Optical data storage medium having organometallic chromophore/polymer
coordinated information layer
    4.
    发明授权
    Optical data storage medium having organometallic chromophore/polymer coordinated information layer 失效
    具有有机金属发色团/聚合物协调信息层的光学数据存储介质

    公开(公告)号:US4605607A

    公开(公告)日:1986-08-12

    申请号:US720633

    申请日:1985-04-08

    摘要: Provided is an optical data storage medium comprising a chromophore/polymer composition information layer, wherein the chromophore is chemically bound or coordinated with the polymer. The chromophore is an organo macrocyclic chromophore containing a constituent metal atom, and preferably a central metal atom, with the chromophore being coordinated to the polymer through the metal atom. As a result, the chromophore/polymer material has excellent film-forming properties so that the medium can be readily and efficiently manufactured. As well, the resulting information layer offers excellent thermomechanical properties and exhibits excellent absorption properties, all in a single component material. By utilizing a single component material, the problem of dye/polymer phase separation frequently encountered in conventional dye/polymer mixtures is also overcome.

    摘要翻译: 提供了包含发色团/聚合物组合物信息层的光学数据存储介质,其中发色团与聚合物化学结合或配位。 发色团是含有组成金属原子的有机大环发色团,优选中心金属原子,发色团通过金属原子与聚合物配位。 结果,发色团/聚合物材料具有优异的成膜性能,因此可以容易且有效地制造介质。 同样,所得到的信息层提供优异的热机械性能并且显示出优异的吸收性能,全部在单一组分材料中。 通过使用单一组分材料,也克服了常规染料/聚合物混合物中经常遇到的染料/聚合物相分离的问题。

    High temperature, high humidity stabilization process for optical
information storage media containing polycarbonate substrates
    6.
    发明授权
    High temperature, high humidity stabilization process for optical information storage media containing polycarbonate substrates 失效
    含有聚碳酸酯基材的光信息存储介质的高温,高湿度稳定过程

    公开(公告)号:US5096742A

    公开(公告)日:1992-03-17

    申请号:US462257

    申请日:1990-01-09

    IPC分类号: G11B7/26

    CPC分类号: G11B7/26

    摘要: Provided is a method for stabilizing an optical recording medium containing a polycarbonate substrate. The method comprises treating the substrate material in a high temperature, high humidity environment for an extended period of time. Dramatic improvements in the useful life of the optical recording medium in which the treated polycarbonate substrate is used have been found to result.

    摘要翻译: 提供一种稳定含有聚碳酸酯基板的光记录介质的方法。 该方法包括在高温高湿环境下长时间处理基材。 已经发现使用经处理的聚碳酸酯基板的光记录介质的使用寿命的显着改善。

    Process for coating a polycarbonate or polymethylmethacrylate containing
base
    7.
    发明授权
    Process for coating a polycarbonate or polymethylmethacrylate containing base 失效
    用于涂覆聚碳酸酯或含聚甲基丙烯酸甲酯基质的方法

    公开(公告)号:US4997744A

    公开(公告)日:1991-03-05

    申请号:US287012

    申请日:1988-12-21

    摘要: Provided is a process and solvent solution for coating an aza-annulene chromophore containing film directly onto a polycarbonate or polymethylmethacrylate comprising base. In the process, a solution of the chromophore, e.g., phthalocyanine, porphyrin or naphthalocynine, is cast directly onto the polycarbonate or polymethylmethacrylate base, with the solvent used in formulating the solution comprising a C.sub.5 -C.sub.7 cyclic alcohol, or a mixture of solvents including at least one of the aforementioned alcohols. The solvent is then removed, preferably by evaporation, in order to yield a smooth, homogeneous chromophore containing film directly on the polycarbonate or polymethylmethacrylate comprising base. This process is particularly applicable to the manufacture of optical recording media as the particular solvents employed in the process exhibit surprising and unique solvency characteristics with respect to aza-annulene chromophores, and do not attack polycarbonate or polymethylmethacrylate containing bases. The process therefore offers the advantage of being able to manufacture a medium employing a polycarbonate or polymethylmethacrylate substrate without the need for a subbing layer.

    Media for optical information storage comprising an organic macrocyclic
chromophore substituted with a film conferring organic substituent
    8.
    发明授权
    Media for optical information storage comprising an organic macrocyclic chromophore substituted with a film conferring organic substituent 失效
    用于光学信息存储的介质,其包含被赋予有机取代基的膜取代的有机大环发色团

    公开(公告)号:US5059510A

    公开(公告)日:1991-10-22

    申请号:US396962

    申请日:1989-08-22

    摘要: Provided is an information recording medium, e.g., an optical recording medium, and a method for recording information thereon. The information layer of the recording medium comprises an organo macrocyclic chromophore containing a central hetero atom or two central hydrogen atoms or isotopes of hydrogen, e.g., a naphthalocyanine having silicon as the hetero atom, which chromophore is substituted with at least one substituent conferring film forming properties to the chromophore, e.g., a monomer or oligomeric substituent comprised of acid, amide or ester units. The information layer thereby offers excellent thermomechanical properties and exhibits excellent absorption properties all in a single component material. By utilizing a single component material, the problem of dye/polymer phase separation frequently encountered in dye/polymer mixtures is also overcome.

    摘要翻译: 提供了一种信息记录介质,例如光记录介质,以及用于在其上记录信息的方法。 记录介质的信息层包含含有中心杂原子或两个中心氢原子或氢的同位素的有机大环发色团,例如具有硅作为杂原子的萘酞菁,该发色团被至少一个赋予成膜的取代基的取代基 发色团的性质,例如由酸,酰胺或酯单元组成的单体或低聚取代基。 信息层由此提供优异的热机械性能,并且在单一成分材料中均显示出优异的吸收性能。 通过使用单一组分材料,也克服了在染料/聚合物混合物中经常遇到的染料/聚合物相分离的问题。

    Storage of optical information using photochiroptical effect
    9.
    发明授权
    Storage of optical information using photochiroptical effect 失效
    光学信息存储使用光电效应

    公开(公告)号:US5011756A

    公开(公告)日:1991-04-30

    申请号:US486031

    申请日:1990-02-27

    申请人: David E. Nikles

    发明人: David E. Nikles

    摘要: Provided is an optical information medium which permits the reading and writing of optical information by actively using polarized light. The optical information medium comprises an information layer containing a compound which undergoes a change upon irradiation with circularly polarized light to provide a new product which is optically active, and which is distinguishable from the original compound in its interaction with polarized light. In a preferred embodiment, the optical medium comprises optical isomers which can be selectively photolyzed by circularly polarized light. While writing must be done using a circularly polarized light source, reading of the recorded information can be accomplished using either circularly polarized light or linearly polarized light.

    摘要翻译: 提供了通过主动使用偏振光来允许读取和写入光学信息的光学信息介质。 光学信息介质包括信息层,该信息层包含在用圆偏振光照射时经历变化的化合物,以提供光学活性的新产物,并且其与偏振光的相互作用与原始化合物区分开。 在优选的实施方案中,光学介质包括光学异构体,其可以通过圆偏振光选择性地光解。 在使用圆偏振光源进行写入时,可以使用圆偏振光或线偏振光来读取记录信息。