公开(公告)号：US4436833A

公开(公告)日：1984-03-13

申请号：US478995

申请日：1983-03-25

申请人： Franz J. Broecker ,  Karl-Heinz Gruendler ,  Laszlo Marosi ,  Matthias Schwarzmann ,  Bruno Triebskorn ,  Guenter Zirker

发明人： Franz J. Broecker ,  Karl-Heinz Gruendler ,  Laszlo Marosi ,  Matthias Schwarzmann ,  Bruno Triebskorn ,  Guenter Zirker

IPC分类号： C07C29/15 ,  B01J23/00 ,  B01J23/80 ,  B01J27/20 ,  C07B61/00 ,  C07C27/00 ,  C07C29/154 ,  C07C31/04 ,  C07C67/00

CPC分类号： B01J27/20 ,  B01J23/80 ,  C07C29/154 ,  Y02P20/52

摘要： A process for the preparation of methanol by reacting a gaseous mixture of carbon monoxide, carbon dioxide and hydrogen at an elevated temperature and under superatmospheric pressure over a catalyst which contains zinc, copper and aluminum, the catalyst being prepared from a co-crystalline material of the formulaCu.sub.2.2 Zn.sub.2.8 (OH).sub.6 (CO.sub.3).sub.2,containing aluminum hydroxide as a structual promoter, by calcination and reduction at from 160.degree. to 350.degree. C. The novel catalyst has the advantage of giving a substantially increased space-time yield and having a longer life.

摘要翻译： 一种通过使一氧化碳，二氧化碳和氢气的气体混合物在升高的温度和超大气压下在含有锌，铜和铝的催化剂上反应制备甲醇的方法，该催化剂由共轭结晶材料 通过在160℃至350℃下煅烧和还原，得到含有氢氧化铝作为结构促进剂的式Cu2.2Zn2.8（OH）6（CO3）2。新型催化剂的优点在于， 时间收益并且寿命更长。

公开(公告)号：US3950368A

公开(公告)日：1976-04-13

申请号：US415416

申请日：1973-11-13

申请人： Franz Josef Broecker ,  Guenter Zirker ,  Bruno Triebskorn ,  Laszlo Marosi ,  Matthias Schwarzmann ,  Winfried Dethlefsen ,  Knut Kaempfer

发明人： Franz Josef Broecker ,  Guenter Zirker ,  Bruno Triebskorn ,  Laszlo Marosi ,  Matthias Schwarzmann ,  Winfried Dethlefsen ,  Knut Kaempfer

IPC分类号： C10G11/20 ,  B01J23/00 ,  B01J23/755 ,  C07B61/00 ,  C07C1/00 ,  C07C1/02 ,  C07C4/00 ,  C07C4/06 ,  C07C9/04 ,  C07C67/00 ,  C07C27/06

CPC分类号： C07C1/02 ,  B01J23/755 ,  C07C4/00 ,  C10G11/02 ,  C10G11/10 ,  C07C2527/236

摘要： A two-stage process for the manufacture of methane from hydrocarbons is described. In the first stage, the hydrocarbons are converted into methane-rich gases, using the nickel catalyst described below. The cracked gases thus obtained are cooled and converted into methane-rich gases in a further catalytic process stage, using a methanization catalyst or the nickel catalyst mentioned below. To produce the nickel catalyst, the compound Ni.sub.6 Al.sub.2 (OH).sub.16.CO.sub.3.4H.sub.2 O is prepared in aqueous solution. The catalyst is obtained from this compound by drying, calcination and subsequent reduction in a stream of hydrogen whilst maintaining very specific temperature gradients between the drying stage and the calcination stage.

公开(公告)号：US3941721A

公开(公告)日：1976-03-02

申请号：US415407

申请日：1973-11-13

申请人： Franz Josef Broecker ,  Guenter Zirker ,  Bruno Triebskorn ,  Laszlo Marosi ,  Matthias Schwarzmann ,  Winfried Dethlefsen ,  Knut Kaempfer

发明人： Franz Josef Broecker ,  Guenter Zirker ,  Bruno Triebskorn ,  Laszlo Marosi ,  Matthias Schwarzmann ,  Winfried Dethlefsen ,  Knut Kaempfer

IPC分类号： B01J23/755 ,  B01J37/08 ,  C07B61/00 ,  C07C1/00 ,  C07C4/00 ,  C07C4/06 ,  C07C9/04 ,  C07C67/00 ,  B01J21/04 ,  B01J23/74

CPC分类号： C07C4/06 ,  B01J23/755 ,  B01J37/08 ,  C07C4/00 ,  C10G11/02 ,  C07C2527/236

摘要： The compound Ni.sub.6 Al.sub.2 (OH).sub.16. CO.sub.3. 4H.sub.2 O is isolated from aqueous solution. The catalyst is obtained from this compound by drying, calcination and subsequent reduction in a stream of hydrogen, whilst maintaining very specific temperature gradients between the drying stage and the calcination stage. A process for the manufacture of gases containing methane from hydrocarbons by steam cracking, in which the abovementioned catalyst is employed, is also described.

摘要翻译： 化合物Ni6Al2（OH）16。 CO3。 4H2O与水溶液分离。 通过干燥，煅烧和随后在氢气流中还原从该化合物获得催化剂，同时在干燥阶段和煅烧阶段保持非常特定的温度梯度。 还描述了使用上述催化剂通过蒸汽裂化从烃制造含甲烷的气体的方法。

公开(公告)号：US4393251A

公开(公告)日：1983-07-12

申请号：US347380

申请日：1982-02-10

申请人： Franz J. Broecker ,  Leopold Hupfer ,  Franz Merger ,  Ernest Miesen ,  Juergen Paetsch ,  Guenter Zirker

发明人： Franz J. Broecker ,  Leopold Hupfer ,  Franz Merger ,  Ernest Miesen ,  Juergen Paetsch ,  Guenter Zirker

IPC分类号： B01J23/80 ,  C07C29/141 ,  C07C29/149 ,  C07C31/20 ,  C07C31/27 ,  C07C33/26 ,  C07C41/26

CPC分类号： B01J23/80 ,  C07C29/141 ,  C07C31/20 ,  C07C31/276 ,  C07C33/26 ,  C07C2101/14 ,  Y02P20/582

摘要： Hydrogenation catalysts which are prepared from mixed crystals of copper-zinc compounds, obtained by precipitation, of the formulaCu.sub.1.5-3 Zn.sub.1-2.5 (CO.sub.3).sub.1-2 (OH).sub.4-6.(H.sub.2 O).sub.0-1by decomposition at 200.degree.-500.degree. C., and are used for the catalytic preparation of propanediols of the formula ##STR1## where the R's may be identical or different and each is an aliphatic, araliphatic or aromatic radical, or the two R's together with the adjacent carbon atom are members of an alicyclic ring, by hydrogenating hydroxypropionaldehydes of the formula ##STR2## where R has the above meanings, and to processes for the preparation of propanediols, using such catalysts. The propane-1,3-diols obtainable by the novel process are valuable starting materials for the preparation of lubricants, plastics, surface coatings and synthetic resins, for example of polyesters derived from the propanediols.

摘要翻译： 由通过沉淀得到的铜 - 锌化合物的混合晶体制备的氢化催化剂，其通式为Cu1.5-3Zn1-2.5（CO3）1-2（OH）4-6。（H2O） 200℃-500℃，并用于催化制备式（I）的丙二醇，其中R可以相同或不同，并且各自为脂族，芳脂族或芳族基团，或两个R与 相邻的碳原子是脂环的成员，通过氢化具有上述含义的式II的羟基丙醛，以及使用这种催化剂制备丙二醇的方法。 通过新方法获得的丙烷-1,3-二醇是用于制备润滑剂，塑料，表面涂层和合成树脂的有价值的起始材料，例如衍生自丙二醇的聚酯。

公开(公告)号：US4849395A

公开(公告)日：1989-07-18

申请号：US167251

申请日：1988-03-11

申请人： Laszlo Marosi ,  Joachim Stabenow ,  Knut Eger ,  Matthias Irgang ,  Guenter Zirker

发明人： Laszlo Marosi ,  Joachim Stabenow ,  Knut Eger ,  Matthias Irgang ,  Guenter Zirker

IPC分类号： B01J23/72 ,  B01J37/30 ,  C01B33/20

CPC分类号： C01B33/20 ,  B01J23/72 ,  B01J37/30

摘要： Amorphous metal/magnesium silicates of the general formulaM.sub.x Mg.sub.y (SiO.sub.2).nH.sub.2 O.where M is a divalent, reducible metal atom from the group consisting of Cu, FeII, Co and Ni, x and y are numbers which together can add up to a value of 1.5 and n after drying, expressed in % by weight, ranges from 0 to 80 are prepared by subjecting a freshly precipitated magnesium silicate to an ion exchange, washing the product and then neutralizing it with an alkali and are used in catalytic reactions after the reducible metal in the metal/magnesium silicates has been converted into the metallic state with a reducing gas.

摘要翻译： 无定形金属/通式为MxMgy（SiO2）·nH2O的硅酸镁。 其中M是由Cu，FeII，Co和Ni组成的组中的二价可还原金属原子，x和y是数值，它们一起加起来的值为1.5，干燥后的n以重量％表示，范围为 通过将新鲜沉淀的硅酸镁进行离子交换，洗涤产物，然后用碱中和，制备0至80，并在金属/硅酸镁中的可还原金属转化为金属状态后用于催化反应 与还原气体。