公开(公告)号：US4028283A

公开(公告)日：1977-06-07

申请号：US725184

申请日：1976-09-21

申请人： Moriyasu Murata ,  Fumio Sai ,  Takashi Fujino

发明人： Moriyasu Murata ,  Fumio Sai ,  Takashi Fujino

IPC分类号： C11D1/12 ,  C11D1/74 ,  C11D3/37 ,  C11D1/06 ,  C11D1/37

CPC分类号： C11D1/12 ,  C11D1/74 ,  C11D3/37 ,  C11D3/3761

摘要： A granular or powdery detergent composition comprising (I) as an active detergent component a surface active agent having a tendency to cake, and (II) as an anti-caking agent, from 0.2 to 20% by weight, based on the total weight of the detergent composition, of a carboxylic acid or an alkali metal salt thereof obtained by reacting (A) a polyalkylene glycol and (B) an acid anhydride, at an (A)/(B) mole ratio of from 1/2 to 1/1, said polyalkylene glycol being selected from (i) polyethylene glycols having an average molecular weight of 2000 to 10000 and (ii) nonionic surface active agents having the formula: ##STR1## wherein a, b and c are numbers satisfying the relations:140 .ltoreq. A + C .ltoreq. 200 AND 30 .ltoreq. B .ltoreq. 40,and the acid anhydride is selected from the group consisting of maleic anhydride, phthalic anhydride and succinic anhydride, and wherein the weight ratio of (II)/(I) is from 1/10 to 3/2.

摘要翻译： 一种粒状或粉末洗涤剂组合物，其包含（I）作为活性洗涤剂组分的具有饼干倾向的表面活性剂，和（II）作为抗结块剂，基于总重量的0.2至20重量％ 洗涤剂组合物，通过使（A）聚亚烷基二醇和（B）酸酐以（A）/（B）摩尔比为1/2至1/1的比例反应获得的羧酸或其碱金属盐， 1，所述聚亚烷基二醇选自（i）平均分子量为2000至10000的聚乙二醇和（ii）具有下式的非离子表面活性剂：其中a，b和c是满足下列关系的数：

公开(公告)号：US4208295A

公开(公告)日：1980-06-17

申请号：US5656

申请日：1979-01-22

申请人： Fumio Sai ,  Takashi Fujino

发明人： Fumio Sai ,  Takashi Fujino

IPC分类号： C11D3/12 ,  C11D3/39 ,  C11D3/395 ,  C11D7/54

CPC分类号： C11D3/3942 ,  C11D3/128

摘要： A bleaching detergent composition comprises (i) a water-insoluble aluminosilicate having a degree of crystallization of 0 to 75% or a water-insoluble aluminosilicate having exchangeable cations partially substituted by calcium and/or magnesium ions, (ii) a surface active agent and (iii) sodium percarbonate. It is very much improved in respect to the storage stability of the sodium percarbonate.

摘要翻译： 漂白洗涤剂组合物包含（i）具有0至75％结晶度的水不溶性硅铝酸盐或具有部分被钙和/或镁离子取代的可交换阳离子的水不溶性硅铝酸盐，（ii）表面活性剂和 （iii）过碳酸钠。 在过碳酸钠的储存稳定性方面有很大的改善。

公开(公告)号：US4178354A

公开(公告)日：1979-12-11

申请号：US858794

申请日：1977-12-08

申请人： Moriyasu Murata ,  Fumio Sai ,  Takashi Fujino

发明人： Moriyasu Murata ,  Fumio Sai ,  Takashi Fujino

IPC分类号： C09K3/00 ,  B01J20/10 ,  B01J39/12 ,  C01B25/36 ,  C01B25/45 ,  C01B37/06 ,  C01B39/54 ,  C02F5/08 ,  C11D3/12 ,  C01B25/26

CPC分类号： C01B33/28 ,  B01J20/10 ,  B01J39/12 ,  C02F5/086 ,  C11D3/128

摘要： An agent for sequestering heavy-metal ions comprising a water-insoluble amorphous alkali metal aluminosilicophosphate having the formula (I):[x(M.sub.2 O).Al.sub.2 O.sub.3.y (SiO.sub.2).z(P.sub.2 O.sub.5).w(H.sub.2 O)] (I)wherein M is alkali metal selected from the group consisting of Na, K and Li, x, y, z and w are integers representing the mole numbers of the respective components, wherein x, y and z satisfy the following relations:0.20.ltoreq.x.ltoreq.1.10,0.20.ltoreq.y.ltoreq.4.00, and0.001.ltoreq.z.ltoreq.0.80,and w is or zero an optional positive number.

摘要翻译： 包含具有式（I）的水不溶性无定形碱金属铝硅磷酸盐螯合重金属离子的试剂：[x（M 2 O）·Al 2 O 3·y（SiO 2）·z（P 2 O 5）·w（H 2 O）]（I） 其中M是选自Na，K和Li的碱金属，x，y，z和w是表示各组分的摩尔数的整数，其中x，y和z满足以下关系：0.20 < x

公开(公告)号：US4028280A

公开(公告)日：1977-06-07

申请号：US715379

申请日：1976-08-18

申请人： Moriyasu Murata ,  Fumio Sai ,  Takashi Fujino

发明人： Moriyasu Murata ,  Fumio Sai ,  Takashi Fujino

IPC分类号： C11D1/37 ,  C11D1/29 ,  C11D3/00 ,  C11D3/065 ,  C11D1/14 ,  C11D3/08

CPC分类号： C11D1/29

摘要： A detergent composition comprising as all or a part of the active detergent component (A) a mixture of up to 70% by weight of unbranched-alkyl ether sulfate, or mixtures thereof, having the formula (I):r.sub.1 --o--(ch.sub.2 ch.sub.2 o).sub.n SO.sub.3 M (I)wherein R.sub.1 is unbranched alkyl (CH.sub.3 (CH.sub.2).sub.p --) having a total number of from 6 to 15 carbon atoms and having a carbon atom number distribution such that the average carbon atom number is within the range of from 8 to 13, n is from 0.5 to 1.5 as an average number in the mixture, and M is alkali metal, alkaline earth metal, ammonium or alkanol amine,And at least 30% by weight of a branched alkyl ether sulfate, or mixtures thereof, having the formula (II): ##STR1## wherein R.sub.2 is an unbranched alkyl having 1 to 12 carbon atoms, R.sub.3 is an unbranched alkyl having 1 to 4 carbon atoms, the group ##STR2## having a carbon number distribution such that the average carbon atom number thereof is within the range of from 8 to 13, and n and M are as defined above for formula (I),and (B) an unbranched alkyl ether sulfate, or mixtures thereof, having the formula (III):r.sub.4 --o--(ch.sub.2 ch.sub.2 o).sub.m SO.sub.3 M (III)wherein R.sub.4 is unbranched saturated alkyl in which the alkyl group having 18 carbon atoms occupies at least 80 percent by weight of the whole component (B), m is 1 to 50 on the average and M is as defined above for formulae (I) and (II),the ratio of (A) to (B) being in the range between 95 : 5 and 5 : 95.

摘要翻译： 一种洗涤剂组合物，其包含作为全部或部分活性洗涤剂组分（A）的具有式（I）的至多70重量％的未分支烷基醚硫酸盐或其混合物的混合物：

公开(公告)号：US4029608A

公开(公告)日：1977-06-14

申请号：US725171

申请日：1976-09-21

申请人： Moriyasu Murata ,  Fumio Sai ,  Takashi Fujino

发明人： Moriyasu Murata ,  Fumio Sai ,  Takashi Fujino

IPC分类号： C11D3/37 ,  B01F17/02 ,  C11D1/12 ,  C11D1/72 ,  C11D1/83 ,  C11D3/20

CPC分类号： C11D1/72 ,  C11D1/12 ,  C11D1/83

摘要： A granular or powdery detergent composition comprising a surface active agent having a tendency to cake, and containing as an anti-caking agent from 0.2 to 20 % by weight of a polyoxyethylene alkyl or alkenyl ether which is solid at room temperature and has the formula:RO(CH.sub.2 CH.sub.2 O).sub.n Hwherein R is alkyl or alkenyl having 12 to 18 carbon atoms, and n is a number from 100 to 300.

摘要翻译： 一种颗粒状或粉末状洗涤剂组合物，其包含具有粘结倾向的表面活性剂，并且含有作为抗结块剂的0.2至20重量％的在室温下为固体的聚氧乙烯烷基或链烯基醚，并具有下式：

公开(公告)号：US3998762A

公开(公告)日：1976-12-21

申请号：US632194

申请日：1975-11-17

申请人： Moriyasu Murata ,  Makoto Yamanaka ,  Fumio Sai ,  Takashi Fujino

发明人： Moriyasu Murata ,  Makoto Yamanaka ,  Fumio Sai ,  Takashi Fujino

IPC分类号： C11D1/14 ,  C11D1/29 ,  C11D3/20 ,  C11D3/37 ,  C11D1/37 ,  C11D3/065

CPC分类号： C11D1/29 ,  C11D1/143 ,  C11D1/146 ,  C11D3/2082 ,  C11D3/3707

摘要： A granular or powdery detergent composition containing as a detergent active component a surfactant having a tendency to cake, wherein the composition contains as a caking-preventing agent the combination of (a) at least 0.2% by weight of a polyethylene glycol having a molecular weight of at least 2000 and (b) at least 0.2% by weight of at least one anhydrous organic acid, or anhydride, or salt thereof, selected from the group consisting of sulfosuccinic acid and its salts, maleic anhydride, maleic acid and its salts, succinic anhydride, succinic acid and its salts, the total amount of the components (a) and (b) being 0.4 to 40% by weight, based on the weight of the detergent composition.

摘要翻译： 作为洗涤剂活性成分含有表面活性剂的粒状或粉末状洗涤剂组合物，其具有粘结的倾向，其中组合物含有防结块剂，（a）至少0.2重量％的具有分子量的聚乙二醇 至少2000和（b）至少0.2重量％的至少一种选自磺基琥珀酸及其盐，马来酸酐，马来酸及其盐的无水有机酸或其酸酐或其盐， 琥珀酸酐，琥珀酸及其盐，基于洗涤剂组合物的重量，组分（a）和（b）的总量为0.4至40重量％。

公开(公告)号：US3960780A

公开(公告)日：1976-06-01

申请号：US627701

申请日：1975-10-31

申请人： Moriyasu Murata ,  Makoto Yamanaka ,  Fumio Sai

发明人： Moriyasu Murata ,  Makoto Yamanaka ,  Fumio Sai

IPC分类号： B01F17/02 ,  C11D1/29 ,  C11D3/37 ,  C11D1/14 ,  C11D17/06

CPC分类号： C11D3/3707 ,  C11D1/29

摘要： A granular or powdery detergent composition comprising from 3 to 25% by weight of a surfactant selected from ether sulfates having the formulae (I) and (II): ##EQU1## and ##EQU2## wherein R.sub.1 and R.sub.2 are hydrogen, alkyl having 1 to 21 carbon atoms or alkenyl having 1 to 21 carbon atoms, provided that the sum of the carbon atoms of R.sub.1 and R.sub.2 is 11 to 21, R.sub.3 is alkyl having 8 to 16 carbon atoms, n is a number of 1 to 10, and M is an alkali metal or an alkaline earth metal,And 10 to 100% by weight, based on said ether sulfate, of a polyethylene glycol having a molecular weight of 2,000 to 50,000.

摘要翻译： 包含3至25重量％的选自具有式（I）和（II）的醚硫酸盐的表面活性剂的颗粒或粉末洗涤剂组合物：R1 ANGLE CH-O-（CH2CH2O）nSO3M（I）R2和O-（ CH 2 CH 2 O）n SO 3 M（II）其中R 1和R 2为氢，具有1至21个碳原子的烷基或具有1至21个碳原子的烯基，条件是R 1和R 2的碳原子总数为11至21，R 3为具有 8〜16个碳原子，n为1〜10的数，M为碱金属或碱土金属，10重量％以重量计，基于硫酸钠，具有分子量的聚乙烯甘油 2,000至50,000。

公开(公告)号：US5427711A

公开(公告)日：1995-06-27

申请号：US246711

申请日：1994-05-20

申请人： Mikio Sakaguchi ,  Ichiro Sakamoto ,  Mutsumi Kuroda ,  Masaki Tsumadori ,  Motomitsu Hasumi ,  Yuichi Sakamoto ,  Ryuichi Akagi ,  Fumio Sai

发明人： Mikio Sakaguchi ,  Ichiro Sakamoto ,  Mutsumi Kuroda ,  Masaki Tsumadori ,  Motomitsu Hasumi ,  Yuichi Sakamoto ,  Ryuichi Akagi ,  Fumio Sai

IPC分类号： B01J39/08 ,  B01J39/14 ,  C01B33/20 ,  C01B33/36 ,  C11D3/12 ,  C11D3/386 ,  C01B33/24 ,  C01B33/32 ,  C11D7/02

CPC分类号： C11D3/38636 ,  B01J39/085 ,  B01J39/14 ,  C01B33/20 ,  C01B33/36 ,  C11D3/1246 ,  C11D3/126

摘要： The synthesized crystalline ion exchange material or a hydrate thereof has a chain structure and a composition represented by the following general formula (A) in an anhydride form:xM.sub.2 O.ySiO.sub.2.zM'O, (A)wherein M represents Na and/or K; M' represents Ca and/or Mg; y/x is 0.5 to 2.0; and z/x is 0.005 to 1.0. The chain structure exhibits at least one main scattering peak at 970.+-.20 cm.sup.-1 in Raman spectra. The detergent composition contains the above synthesized inorganic crystalline ion exchange material. The inorganic ion exchange material of the present invention is excellent in both cationic exchange capacity and anti-solubility, making it useful to be used for a water softener and alkalinity regulator in detergents. The detergent composition of the present invention contains an inorganic ion exchange material which has anti-solubility as well as excellent ion exchange capacity and alkaline capacity, thereby offering excellent washing effects and is suitable for the concentration of detergent.

摘要翻译： 合成的结晶离子交换材料或其水合物具有以下通式（A）表示的链状结构和酸酐形式的组成：xM2O.ySiO2.zM'O，（A）其中M表示Na和/或K ; M'表示Ca和/或Mg; y / x为0.5〜2.0; z / x为0.005〜1.0。 该链结构在拉曼光谱中显示出970 +/- 20cm-1处的至少一个主散射峰。 洗涤剂组合物含有上述合成的无机结晶离子交换材料。 本发明的无机离子交换材料的阳离子交换容量和抗溶解性均优异，因此可用于洗涤剂中的软水剂和碱度调节剂。 本发明的洗涤剂组合物含有具有抗溶解性以及优异的离子交换容量和碱性能的无机离子交换材料，从而提供优异的洗涤效果，适用于洗涤剂的浓缩。

公开(公告)号：US5411674A

公开(公告)日：1995-05-02

申请号：US943123

申请日：1992-09-10

申请人： Shuji Tagata ,  Fumio Sai

发明人： Shuji Tagata ,  Fumio Sai

IPC分类号： C11D1/28 ,  C11D1/12 ,  C11D1/14 ,  C11D1/22 ,  C11D1/29 ,  C11D1/52 ,  C11D1/66 ,  C11D1/72 ,  C11D1/75 ,  C11D1/83 ,  C11D10/04 ,  C11D1/10 ,  C11D1/04

CPC分类号： C11D10/045 ,  C11D10/04 ,  C11D10/042 ,  C11D1/123 ,  C11D1/14 ,  C11D1/143 ,  C11D1/22 ,  C11D1/29 ,  C11D1/523 ,  C11D1/662 ,  C11D1/72 ,  C11D1/75

摘要： A detergent composition which has an excellent detergency against muddy dirt of clothing. It comprises (a) nonionic surfactant, (b) fatty acid or salt thereof and (c) sulfosuccinic amide, and further (d) anionic surfactant as occasion demands.

摘要翻译： 一种洗涤剂组合物，其对衣物的泥土污垢具有优异的去污力。 它包括（a）非离子表面活性剂，（b）脂肪酸或其盐和（c）磺基琥珀酰胺，以及（d）阴离子表面活性剂。

公开(公告)号：US4163732A

公开(公告)日：1979-08-07

申请号：US853245

申请日：1977-11-21

申请人： Fumio Sai ,  Moriyasu Murata

发明人： Fumio Sai ,  Moriyasu Murata

IPC分类号： C11D3/12 ,  C11D3/36 ,  C11D3/08 ,  C11D7/36

CPC分类号： C11D3/128

摘要： A detergent composition containing, as a builder component, a water-insoluble, phosphorus-containing alkali metal aluminosilicate having the formulaX(M.sub.2 O).multidot.Al.sub.2 O.sub.3 .multidot.Y(SiO.sub.2).multidot.z(P.sub.2 O.sub.5).multidot.w(H.sub.2 O)wherein0.50.ltoreq.x.ltoreq.1.100.80.ltoreq.y.ltoreq.2.500.05.ltoreq.z.ltoreq.0.80and w is zero or an optional positive number.

摘要翻译： 一种洗涤剂组合物，其含有具有式X（M 2 O）x Al 2 O 3 x Y（SiO 2）x z（P 2 O 5）xw（H 2 O）的水不溶性的含磷碱金属硅铝酸盐作为助洗剂组分，其中0.050≤X= 1。