518616
申请日：2007-11-20
申请人： Finn Joensen , Poul Erik Hojlund Nielsen , Niels Christian Schiodt , Ton V.W. Janssens , Bodil Voss
发明人： Finn Joensen , Poul Erik Hojlund Nielsen , Niels Christian Schiodt , Ton V.W. Janssens , Bodil Voss
IPC分类号： C07C1/20
CPC分类号： C10G3/49 , C10G2300/1011 , C10G2300/1022 , C10G2300/805 , C10G2400/02 , C10G2400/20 , Y02P30/20
摘要： Process for the synthesis of hydrocarbon constituents of gasoline comprising catalytic conversion in a gasoline synthesis step of an oxygenate-containing feed comprising methanol and/or dimethyl ether and a mixture of at least on a total oxygenate basis 0.05 wt % C3+ higher alcohols and/or their oxygenate equivalents to hydrocarbon constituents of gasoline.
摘要翻译： 在包含甲醇和/或二甲醚的含氧化合物进料的汽油合成步骤和至少在总含氧化合物基础上的混合物，基于0.05重量％的C3 +高级醇和/或 它们的含氧化合物等同于汽油的烃成分。
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公开(公告)号：US20110314834A1
公开(公告)日：2011-12-29
申请号：US12674272
申请日：2008-08-13
IPC分类号： F02C6/18
CPC分类号： C07C29/1518 , C07C41/01 , C10G3/42 , C10G2300/1022 , C10G2400/02 , Y02E20/14 , Y02P30/20 , C07C31/04 , C07C43/043
摘要： A process for the preparation of hydrocarbon products and for the generation of power comprising the steps of (a) providing a synthesis gas having a hydrogen to carbon monoxide ratio of between 0.1 and 1; (b) contacting the synthesis gas with one or more catalysts which together catalyse a reaction of hydrogen and carbon monoxide to oxygenates comprising methanol and dimethyl ether with a dimethyl ether to methanol ratio of higher than 2 and a carbon dioxide content of above 20 mole %; (c) contacting the carbon dioxide containing oxygenate mixture at an inlet temperature of between 240 and 4000 C with a catalyst being active in the conversion of oxygenate to higher hydrocarbons and a tail gas being rich in carbon dioxide; (d) combusting the carbon dioxide rich tail gas, optionally admixed with fresh carbon monoxide rich synthesis gas in a gas turbine combustion chamber to flue gas; and (e) expanding the flue gas stream through a gas turbine for the generation of power.
摘要翻译： 一种用于制备烃产物和产生动力的方法，包括以下步骤：（a）提供氢与一氧化碳比为0.1至1的合成气; （b）使合成气与一种或多种催化剂接触，这些催化剂一起催化氢和一氧化碳与包含甲醇和二甲醚的含氧化合物的反应，甲醚与甲醇的比例高于2，二氧化碳含量高于20摩尔％ ; （c）在240至4000℃的入口温度下使含二氧化碳混合物与含氧化合物转化为高级烃和富含二氧化碳的尾气有活性的催化剂接触; （d）燃烧富含二氧化碳的尾气，任选地与燃气轮机燃烧室中的新鲜的富含一氧化碳的合成气混合成烟道气; 和（e）通过用于发电的燃气轮机扩大烟气流。
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公开(公告)号：US5908963A
公开(公告)日：1999-06-01
申请号：US894066
申请日：1997-12-12
申请人： Bodil Voss , Finn Joensen , John Bogild Hansen
发明人： Bodil Voss , Finn Joensen , John Bogild Hansen
CPC分类号： C07C41/01
摘要： A process for the preparation of dimethyl ether. The process prepares fuel grade dimethyl ether from a hydrogen and carbon oxides synthesis gas.
摘要翻译： PCT No.PCT / DK96 / 00047 Sec。 371日期1997年12月12日 102（e）日期1997年12月12日PCT 1996年1月29日PCT PCT。 公开号WO96 / 23755 日期1996年8月8日制备二甲醚的方法。 该方法由氢和碳氧化物合成气制备燃料级二甲醚。
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公开(公告)号：US5728871A
公开(公告)日：1998-03-17
申请号：US832880
申请日：1997-04-04
申请人： Finn Joensen , Bodil Voss , Ib Dybkj.ae butted.r
发明人： Finn Joensen , Bodil Voss , Ib Dybkj.ae butted.r
IPC分类号： B01J23/80 , B01J27/13 , C07B61/00 , C07C29/151 , C07C41/01 , C07C51/10 , C07C51/12 , C07C53/08 , C07C67/36
CPC分类号： C07C41/01 , C07C29/151 , C07C51/12 , Y02P20/52
摘要： A process for the preparation of acetic acid by catalytic conversion of a synthesis gas being rich in hydrogen and carbon monoxide, comprising steps of: (i) introducing a stream of the synthesis gas into a first reaction step at a predetermined pressure and temperature and reacting the synthesis gas in the presence of a catalyst being active in formation of methanol and dehydration of methanol, so as to obtain a gaseous process phase containing methanol, dimethyl ether, and water; (ii) cooling the gaseous process phase of step (i) and obtaining a liquid phase with the methanol, dimethyl ether and water and a gaseous phase comprising carbon dioxide and residual amounts of dimethyl ether; (iii) introducing the liquid phase formed in step (ii) into a second reaction step at a predetermined pressure and temperature and adding a predetermined amount of carbon monoxide; and (iv) carbonylating methanol and dimethyl ether in the liquid phase with carbon monoxide by contact with a catalyst being active in the carbonylation of alcohols and ethers with carbon monoxide; and (v) recovering from effluent of step (iv) a product stream mainly consisting of the acetic acid product.
摘要翻译： 一种通过催化转化富氢和一氧化碳的合成气来制备乙酸的方法，包括以下步骤：（i）将合成气流在预定压力和温度下引入第一反应步骤，并使 在催化剂存在下，合成气在甲醇形成和甲醇脱水过程中起作用，得到含有甲醇，二甲醚和水的气相工艺相; （ii）冷却步骤（i）的气相工艺阶段，并用甲醇，二甲醚和水以及包含二氧化碳和残留量二甲醚的气相获得液相; （iii）将步骤（ii）中形成的液相以预定的压力和温度引入第二反应步骤并加入预定量的一氧化碳; 和（iv）通过与醇和醚与一氧化碳的羰基化反应活性的催化剂接触将液相中的甲醇和二甲醚与一氧化碳反应; 和（v）从步骤（iv）的流出物回收主要由乙酸产物组成的产物流。
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