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1.发明授权
公开(公告)号：US5032653A
公开(公告)日：1991-07-16
申请号：US212689
申请日：1988-06-28
摘要： A method is provided for the direct synthesis of novel polymeric materials functionalized with desirable nitrogen-containing functional groups such as terminal azido, cyano, carbonylamino or thiocarbonylamino groups. Polymerization and functionalization occur in a substantially simultaneous manner. All necessary reactants for the functionalization are present when polymerization is initiated. The nitrogen-containing functional group is provided as a part of a molecule having a release moiety which is preferably resonance stabilized or a tertiary alkyl type and which acts to aid the nitrogen-containing species in functioning as a leaving group.
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2.发明授权Terminally-substituted polymeric compositions from cationically polymerizable monomers and initiators 失效来自阳离子可聚合单体和引发剂的末端取代的聚合物组合物
公开(公告)号：US5336745A
公开(公告)日：1994-08-09
申请号：US700980
申请日：1991-05-16
摘要： A method is provided for the direct synthesis of novel polymeric materials functionalized with desirable nitrogen-containing functional groups such as terminal azido, cyano, carbonylamino or thiocarbonylamino groups. Polymerization and functionalization occur in a substantially simultaneous manner. All necessary reactants for the functionalization are present when polymerization is initiated. The nitrogen-containing functional group is provided as a part of a molecule having a release moiety which is preferably resonance stabilized or of tertiary alkyl type and which acts to aid the nitrogen-containing species in functioning as a leaving group.
摘要翻译： 提供了一种用于直接合成用所需含氮官能团如末端叠氮基，氰基，羰基氨基或硫代羰基氨基官能化的新型聚合物的方法。 聚合和官能化基本上同时发生。 当开始聚合时，存在用于官能化的所有必需的反应物。 提供含氮官能团作为分子的一部分，其具有优选共振稳定的或叔烷基型的释放部分，并且用于帮助含氮物质起到离去基团的作用。
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公开(公告)号：US4982045A
公开(公告)日：1991-01-01
申请号：US385712
申请日：1989-07-26
申请人： Frank J. Chen , Robert D. Lundberg
发明人： Frank J. Chen , Robert D. Lundberg
IPC分类号： C08F10/08
CPC分类号： C08F10/08
摘要： This process is one in which a butene feed is passed through a fixed bed of granular aluminum trichloride catalyst, preferably in the presence of an added co-catalyst, to produce a polymerized butene product having number-average molecular weight of greater than about 250.
摘要翻译： 该方法是使丁烯进料通过三氯化钛颗粒催化剂的固定床，优选在加入的助催化剂存在下，生产数均分子量大于约250的聚合丁烯产物。
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4.发明授权Process for preparing polybutenes having enhanced reactivity using boron trifluoride catalysts (PT-647) 失效使用三氟化硼催化剂（PT-647）制备具有增强反应性的聚丁烯的方法
公开(公告)号：US4849572A
公开(公告)日：1989-07-18
申请号：US136867
申请日：1987-12-22
CPC分类号： B01J19/1881 , B01J19/0013 , C08F10/10 , B01J2219/00099 , F02B2275/14
摘要： There is provided a process for preparing polybutenes having enhanced reactivity using a BF.sub.3 catalyst and an immediate quench procedure and controlled polymerization times of 12 to 40 minutes in combination with isobutylene conversions of at least 70%.
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公开(公告)号：US5563313A
公开(公告)日：1996-10-08
申请号：US398463
申请日：1995-03-03
申请人： Tze-Chiang Chung , Frank J. Chen , Jon E. Stanat , Alok Kumar
发明人： Tze-Chiang Chung , Frank J. Chen , Jon E. Stanat , Alok Kumar
CPC分类号： C08F10/00
摘要： Immobilized Lewis Acid catalyst comprising polymer having at least one Lewis Acid immobilized within the structure therein, said polymer having monomer units represented by the structural formula:--[A].sub.a --[B].sub.b --[C].sub.c --wherein a represents about 1 to about 99 mole %b represents about 0 to about 50 mole %c represents about 1 to about 99 mole %a+b+c is preferably about 100%; ##STR1## C is selected from the group consisting of: ##STR2## (III) combinations thereof, wherein D is OH, halide, OR.sup.4, NH.sub.2, NHR.sup.3, OM', or OM";E is the residue of the reaction of at least one Lewis Acid with the D substituent of monomer unit B;R.sup.1 represents proton, C.sub.1 -C.sub.24 alkyl group, or C.sub.3 -C.sub.24 cycloalkyl;R.sup.2 represents C.sub.1 -C.sub.24 alkylene group, C.sub.3 -C.sub.24 cycloalkylene, C.sub.6 -C.sub.18 arylene, or C.sub.7 -C.sub.30 alkylarylene;R.sup.3 represents C.sub.1 -C.sub.24 alkyl, C.sub.3 -C.sub.24 cycloalkyl, C.sub.1 -C.sub.24 aryl, or C.sub.7 -C.sub.30 alkylaryl;R.sup.4 represents C.sub.1 -C.sub.24 alkyl, C.sub.3 -C.sub.24 cycloalkyl, C.sub.1 -C.sub.24 aryl, or C.sub.7 -C.sub.30 alkylaryl;M' represents alkali metal;M" represents alkaline-earth metal.Also disclosed are polymerization and alkylation processes utilizing the immobilized Lewis Acid catalysts. Another aspect of the present invention is a method of manufacturing immobilized Lewis Acid catalysts.
摘要翻译： 固定化路易斯酸催化剂，其包含具有固定在其结构内的至少一种路易斯酸的聚合物，所述聚合物具有由以下结构式表示的单体单元： - [A] a- [B] b- [C] c - 其中a表示约1 至约99摩尔％b表示约0至约50摩尔％c表示约1至约99摩尔％a + b + c优选约100％; 其中D是OH，卤化物，OR4，NH2，NHR3，OM'或其组合的组合。 OM“ E是至少一种路易斯酸与单体单元B的D取代基反应的残基; R1表示质子，C1-C24烷基或C3-C24环烷基; R2表示C1-C24亚烷基，C3-C24亚环烷基，C6-C18亚芳基或C7-C30烷基亚芳基; R3表示C1-C24烷基，C3-C24环烷基，C1-C24芳基或C7-C30烷基芳基; R4表示C1-C24烷基，C3-C24环烷基，C1-C24芳基或C7-C30烷基芳基; M'表示碱金属; M“表示碱土金属。 还公开了使用固定化的路易斯酸催化剂的聚合和烷基化方法。 本发明的另一方面是制备固定化的路易斯酸催化剂的方法。
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6.发明授权AlCl.sub.3 -catalyzed process for preparing poly-N-butenes from mixed butenes 失效用于从混合丁烯制备聚-N-丁烯的AlCl 3催化方法
公开(公告)号：US5326921A
公开(公告)日：1994-07-05
申请号：US947904
申请日：1992-09-18
申请人： Frank J. Chen
发明人： Frank J. Chen
IPC分类号： C08F10/08 , C08F240/00 , C07C2/02
CPC分类号： C08F240/00 , C08F10/08
摘要： Poly-n-butene is prepared from a mixed C.sub.4 hydrocarbon feedstream containing less than about 5 wt. % isobutylene using an AlCl.sub.3 -HCl catalyst system wherein the HCl is introduced separately into the feedstream to form organochloride in the feedstream. Polymer product having a very narrow molecular weight distribution is obtained over the M.sub.n range of 300 to 900.
摘要翻译： 聚正丁烯由含有小于约5wt。％的混合C4烃原料流制备。 使用AlCl 3 -HCl催化剂体系的％异丁烯，其中将HCl单独引入进料流中以在进料流中形成有机氯化物。 通过300至900的＆upbar＆Mn范围获得具有非常窄的分子量分布的聚合物产物。
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公开(公告)号：US5288677A
公开(公告)日：1994-02-22
申请号：US723130
申请日：1991-06-28
申请人： Tze-Chiang Chung , Frank J. Chen , Jon E. Stanat , Alok Kumar
发明人： Tze-Chiang Chung , Frank J. Chen , Jon E. Stanat , Alok Kumar
CPC分类号： C08F10/00
摘要： Immobilized Lewis Acid catalyst comprising polymer having at least one Lewis Acid immobilized within the structure therein, said polymer having monomer units represented by the structural formula: ##STR1## wherein a represents about 1 to about 99 mole % b represents about 0 to about 50 mole %c represents about 1 to about 99 mole %a+b+c is preferably about 100%; ##STR2## C is selected from the group consisting of: ##STR3## D is OH, halide, OR.sup.4, NH.sub.2, NHR.sup.3, OM', or OM"; E is the residue of the reaction of at least one Lewis Acid with the D substituent of monomer unit B;R.sup.1 represents proton, C.sub.1 -C.sub.24 alkyl group, or C.sub.3 -C.sub.24 cycloalkyl;R.sup.2 represents C.sub.1 -C.sub.24 alkyl group, C.sub.3 -C.sub.24 cycloalkyl, C.sub.6 -C.sub.18 aryl, or C.sub.7 -C.sub.30 alkylaryl;R.sup.3 represents C.sub.6 -C.sub.18 alkyl, C.sub.3 -C.sub.24 cycloalkyl, C.sub.6 -C.sub.18 aryl, or C.sub.7 -C.sub.30 alkylaryl;R.sup.4 represents C.sub.6 -C.sub.18 alkyl, C.sub.3 -C.sub.24 cycloalkyl, C.sub.6 -C.sub.18 aryl, or C.sub.7 -C.sub.30 alkylaryl;M' represents alkali metal;M" represents alkaline-earth metal.Also disclosed are polymerization and alkylation processes utilizing the immobilized Lewis Acid catalysts. Another aspect of the present invention is a method of manufacturing immobilized Lewis Acid catalysts.
摘要翻译： 固定化路易斯酸催化剂，其包含具有固定在其结构内的至少一种路易斯酸的聚合物，所述聚合物具有由以下结构式表示的单体单元：（*化学结构*）其中a表示约1至约99摩尔％b表示约0至 约50摩尔％c表示约1至约99摩尔％a + b + c优选约100％; （*化学结构*）（*化学结构*）C选自：（*化学结构*）（I）（*化学结构*）（II）的组合。（III）D是OH，卤化物 ，OR4，NH2，NHR3，OM'或OM“; E是至少一种路易斯酸与单体单元B的D取代基反应的残基; R 1表示质子，C 1 -C 24烷基或C 3 -C 24 环烷基; R2表示C1-C24烷基，C3-C24环烷基，C6-C18芳基或C7-C30烷基芳基; R3表示C6-C18烷基，C3-C24环烷基，C6-C18芳基或C7-C30烷基芳基; R4 代表C 6 -C 18烷基，C 3 -C 24环烷基，C 6 -C 18芳基或C 7 -C 30烷基芳基; M'表示碱金属; M“表示碱土金属。 还公开了利用固定化的路易斯酸催化剂的聚合和烷基化方法。 本发明的另一方面是制备固定化的路易斯酸催化剂的方法。
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8.发明授权
公开(公告)号：US5017279A
公开(公告)日：1991-05-21
申请号：US479328
申请日：1990-02-13
申请人： Alexis A. Oswald , Frank J. Chen , Ramon L. Espino , Kuo L. Peng
发明人： Alexis A. Oswald , Frank J. Chen , Ramon L. Espino , Kuo L. Peng
IPC分类号： C10G50/02 , C10G69/12 , C10M107/10
CPC分类号： C10G50/02 , C10G69/123 , C10M107/10 , C10M2205/00 , C10M2205/028
摘要： A multistep process is disclosed for the manufacture of synthetic lubricants from the C.sub.8 to C.sub.24 linear olefin components of below liquid fuel value petroleum distillate fractions derived via the high temperature thermal cracking of petroleum residua. Such feeds contain major amounts of 1-n-olefins, n-paraffins and greater than 0.1% concentration of sulfur mostly in the form aromatic, thiophene type sulfur compounds.In the first step of the present process such feeds are enriched in the straight chain aliphatic hydrocarbon components by one or more separation processes, preferably via urea adduction or by crystallization. In the second step, the olefin components are oligomerized to sulfur containing C.sub.30 to C.sub.60 polyolefins, preferably in the presence of BF.sub.3 complex catalysts. In the third step, the polyolefins are hydrogenated to novel isoparaffin lubricants in the presence of sulfur resistant catalysts, preferably transition metal sulfides.
摘要翻译： 公开了一种多步骤方法，用于从通过石油残渣的高温热裂解得到的低于液体燃料值石油馏分的C8至C24直链烯烃组分制造合成润滑剂。 这些进料含有主要量的1-正烯烃，正链烷烃和大于0.1％浓度的硫，主要是形成芳族噻吩型硫化合物。 在本方法的第一步中，这些进料通过一个或多个分离方法富含直链脂族烃组分，优选通过尿素内收或通过结晶富集。 在第二步中，优选在BF 3配位催化剂的存在下将烯烃组分低聚成含有C 30至C 60的聚烯烃。 在第三步中，在耐硫催化剂，优选过渡金属硫化物的存在下，将聚烯烃氢化成新的异链烷烃润滑剂。
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公开(公告)号：US5481054A
公开(公告)日：1996-01-02
申请号：US398637
申请日：1995-03-03
申请人： Tze-Chiang Chung , Frank J. Chen , Jon E. Stanat , Alok Kumar
发明人： Tze-Chiang Chung , Frank J. Chen , Jon E. Stanat , Alok Kumar
CPC分类号： C08F10/00
摘要： Immobilized Lewis Acid catalyst comprising polymer having at least one Lewis Acid immobilized within the structure therein, said polymer having monomer units represented by the structural formula:--[A].sub.a --[B].sub.b --[C].sub.c --whereina represents about 1 to about 99 mole %b represents about 0 to about 50 mole %c represents about 1 to about 99 mole %a+b+c is preferably about 100%; ##STR1## C is selected from the group consisting of: ##STR2## (III) combinations thereof, wherein D is OH, halide, OR.sup.4, NH.sub.2, NHR.sup.3, OM', or OM";E is the residue of the reaction of at least one Lewis Acid with the D substituent of monomer unit B;R.sup.1 represents proton, C.sub.1 -C.sub.24 alkyl group, or C.sub.3 -C.sub.24 cycloalkyl;R.sup.2 represents C.sub.1 -C.sub.24 alkylene group, C.sub.3 -C.sub.24 cycloalkylene, C.sub.6 -C.sub.18 arylene, or C.sub.7 -C.sub.30 alkylarylene;R.sup.3 represents C.sub.1 -C.sub.24 alkyl, C.sub.3 -C.sub.24 cycloalkyl, C.sub.1 -C.sub.24 aryl, or C.sub.7 -C.sub.30 alkylaryl;R.sup.4 represents C.sub.1 -C.sub.24 alkyl, C.sub.3 -C.sub.24 cycloalkyl, C.sub.1 -C.sub.24 aryl, or C.sub.7 -C.sub.30 alkylaryl;M' represents alkali metal;M" represents alkaline-earth metal.Also disclosed are polymerization and alkylation processes utilizing the immobilized Lewis Acid catalysts. Another aspect of the present invention is a method of manufacturing immobilized Lewis Acid catalysts.
摘要翻译： 固定化路易斯酸催化剂，其包含具有固定在其结构内的至少一种路易斯酸的聚合物，所述聚合物具有由以下结构式表示的单体单元： - [A] a- [B] b- [C] c-，其中a表示约1 至约99摩尔％b表示约0至约50摩尔％c表示约1至约99摩尔％a + b + c优选约100％; 其中D是OH，卤化物，OR4，NH2，NHR3，OM'或其组合的组合。 OM“ E是至少一种路易斯酸与单体单元B的D取代基反应的残基; R1表示质子，C1-C24烷基或C3-C24环烷基; R2表示C1-C24亚烷基，C3-C24亚环烷基，C6-C18亚芳基或C7-C30烷基亚芳基; R3表示C1-C24烷基，C3-C24环烷基，C1-C24芳基或C7-C30烷基芳基; R4表示C1-C24烷基，C3-C24环烷基，C1-C24芳基或C7-C30烷基芳基; M'表示碱金属; M“表示碱土金属。 还公开了利用固定化的路易斯酸催化剂的聚合和烷基化方法。 本发明的另一方面是制备固定化的路易斯酸催化剂的方法。
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公开(公告)号：US4935576A
公开(公告)日：1990-06-19
申请号：US276135
申请日：1988-11-25
申请人： Frank J. Chen
发明人： Frank J. Chen
IPC分类号： B01J31/14 , C07B61/00 , C07C2/30 , C07C11/02 , C08F4/42 , C08F4/54 , C08F10/00 , C08F10/08 , C08F110/08
CPC分类号： C08F110/08
摘要： Polybutene is prepared from a mixed C.sub.4 hydrocarbon feedstream using an organo-aluminum/HCl catalyst system wherein the HCl is introduced separately into the feedstream to form organochloride in the feedstream. Polybutene product having a very narrow molecular weight distribution is obtained over the M.sub.n range of 700 to 3,000. Dispersants derived from this polybutene exhibit substantially improved performance in lubricating oil compositions.
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