摘要:
The thermoplastic, isocyanate-free polyurethane which contains acidic groups, is soluble in tetrahydrofuran, has a molecular weight of from 15,000 to 70,000 and is composed ofA) 1 mol of a polyol having a molecular weight of from 400 to 4000,B) from 0.3 to 9 mol of a mixture ofB1) if required, a diol of 2 to 18 carbon atoms andB2) from 0.03 to 0.4 mol of a diol having at least one acidic group,C) from 0 to 1 mol of a polyol having 3 to 18 carbon atoms and at least 3 OH groups,D) from 1.25 to 13 mol of a diisocyanate of 6 to 30 carbon atoms andE) from 0 to 1 mol of a primary or secondary amino alcohol of 2 to 16 carbon atoms,the molar ratio of the OH and any NH groups present in the sum of the components A, B, C and E to the NCO groups of component D being from 0.98 to 1.4, is obtainable by reacting the above components in the melt and is suitable in particular as a binder for magnetic recording media.
摘要:
A process for the preparation of thermoplastic polyurethane by reacting (a) isocyanates with (b) compounds reactive toward isocyanates and having a molecular weight (Mw) of from 500 to 10 000 g/mol and (c) chain extenders having a molecular weight of from 50 to 499 g/mol, if appropriate in the presence of (d) catalysts and/or (e) conventional additives, wherein the chain extender mixture consisting of a main chain extender (c1) and one or more co-chain extenders (c2) is used and the thermoplastic polyurethane prepared has a rigid phase fraction of greater than 0.40, the rigid phase fraction being defined by the following formula: rigid phase fraction = { ∑ x = 1 k [ ( m KVx / M KVx ) * M Iso + m KVx ] } / m ges with the following meanings: MKVx: molar mass of the chain extender x in g/mol mKVx: mass of the chain extender x in g MIso: molar mass of the isocyanate used in g/mol mges: total mass of all starting materials in g k: number of chain extenders.
摘要:
Process for continuous production of thermoplastically processable polyurethane elastomers with improved homogeneity, by metering a polyisocyanate (A), a proportion of from 1 to 80 equivalent %, based on the isocyanate group content of the polyisocyanate (A), of a compound (B) having an average of at least 1.8 and at most 3.0 hydrogen atoms having Zerewitinoff activity, with an average molar mass of from 450 g/mol to 5000 g/mol, a proportion of from 12 to 99 equivalent %, based on the isocyanate group content of the polyisocyanate (A), of a chain extender (C) having an average of at least 1.8 and at most 3.0 hydrogen atoms having Zerewitinoff activity per molecule, with an average molar mass of from 60 g/mol to 400 g/mol, from 0 to 30% by weight, based on the total amount of the polyurethane elastomer, of catalysts and further auxiliaries and additives (D), the molar NCO:OH ratio of polyisocyanate (A) to the entirety composed of the compound (B), of the chain extender (C), and of the further auxiliaries and additives (D) being from 0.9:1 to 1.2:1 into a self-cleaning twin-screw extruder which is operated at high shear rates, and then bringing the mixture from the self-cleaning twin-screw extruder into a further apparatus in order to complete the reaction, which comprises setting shear rates above 6000 s−1 and residence times in the range from 1 to 20 s in the self-cleaning twin-screw extruder.
摘要:
A composite element in the furniture sector, preferably furniture doors and furniture carcasses, comprises (i) laminated or unlaminated materials based on wood, wood boards or particle boards and/or wood-like materials, preferably based on wood boards or particle boards, and (ii) thermoplastic polyurethane. Processes for the production of these composite elements and in particular furniture carcasses or doors comprising the novel composite elements are furthermore described. In particular, film hinges, preferably for furniture construction, for example for furniture carcasses, drawers or door frames, in particular for furniture carcasses based on thermoplastic polyurethanes are described.
摘要:
Thermoplastic polyurethane (i) comprising from 20% by weight to 70% by weight of isocyanate dissolved in the thermoplastic polyurethane, based on the total weight of the thermoplastic polyurethane (i) comprising the isocyanates.