公开(公告)号：US20110146859A1

公开(公告)日：2011-06-23

申请号：US12643242

申请日：2009-12-21

申请人： Frank Schmitz ,  Georges Marcel Victor Thielen ,  Nicola Costantini ,  Giorgio Agostini ,  Isabelle Lea Louise Marie Lambert ,  Richard Michael D'Sidocky ,  Larry Ashley Gordon ,  Xiaoping Yang ,  Bruce Raymond Hahn ,  Rebecca Lee Dando ,  John Eugene Varner ,  Leslie Allen Haller

发明人： Frank Schmitz ,  Georges Marcel Victor Thielen ,  Nicola Costantini ,  Giorgio Agostini ,  Isabelle Lea Louise Marie Lambert ,  Richard Michael D'Sidocky ,  Larry Ashley Gordon ,  Xiaoping Yang ,  Bruce Raymond Hahn ,  Rebecca Lee Dando ,  John Eugene Varner ,  Leslie Allen Haller

IPC分类号： B60C19/08 ,  H01B1/24

CPC分类号： B60C1/0016 ,  B60C19/08 ,  C08K3/04 ,  C08K3/041 ,  C08K2201/011 ,  C08L7/00 ,  C08L9/00

摘要： The present invention is directed to a method of conducting static electricity in a pneumatic tire, comprising the steps of mixing a rubber compound comprising at least one diene based rubber, from 60 to 150 phr of precipitated silica, less than 40 phr of carbon black, and from 1 to 10 phr of carbon nanotubes having a length of at least 5 microns; forming a tire tread from the rubber compound; and including the tire tread in the tire; wherein the volume resistivity of the tire tread is less than 1×109 ohm-cm as measured by ASTM D257-98.

摘要翻译： 本发明涉及一种在充气轮胎中进行静电的方法，包括以下步骤：将包含至少一种二烯基橡胶的橡胶混合物，60至150phr的沉淀二氧化硅，少于40phr的炭黑， 和1至10phr长度至少为5微米的碳纳米管; 从橡胶组合物形成轮胎胎面; 并将轮胎胎面包括在轮胎中; 其中根据ASTM D257-98测量，轮胎胎面的体积电阻率小于1×109ohm-cm。

公开(公告)号：US20110275751A1

公开(公告)日：2011-11-10

申请号：US13117475

申请日：2011-05-27

申请人： Nicola Costantini ,  Georges Marcel Victor Thielen ,  Frank Schmitz ,  Jerome Joel Daniel Delville ,  Christian Jean-Marie Kaes

发明人： Nicola Costantini ,  Georges Marcel Victor Thielen ,  Frank Schmitz ,  Jerome Joel Daniel Delville ,  Christian Jean-Marie Kaes

IPC分类号： C08K3/22

CPC分类号： B60C1/0016 ,  C08K3/011 ,  C08K3/22 ,  C08K5/0025 ,  C08K5/39 ,  C08K5/40 ,  C08K5/44 ,  C08L9/06 ,  C08L2666/08

摘要： The present invention is directed to a pneumatic tire comprising a ground contacting tread, the tread comprising a rubber composition comprising a solution polymerized styrene-butadiene rubber having a bound styrene content of at least 36 percent by weight and a vinyl 1,2 content of less than 25 percent by weight; optionally, at least one additional diene based rubber; silica; a sulfur donor; a sulfenamide accelerator; at least one secondary accelerator selected from the group consisting of guanidines, dithiocarbamates and thiurams; and an α,ω-bis(N,N′-dihydrocarbylthiocarbamamoyldithio)alkane; wherein the zinc content of the rubber composition is less than 0.5 parts by weight, per 100 parts by weight of elastomer (phr) as Zn metal.

摘要翻译： 本发明涉及一种充气轮胎，其包括接地胎面，所述胎面包含橡胶组合物，所述橡胶组合物包含具有至少36重量％的结合苯乙烯含量的溶液聚合的丁苯橡胶和乙烯基1,2含量少 超过25％; 任选地，至少一种另外的二烯基橡胶; 二氧化硅 硫供体; 亚磺酰胺促进剂; 选自鸟苷，二硫代氨基甲酸盐和秋兰姆的至少一种二级促进剂; 和α，ω-双（N，N'-二烃基硫代氨基甲酰基二硫代）烷烃; 其中，相对于Zn金属100重量份的弹性体（phr），橡胶组合物的锌含量小于0.5重量份。

公开(公告)号：US20140336330A1

公开(公告)日：2014-11-13

申请号：US13892578

申请日：2013-05-13

申请人： Nicola Costantini ,  Georges Marcel Victor Thielen ,  Frank Schmitz ,  Jerome Joel Daniel Delville ,  Christian Jean-Marie Kaes

发明人： Nicola Costantini ,  Georges Marcel Victor Thielen ,  Frank Schmitz ,  Jerome Joel Daniel Delville ,  Christian Jean-Marie Kaes

IPC分类号： C08L9/06

CPC分类号： B60C1/0016 ,  C08K3/36 ,  C08L9/00 ,  C08L9/06 ,  C08L2205/02 ,  C08L2205/03

摘要： The present invention is directed to a pneumatic tire comprising a ground contacting tread, the tread comprising a rubber composition comprising a solution polymerized styrene-butadiene rubber having a bound styrene content of at least 36 percent by weight and a vinyl 1,2 content of less than 25 percent by weight; optionally, at least one additional diene based rubber; silica; a sulfur donor; a sulfenamide accelerator; at least one secondary accelerator selected from the group consisting of guanidines, dithiocarbamates and thiurams; and an α,ω-bis(N,N′-dihydrocarbylthiocarbamamoyldithio)alkane; wherein the zinc content of the rubber composition is less than 0.5 parts by weight, per 100 parts by weight of elastomer (phr) as Zn metal.

摘要翻译： 本发明涉及一种充气轮胎，其包括接地胎面，所述胎面包含橡胶组合物，所述橡胶组合物包含具有至少36重量％的结合苯乙烯含量的溶液聚合的丁苯橡胶和乙烯基1,2含量少 超过25％; 任选地，至少一种另外的二烯基橡胶; 二氧化硅 硫供体; 亚磺酰胺促进剂; 选自鸟苷，二硫代氨基甲酸盐和秋兰姆的至少一种二级促进剂; 和α，ω-双（N，N'-二烃基硫代氨基甲酰基二硫代）烷烃; 其中，相对于Zn金属100重量份的弹性体（phr），橡胶组合物的锌含量小于0.5重量份。

公开(公告)号：US20100144946A1

公开(公告)日：2010-06-10

申请号：US12328212

申请日：2008-12-04

申请人： Nicola Costantini ,  Georges Marcel Victor Thielen ,  Frank Schmitz

发明人： Nicola Costantini ,  Georges Marcel Victor Thielen ,  Frank Schmitz

IPC分类号： C08K3/22 ,  B60C1/00

CPC分类号： C08K3/22 ,  B60C1/0016 ,  C08K3/011 ,  C08K5/0025 ,  C08K5/39 ,  C08K5/40 ,  C08K5/44 ,  C08L9/06 ,  C08L2666/08

摘要： The present invention is directed to a pneumatic tire comprising a ground contacting tread, the tread comprising a rubber composition comprising a solution polymerized styrene-butadiene rubber having a bound styrene content of at least 36 percent by weight and a vinyl 1,2 content of less than 25 percent by weight; optionally, at least one additional diene based rubber; silica; a sulfur donor; a sulfenamide accelerator; at least one secondary accelerator selected from the group consisting of guanidines, dithiocarbamates and thiurams; and an α,ω-bis(N,N′-dihydrocarbylthiocarbamamoyldithio)alkane; wherein the zinc content of the rubber composition is less than 0.5 parts by weight, per 100 parts by weight of elastomer (phr) as Zn metal.

摘要翻译： 本发明涉及一种充气轮胎，其包括接地胎面，所述胎面包含橡胶组合物，所述橡胶组合物包含具有至少36重量％的结合苯乙烯含量的溶液聚合的丁苯橡胶和乙烯基1,2含量少 超过25％; 任选地，至少一种另外的二烯基橡胶; 二氧化硅 硫供体; 亚磺酰胺促进剂; 选自鸟苷，二硫代氨基甲酸盐和秋兰姆的至少一种二级促进剂; 和α，ω-双（N，N'-二烃基硫代氨基甲酰基二硫代）烷烃; 其中，相对于Zn金属100重量份的弹性体（phr），橡胶组合物的锌含量小于0.5重量份。

公开(公告)号：US20110120606A1

公开(公告)日：2011-05-26

申请号：US12624945

申请日：2009-11-24

申请人： Nicola Costantini ,  Georges Marcel Victor Thielen ,  Frank Schmitz ,  Maurice Peter Klinkenberg ,  Kenneth Allen Bates ,  Fernand Antoine Joseph Fourgon

发明人： Nicola Costantini ,  Georges Marcel Victor Thielen ,  Frank Schmitz ,  Maurice Peter Klinkenberg ,  Kenneth Allen Bates ,  Fernand Antoine Joseph Fourgon

IPC分类号： B60C1/00

CPC分类号： C08L15/00 ,  C08C19/44 ,  C08K3/013 ,  C08K3/36 ,  C08L9/00 ,  C08L2666/08 ,  C08L19/006

摘要： The present invention is directed to a pneumatic tire comprising a ground contacting tread, the tread comprising a rubber composition comprising from about 60 to about 90 phr of a functionalized solution polymerized styrene-butadiene rubber having a bound styrene content of at least 36 percent by weight, a vinyl 1,2 content of less than 25 percent by weight, and functionalized with an alkoxysilane group and a thiol group; from about 40 to about 10 phr of a high-cis polybutadiene; and from about 50 to about 150 phr of silica.

摘要翻译： 本发明涉及一种包括接地胎面的充气轮胎，胎面包含橡胶组合物，该橡胶组合物包含约60至约90phr的具有至少36重量％的结合苯乙烯含量的聚合苯乙烯 - 丁二烯橡胶的官能化溶液 ，乙烯基1,2-含量小于25重量％，并用烷氧基硅烷基和硫醇基官能化; 约40至约10phr的高顺式聚丁二烯; 和约50至约150phr的二氧化硅。

公开(公告)号：US07671132B1

公开(公告)日：2010-03-02

申请号：US12336773

申请日：2008-12-17

申请人： Georges Marcel Victor Thielen ,  Frank Schmitz ,  Nicola Costantini

发明人： Georges Marcel Victor Thielen ,  Frank Schmitz ,  Nicola Costantini

IPC分类号： C08L23/04 ,  C08L25/10

CPC分类号： C08L9/00 ,  B60C1/0016 ,  C08L9/06 ,  C08L23/02 ,  C08L25/06 ,  C08L25/16 ,  C08L2666/02

摘要： The present invention is directed to a pneumatic tire comprising a ground contacting tread, the tread comprising a rubber composition comprising from 30 to 70 parts by weight, per 100 parts by weight of s first elastomer (phr) having a glass transition temperature Tg ranging from about −40° C. to about −10° C. and a solubility parameter ranging from about 4.1 MPa1/2 to about 4.5 MPa1/2; from 70 to 30 phr of a second elastomer having a Tg ranging from about −105° C. to about −30° C. and a solubility parameter ranging from about 3.7 MPa1/2 to about 4.1 MPa1/2; from 1 to 40 phr of a first plasticizer having a solubility parameter ranging from 3.4 MPa1/2 to 3.8 MPa1/2; from 1 to 20 phr of a second plasticizer having a solubility parameter ranging from 4.3 MPa1/2 to 4.7 MPa1/2; and from 30 to 150 phr of silica.

摘要翻译： 本发明涉及一种充气轮胎，其包括接地胎面，所述胎面包含橡胶组合物，所述橡胶组合物包含30至70重量份，相对于每100重量份的第一弹性体（phr），其玻璃化转变温度Tg范围为 约-40℃至约-10℃，溶解度参数为约4.1MPa1 / 2至约4.5MPa1 / 2; 70至30phr的Tg范围为约-105℃至约-30℃的第二弹性体，溶解度参数为约3.7MPa 1/2至约4.1MPa 1/2; 1〜40phr的溶解度参数为3.4MPa·2〜3.8MPa·1/2的第一增塑剂; 1至20phr的溶解度参数范围为4.3MPa1 / 2至4.7MPa1 / 2的第二增塑剂; 和30至150phr的二氧化硅。

公开(公告)号：US20120083559A1

公开(公告)日：2012-04-05

申请号：US12894295

申请日：2010-09-30

申请人： Nicola Costantini

发明人： Nicola Costantini

IPC分类号： C08K5/5398

CPC分类号： C08K5/5398 ,  B60C1/0016 ,  C08K5/0025 ,  C08K5/44 ,  C08L21/00 ,  C08L2666/08

摘要： The present invention is directed to a pneumatic tire comprising a ground contacting tread, the tread comprising a rubber composition comprising at least one additional diene based rubber; silica; a sulfur donor; a sulfenamide accelerator; and a dithiophosphate of the formula wherein Q is divalent Zn or S, and R3 may be identical or different, and R3 is hydrogen or a monovalent hydrocarbon group of 1 to 18 carbon atoms; wherein the zinc content of the rubber composition is less than 0.5 parts by weight, per 100 parts by weight of elastomer (phr) as Zn meta.

摘要翻译： 本发明涉及一种充气轮胎，其包括接地胎面，所述胎面包括橡胶组合物，所述橡胶组合物包含至少一种另外的二烯基橡胶; 二氧化硅 硫供体; 亚磺酰胺促进剂; 和下式的二硫代磷酸酯，其中Q是二价的Zn或S，R3可以相同或不同，R3是氢或1至18个碳原子的一价烃基; 其中，相对于每100重量份作为Zn元素的弹性体（phr），橡胶组合物的锌含量小于0.5重量份。