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    Process for preparing organic glasses
    3.
    发明授权
    Process for preparing organic glasses 失效
    制备有机眼镜的方法

    公开(公告)号：US5128384A

    公开(公告)日：1992-07-07

    申请号：US751648

    申请日：1991-08-26

    申请人： Fiorenzo Renzi ,  Franco Rivetti ,  Claudio Gagliardi ,  Ugo Romano

    发明人： Fiorenzo Renzi ,  Franco Rivetti ,  Claudio Gagliardi ,  Ugo Romano

    IPC分类号： C08F299/02 ,  C08F2/46 ,  C08F18/24 ,  C08F290/00 ,  C08F290/06 ,  C09D4/00 ,  C09J163/00 ,  C09J163/10 ,  G02B1/04

    CPC分类号： C08F290/061 ,  C08F18/24 ,  G02B1/04

    摘要： Organic glasses and surface coatings are prepared, with short hardening cycles, by submitting to the action of U.V. light a liquid polymerizable composition containing at least one di-(allyl carbonate) or poly(allyl carbonate) of a diol or polyol, a photoinitiator and a vinyl ester monomer and/or an organic peroxide.The composition can additionally contain small amounts of an organic compound selected from among those compounds which are used in the art in order to stabilize the organic polymers to the degrading action of U.V. light.The composition is preferably heated before being treated with U.V. light.

    摘要翻译： 制备有机玻璃和表面涂层，具有短的硬化周期，通过提交U.V.的作用。 点亮含有二醇或多元醇，光引发剂和乙烯基酯单体和/或有机过氧化物的至少一种二（碳酸烯丙酯）或聚（碳酸烯丙酯）的液体可聚合组合物。 该组合物可以另外含有少量的选自本领域中使用的那些化合物中的有机化合物，以便将有机聚合物稳定到紫外线的降解作用。 光。 组合物优选在用紫外线处理之前加热。 光。

    Organic glass with improved impact strength and with a refractive index equal or similar to that of mineral glass
    7.
    发明授权
    Organic glass with improved impact strength and with a refractive index equal or similar to that of mineral glass 失效
    有机玻璃具有改善的冲击强度，折射率等于或类似于矿物玻璃

    公开(公告)号：US5286816A

    公开(公告)日：1994-02-15

    申请号：US49600

    申请日：1993-04-20

    申请人： Franco Rivetti ,  Fiorenzo Renzi ,  Claudio Gagliardi

    发明人： Franco Rivetti ,  Fiorenzo Renzi ,  Claudio Gagliardi

    IPC分类号： C08F4/34 ,  C08F218/00 ,  G02B1/04 ,  C08F216/12 ,  C08F218/12 ,  C08F226/06

    CPC分类号： C08F218/00 ,  G02B1/04

    摘要： An organic glass with improved impact strength and with a refractive index equal or similar to that of mineral glass (crown glass), is composed of the product of the radicalic polymerization of the polymerizable liquid composition obtained by the transesterification of:(A) diallyl carbonate with a mixture of polyols:(B) bis(2-hydroxyethylether) of bisphenol-A,(C) diethylene glycol, and(D) tris(hydroxyethyl) isocyanurate,where for every 100 parts b.w. of the sum of polyols (B), (C) and (D), polyol (B) is present in a quantity of from 20 to 60% b.w., polyol (C) is present in a quantity of from 20 to 60% b.w. and polyol (D) is present in a quantity of from 10 to 40% b.w.; and where the molar ratio between the diallyl carbonate and the sum of polyols (A)/(B)+(C)+(D) is equal to or higher than 3/1.

    摘要翻译： 具有与矿物玻璃（冠状玻璃）相同或相似的折射率改善的有机玻璃由通过酯交换反应获得的可聚合液体组合物的自由基聚合的产物组成：（A）碳酸二烯丙酯 与双酚A的（B）双（2-羟基乙基醚），（C）二甘醇和（D）三（羟乙基）异氰脲酸酯的（B）双（2-羟基乙醚）的混合物，其中每100份bw 的多元醇（B），（C）和（D）的总和，多元醇（B）的存在量为20至60％b.w.多元醇（C）的存在量为20至60％b.w。 和多元醇（D）的存在量为10-40％b.w。 并且其中二烯丙基碳酸酯与多元醇（A）/（B）+（C）+（D）之和的摩尔比等于或高于3/1。

    Liquid polymerizable composition for the production of high refractive index optical articles
    8.
    发明授权
    Liquid polymerizable composition for the production of high refractive index optical articles 失效
    用于生产高折射率光学制品的液体可聚合组合物

    公开(公告)号：US5204430A

    公开(公告)日：1993-04-20

    申请号：US702153

    申请日：1991-05-14

    申请人： Fiorenzo Renzi ,  Franco Rivetti ,  Ugo Romano ,  Claudio Gagliardi ,  Umberto Sgambato

    发明人： Fiorenzo Renzi ,  Franco Rivetti ,  Ugo Romano ,  Claudio Gagliardi ,  Umberto Sgambato

    IPC分类号： C08F218/00 ,  G02B1/04

    CPC分类号： C08F218/00 ,  G02B1/04

    摘要： A liquid composition comprising:(A) a monomeric, or essentially monomeric, diallyl-carbonate of a possibly halogenated diol containing aromatic groups; or a diallyl-ester of a halogenated aromatic bicarboxy acid;(B) a reactive monomer selected from diallyl orthophthalate, diallyl isophthalate, diallyl terephthalate, triallyl cyanurate and triallyl isocyanurate;(C) an oligomeric, or essentially oligomeric, diallyl-carbonate of diethylene glycolis polymerized under the action of a free-radical initiator, in order to yield optical articles having a high refractive index, low light dispersion, and with enhanced mechanical and color characteristics.

    摘要翻译： 一种液体组合物，其包含：（A）含有芳族基团的可能卤化的二醇的单体或基本上单体的二烯丙基碳酸酯; 或卤代芳族二羧酸的二烯丙基酯; （B）选自邻苯二甲酸二烯丙酯，间苯二甲酸二烯丙酯，对苯二甲酸二烯丙酯，氰尿酸三烯丙酯和异氰脲酸三烯丙酯的反应性单体; （C）二甘醇二烯丙基酯或二烯丙基二烯丙基酯的碳酸酯在自由基引发剂的作用下聚合，以产生具有高折射率，低光分散性和增强的机械和颜色的光学制品 特点

    Liquid composition polymerizable into organic glasses of high refractive index
    9.
    发明授权
    Liquid composition polymerizable into organic glasses of high refractive index 失效
    可折叠成高折射率有机玻璃的液体组合物

    公开(公告)号：US5059663A

    公开(公告)日：1991-10-22

    申请号：US561793

    申请日：1990-08-02

    申请人： Franco Rivetti ,  Fiorenzo Renzi

    发明人： Franco Rivetti ,  Fiorenzo Renzi

    IPC分类号： C07C69/96 ,  C08F218/00 ,  C08F290/00 ,  C08F299/00 ,  G02B1/04

    CPC分类号： C08F218/00 ,  G02B1/04

    摘要： A liquid composition stable during storage and polymerizable radically into organic glasses having a high refractive index, containing:(A) from 20 to 80% wt of a mixture of monomer and oligomers of a carbonic allyl derivative representable by the formula (I): ##STR1## where: X=halogen (except fluorine);a and be independently assume the values 1 or 2;n assumes values from 1 to 5 on condition that at least 10% by weight of the mixture consists of carbonic allyl oligomer derivatives (n>1); and(B) from 80 to 20% by weight of a liquid monomer copolymerizable with the component (A) and chosen from diallyl isophthalate, diallyl terephthalate, triallyl cyanurate and triallyl isocyanurate.

    Liquid polymerizable compositions for the production of substitutes for optical glasses
    10.
    发明授权
    Liquid polymerizable compositions for the production of substitutes for optical glasses 失效
    用于生产光学眼镜替代物的液体可聚合组合物

    公开(公告)号：US4835233A

    公开(公告)日：1989-05-30

    申请号：US237664

    申请日：1988-08-25

    申请人： Fiorenzo Renzi ,  Franco Rivetti ,  Ugo Romano

    发明人： Fiorenzo Renzi ,  Franco Rivetti ,  Ugo Romano

    IPC分类号： C08F18/00 ,  C08F218/00 ,  C08F290/00 ,  C08F299/02 ,  G02B1/04

    CPC分类号： C08F218/00 ,  G02B1/04

    摘要： A liquid, fluid composition, comprising:(a) bis(allylcarbonate) of monomer diethylene glycol;(b) bis(allylcarbonate) of oligomer diethylene glycol;(c) tris(allylcarbonate) of monomer tris(hydroxyethyl)isocyanurate;(d) a monofunctional, unsaturated vinyl or methacryl ester monomer,is polymerized inside a mould (casting process), with fast polymerization cycle, to yield optical articles.

    摘要翻译： 一种液体流体组合物，其包含：（a）单体二甘醇的双（烯丙基碳酸酯）; （b）低聚物二甘醇二（烯丙基碳酸酯）; （c）单体三（羟乙基）异氰脲酸酯的三（碳酸烯丙酯） （d）单官能的，不饱和的乙烯基或甲基丙烯酸酯单体在模具（铸造工艺）内聚合，具有快速的聚合循环，以产生光学制品。