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    Thermoplastic moulding compositions
    1.
    发明授权
    Thermoplastic moulding compositions 失效
    热塑性成型组合物

    公开(公告)号：US4937286A

    公开(公告)日：1990-06-26

    申请号：US107155

    申请日：1987-10-13

    申请人： Frank Wingler ,  Klaus Summermann ,  Ulrich Jansen ,  Joachim Doring ,  Alfred Pischtschan

    发明人： Frank Wingler ,  Klaus Summermann ,  Ulrich Jansen ,  Joachim Doring ,  Alfred Pischtschan

    IPC分类号： C08L25/08 ,  C08L25/16 ,  C08L35/06 ,  C08L51/00 ,  C08L51/04

    CPC分类号： C08L25/16 ,  C08L35/06 ,  C08L51/04

    摘要： Thermoplastic moulding compositions ofA. 90 to 30 parts by weight of a copolymer prepared by solution or bulk polymerization of a.sub.1 30 to 45% by weight of .alpha.-methylstyrene, a.sub.2 26 to 35% by weight of acrylonitrile and a.sub.3 44 to 20% by weight of styrene and/or p-methylstyrene, and with a content of incorporated acrylonitrile of 27-30% by weight,B. 5 to 60 parts by weight of a random copolymer of b.sub.1 18 to 24% by weight of maleic anhydride and b.sub.2 82 to 76% by weight of styrene and/or p-methylstyrene andC. 5 to 40 parts by weight of a graft polymer of 70 to 30% by weight of a mixture of c.sub.1 a vinylaromatic and/or C.sub.1 -C.sub.4 -alkyl and c.sub.2 acrylonitrile, on 30 to 70% by weight of a rubber with a glass transistion temperature of less than -10.degree. C.

    摘要翻译： A.热塑性成型组合物：90〜30重量份通过a1〜30〜45重量％的α-甲基苯乙烯的溶液或本体聚合制备的共聚物，a2-26〜35重量％的丙烯腈和a3〜44〜20重量％ 苯乙烯和/或对甲基苯乙烯的重量，并且所加入的丙烯腈的含量为27-30重量％，B。5至60重量份的b1 18至24重量％的马来酸酐和b2的无规共聚物 82至76重量％的苯乙烯和/或对甲基苯乙烯和C 5-40重量份的接枝聚合物，70至30重量％的c1乙烯基芳族化合物和/或C 1 -C 4烷基的混合物和 丙烯腈，30〜70重量％的玻璃化转变温度低于-10℃的橡胶。

    Process for the continuous coagulation of vinyl polymer latices
    2.
    发明授权
    Process for the continuous coagulation of vinyl polymer latices 失效
    乙烯基聚合物胶乳的连续凝结方法

    公开(公告)号：US5314990A

    公开(公告)日：1994-05-24

    申请号：US692496

    申请日：1991-04-29

    申请人： Ulrich Jansen ,  Karl-Heinz Ott ,  Wolfgang Herrig ,  Otto Koch ,  Alfred Pischtschan ,  Dieter Wittmann

    发明人： Ulrich Jansen ,  Karl-Heinz Ott ,  Wolfgang Herrig ,  Otto Koch ,  Alfred Pischtschan ,  Dieter Wittmann

    IPC分类号： C08J3/16 ,  C08F6/22 ,  C08F6/16

    CPC分类号： C08F6/22

    摘要： A process for the continuous processing of vinyl polymer latices to produce thermoplastically processible vinyl polymer powder by coagulating a stream of a vinyl polymer latex by the addition of a stream of a coagulant with intensive mixing and shearing in a cascade of vessels at an average residence time per vessel of 10 to 60 minutes and at temperatures from 50 to 120.degree. C., volatile auxiliary substances and residual monomers in the polymer being optionally removed by steam distillation and part of the serum separated from the vinyl polymer being added to the stream of coagulant.

    摘要翻译： 一种连续处理乙烯基聚合物胶乳以通过凝结乙烯基聚合物胶乳物流的方式连续处理乙烯基聚合物胶乳的方法，该方法是通过在凝结剂流中加入混合物并在平均停留时间的梯级下进行剪切 每个容器10至60分钟，温度为50至120℃，通过蒸汽蒸馏任选除去聚合物中的挥发性辅助物质和残留单体，并将部分从乙烯基聚合物中分离的血清加入到凝结剂流中 。

    ABS moulding material with improved workability and a high lustre
    5.
    发明授权
    ABS moulding material with improved workability and a high lustre 失效
    ABS成型材料具有改善的加工性和高光泽

    公开(公告)号：US07074854B2

    公开(公告)日：2006-07-11

    申请号：US10204137

    申请日：2001-02-12

    申请人： Herbert Eichenauer ,  Eckhard Wenz ,  Heinrich Alberts ,  Ulrich Jansen ,  Hans-Erich Gasche

    发明人： Herbert Eichenauer ,  Eckhard Wenz ,  Heinrich Alberts ,  Ulrich Jansen ,  Hans-Erich Gasche

    IPC分类号： C08L51/04

    CPC分类号： C08L51/04 ,  C08F279/02 ,  C08F279/04 ,  C08L25/12 ,  C08L55/02 ,  C08L67/00 ,  C08L69/00 ,  C08L77/00 ,  C08L2666/02 ,  C08L2666/24 ,  C08L2666/14 ,  C08L2666/04

    摘要： A Polymer compositions that features high degree of toughness, very good processability and extremely high gloss is disclosed. The composition contains (I) a graft rubber polymer obtained by emulsion polymerization of styrene and acrylonitrile in the presence of a mixture of (A) a butadiene polymer latex having a mean particle diameter d50≦250 nm, a particle size distribution width of 20 to 80 nm and a gel content of 30 to 95 wt. %, (B) a butadiene polymer latex with a mean particle diameter d50>250 to 350 nm, a particle size distribution width of 30 to 100 nm and gel content of 30 to 80 wt. %, and (C) a butadiene polymer latex (C) with a mean particle diameter d50>350 nm, a particle size distribution width of 40 to 150 nm, and a gel content of 50 to 95 wt. %. and (II) a rubber-free copolymer of styrene and acrylonitrile. At least one of (A), (B) and (C) is a product of seed polymerization.

    摘要翻译： 公开了具有高韧性，非常好的加工性和极高光泽度的聚合物组合物。 该组合物含有（I）通过苯乙烯和丙烯腈的乳液聚合得到的接枝橡胶聚合物，该混合物是（A）平均粒径d <50％= 250nm的丁二烯聚合物胶乳 ，粒径分布宽度为20〜80nm，凝胶含量为30〜95wt。 ％，（B）平均粒径d <50> 250〜350nm，粒径分布宽度为30〜100nm，凝胶含量为30〜80重量％的丁二烯聚合物胶乳。 ％，和（C）平均粒径d <50 <350纳米，粒度分布宽度为40〜150nm，凝胶含量为50〜95的丁二烯聚合物胶乳（C） 重量 ％。 和（II）苯乙烯和丙烯腈的无橡胶共聚物。 （A），（B）和（C）中的至少一种是种子聚合的产物。

    Polymer compositions with an improved constancy of characteristics
    6.
    发明授权
    Polymer compositions with an improved constancy of characteristics 有权
    具有改善的特性恒定性的聚合物组合物

    公开(公告)号：US06767964B2

    公开(公告)日：2004-07-27

    申请号：US10204147

    申请日：2002-08-16

    申请人： Herbert Eichenauer ,  Adolf Schmidt ,  Ulrich Jansen

    发明人： Herbert Eichenauer ,  Adolf Schmidt ,  Ulrich Jansen

    IPC分类号： C08G6348

    CPC分类号： C08L51/04 ,  C08F279/04 ,  C08L25/12 ,  C08L55/02 ,  C08L2205/02 ,  C08L2666/24 ,  C08L2666/02

    摘要： A thermoplastic molding composition that features constancy of properties, especially toughness and processability is disclosed. The composition contains a first graft rubber polymer that is a product of emulsion polymerisation of styrene and acrylonitrile in the presence of a butadiene polymer latex (A) with a mean particle diameter d50 of 80 to 220 nm, a second graft rubber polymer obtained by emulsion polymerisation of styrene and acrylonitrile in the presence of a butadiene polymer latex (B) with a mean particle diameter d50 of 340 to 480 nm, and a rubber-free copolymer of styrene and acrylonitrile. Importantly, the butadiene polymer latex (A) is the product of seed polymerization using a seed latex with a mean particle diameter of 10 to 100 nm, and the butadiene polymer latex (B) is the product of seed polymerisation using the butadiene polymer latex (A) as seed latex.

    Thermoplastic molding materials based on special graft rubber components
    8.
    发明授权
    Thermoplastic molding materials based on special graft rubber components 失效
    基于特殊接枝橡胶成分的热塑性成型材料

    公开(公告)号：US06828380B2

    公开(公告)日：2004-12-07

    申请号：US10220707

    申请日：2002-11-21

    申请人： Liqing-Lee Sun ,  Eckhard Wenz ,  Herbert Eichenauer ,  Stefan Moss ,  Heinrich Alberts ,  Hans-Bernhard Hauertmann ,  Karl Zabrocki ,  Hans-Erich Gasche ,  Ulrich Jansen

    发明人： Liqing-Lee Sun ,  Eckhard Wenz ,  Herbert Eichenauer ,  Stefan Moss ,  Heinrich Alberts ,  Hans-Bernhard Hauertmann ,  Karl Zabrocki ,  Hans-Erich Gasche ,  Ulrich Jansen

    IPC分类号： C08L5502

    CPC分类号： C08L51/04 ,  C08F279/02 ,  C08F279/04 ,  C08L55/02 ,  C08L2666/14 ,  C08L2666/02

    摘要： A molding composition having good surface gloss, high elongation at break and good thermoplastic processability is disclosed. The composition contains (A) a graft polymer that is obtained by free-radical polymerization of resin-forming vinyl monomers in the presence of rubber in latex form, (B) a copolymer of styrene and acrylonitrile and an optional (C) a resin selected from the group consisting of polycarbonates, polyester-carbonates, polyesters and polyamides. The preparation of the graft polymer is characterized in that (i) before the start of the grafting polymerization reaction the rubber latex is brought to a pH of 9 to 11, (ii) the redox initiator components are employed in amounts of 0.1 to 2.5 wt. % (based on the monomers metered in) and (iii) during the entire grafting polymerization reaction the pH remains constant±0.5 and in the range of 11.0 to 8.8, and (iv) the temperature difference between the start and end of the reaction is at least 10° C.

    摘要翻译： 公开了具有良好的表面光泽度，高断裂伸长率和良好的热塑性加工性能的成型组合物。 该组合物含有（A）通过在胶乳形式的橡胶存在下形成树脂的乙烯基单体的自由基聚合获得的接枝聚合物，（B）苯乙烯和丙烯腈的共聚物和任选的（C）树脂选择 由聚碳酸酯，聚酯 - 碳酸酯，聚酯和聚酰胺组成。 接枝聚合物的制备的特征在于：（i）在接枝聚合反应开始之前，使橡胶胶乳的pH值达到9至11，（ii）氧化还原引发剂组分的用量为0.1至2.5重量％ 。 ％（基于计量的单体）和（iii）在整个接枝聚合反应期间，pH保持恒定±0.5且在11.0至8.8的范围内，和（iv）反应开始和结束之间的温度差为 至少10℃