Optical elements based on liquid-crystalline substances with no
birefringence in a non-perpendicular direction and a process for their
preparation
    6.
    发明授权
    Optical elements based on liquid-crystalline substances with no birefringence in a non-perpendicular direction and a process for their preparation 失效
    基于在非垂直方向上没有双折射的液晶物质的光学元件及其制备方法

    公开(公告)号:US5359439A

    公开(公告)日:1994-10-25

    申请号:US11587

    申请日:1993-02-01

    摘要: The invention relates to optical elements based on liquid-crystalline substances, and to a process for the production thereof. The optical elements based on liquid-crystalline substances are ones which exhibit no birefringence in a defined direction of incidence, optical elements in which no birefringence occurs perpendicularly to the surface being excepted. The process for preparing the optical elements comprises illuminating a liquid-crystalline substance with unpolarized light of suitable wavelength at a defined angle in such a way that, after illumination, the director of this substance is aligned parallel to the direction of the illuminating light on passing through said substance.

    摘要翻译: 本发明涉及基于液晶物质的光学元件及其生产方法。 基于液晶物质的光学元件是在确定的入射方向上不显示双折射的光学元件,其中不存在垂直于表面的双折射的光学元件除外。 制备光学元件的方法包括用限定角度的合适波长的非偏振光照射液晶物质,使得在照射之后,该物质的导向体与经过的照明光的方向平行排列 通过所述物质。

    Dimethylsilyl-substituted benzoyl chlorides and a process for preparing
the same
    7.
    发明授权
    Dimethylsilyl-substituted benzoyl chlorides and a process for preparing the same 失效
    二甲基甲硅烷基取代的苯甲酰氯及其制备方法

    公开(公告)号:US4914221A

    公开(公告)日:1990-04-03

    申请号:US229188

    申请日:1988-08-08

    IPC分类号: C07F7/12 C07F7/08

    CPC分类号: C07F7/0896

    摘要: The invention relates to dimethylsilyl-substituted benzoyl chlorides and a process for preparing the same, which comprises reacting a dihaloaromatic compound with dimethylchlorosilane and magnesium by the Grignard method to form halophenyldimethylsilanes, then reacting the halophenyldimethylsilanes with magnesium in the presence of carbon dioxide to form the corresponding dimethylsilyl-substituted benzoic acids, and thereafter reacting the dimethylsilyl-substituted benzoic acids with a halogenating agent, such as thionyl chloride, to form dimethylsilyl-substituted benzoyl chlorides.

    摘要翻译: 本发明涉及二甲基甲硅烷基取代的苯甲酰氯及其制备方法,其包括通过格利雅法将二卤代芳族化合物与二甲基氯硅烷和镁反应形成卤代苯基二甲基硅烷,然后在二氧化碳存在下使卤代苯基二甲基硅烷与镁反应形成 然后使二甲基甲硅烷基取代的苯甲酸与卤化剂如亚硫酰氯反应,形成二甲基甲硅烷基取代的苯甲酰氯。

    Cyclosiloxanes containing mesogenic side groups
    10.
    发明授权
    Cyclosiloxanes containing mesogenic side groups 失效
    含有介晶侧基的环硅氧烷

    公开(公告)号:US5304667A

    公开(公告)日:1994-04-19

    申请号:US38312

    申请日:1993-03-29

    CPC分类号: C09K19/408 C07F7/21

    摘要: The present invention relates to cyclic siloxanes which have at least one group of formula (1) bonded to a silicon atom--(CH.sub.2).sub.x --R"--[--L--A--].sub.y --(L).sub.z --T (1),in which x is an integer having a value of at least 2, preferably having a value of from 2 to 10, R" is a chemical bond or a divalent radical of the formula --COO--, --OOC--, --CH.sub.2 --CH.sub.2 --, --CH.dbd.CH--, --C.tbd.C--, --N.dbd.N--, --N.dbd.N, --N.dbd.CH--, --CH.dbd.N or --Si(R).sub.2 --, where the radical R is identical or different and is an optionally substituted hydrocarbon radical having from 1 to 18 carbon atoms, L which is the same or different represents the 1,4-phenylene or 1,4-cyclohexylene radicals which are optionally 2-, 3-, 5- and/or 6-substituted by at least one radical Q, Q is the same or different radical selected from hydrogen, fluorine or chlorine atoms or cyano, methyl or trifluoromethyl groups, A is the same or different and represents divalent radicals R" is a chemical bond or a divalent radical of the formula --CH.sub.2 --O--, --O--CH.sub.2 --, y is an integer having a value of from 0 to 10, preferably from 0 to 2, z is an integer having a value of from 0 to 10, preferably from 0 to 2, with the proviso that the sum y+z is at least 1, and T is a cholesteryl radical or a substituted or unsubstituted hydrocarbon radical having from 1 to 18 carbon atoms, in which the substituents are preferably selected from the group consisting of halogen atoms, cyano groups, nitro groups, hydrocarbonoxy groups having from 1 to 10 carbon atoms and mixtures thereof.

    摘要翻译: 本发明涉及具有至少一个结合到硅原子 - (CH 2)x R“ - ( - LA-)y - (L)zT(1)的式(1)的基团的环状硅氧烷,其中x是 整数,其值至少为2,优选为2至10,R“为化学键或式-COO - , - OOC - , - CH 2 -CH 2 - , - CH = CH - , - C(三键)C - , - N = N - , - N = N,-N = CH-,-CH = N或-Si(R)2 - ,其中基团R相同或不同, 是具有1至18个碳原子的任选取代的烃基,相同或不同的L代表任选为2-,3-,5-和/或6的1,4-亚苯基或1,4-亚环己基 被至少一个基团Q取代,Q是选自氢,氟或氯原子的相同或不同的基团或氰基,甲基或三氟甲基,A相同或不同,表示二价基团R“是化学键或 式-CH 2 -O - , - O-CH 2 - 的二价基团,y是具有va的整数 0至10,优选0至2,z为0至10,优选0至2的整数,条件是和y + z至少为1,T为 胆固醇基或具有1至18个碳原子的取代或未取代的烃基,其中取代基优选选自卤素原子,氰基,硝基,具有1至10个碳原子的烃氧基及其混合物 。