Purification of diethynylbenzenes
    2.
    发明授权
    Purification of diethynylbenzenes 失效
    二丁基苯酚的纯化

    公开(公告)号:US3594437A

    公开(公告)日:1971-07-20

    申请号:US3594437D

    申请日:1969-11-28

    Applicant: GEN ELECTRIC

    Inventor: WHITE DWAIN M

    CPC classification number: C07C7/14 C07C15/48

    Abstract: IMPURE DIETHYNYLBENZENES ARE PURIFIED BY COOLING A SOLUTION OF THE MATERIAL IN A LIQUID ALKANE, MAINTAINING THE TEMPERATURE OF THE SOLUTION AT LEAST AS LOW AS -50*C., UNTIL THE PURIFIED DIETHYNYLBENZENE PRECIPITATES FROM THE SOLUTION AND ISOLATING THE PRECIPITATE FROM THE SOLUTION.

    Process for producing phenols and xanthenes
    3.
    发明授权
    Process for producing phenols and xanthenes 失效
    生产酚醛和辛烷的方法

    公开(公告)号:US3522275A

    公开(公告)日:1970-07-28

    申请号:US3522275D

    申请日:1967-08-11

    Applicant: GEN ELECTRIC

    Abstract: 1,219,638. Preparing phenols and xanthenes. GENERAL ELECTRIC CO. 27 June, 1968 [11 Aug., 1967], No. 30743/68. Heading C2C. Phenols of the formula where R, R 1 and R 11 are H atoms, or alkyl, cycloalkyl, alkaryl, aryl or aralkyl radicals, R 1 in addition can be an alkoxy radical, R 11 in addition can be an OH, alkoxy or aryloxy radical, and a pair of adjacent R 11 radicals or R 1 and R 11 radicals may represent a fused ring system, are obtained by heating in an inert atmosphere a diphenyl ether of formula to a temperature of 250‹ to 450‹ C., and when an R 1 on the benzene nucleus which does not contain the R 2 CH group is hydrogen, xanthenes of the formula are obtained. An oxidizing agent may be added to the reaction mixture. Examples are given for the production of the compounds. The invention also comprises the following compounds per se: 2-methyl-6-(diphenylmethyl) - phenol, 2 - methyl - 6 - (4 - -methoxybenzyl) - phenol, 2 - methyl - 6 - (3,5 - dimethyl- 4 - methoxy - or - hydroxybenzyl) - phenol.

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