Abstract:
A method for forming a hybrid zeolitic imidazolate framework (ZIF) comprises the formation steps of: preparing a first solution comprising: a 2-methylimidazolate or a functionalized derivative thereof; and a carboxaldehyde-2-imidazolate or a functionalized derivative thereof; preparing a second solution comprising a metal ion; and combining the first solution and the second solution to form the hybrid ZIF, wherein a first fraction of 2-methylimidazolate or a functionalized derivative thereof in the hybrid ZIF is from about 5 to about 95 or any value there between and a second fraction carboxaldehyde-2-imidazolate or a functionalized derivative thereof in the hybrid ZIF is 100—the first fraction is disclosed. A metal-organic framework (MOF) comprising the hybrid ZIF and a molecular sieve device comprising the hybrid ZIF are also disclosed.
Abstract:
The disclosed technology includes a membrane-based device configured to concentrate black liquor, which results from papermaking. Certain embodiments may comprise a nanofiltration membrane configured to remove lignin from black liquor, and the nanofiltration membrane may include a first macroporous polymer substrate and a first graphene oxide membrane covering the first macroporous polymer substrate. Some embodiments may comprise a reverse osmosis membrane, which may include a second macroporous polymer substrate and a second graphene oxide membrane covering the second macroporous polymer substrate.
Abstract:
The disclosed technology includes a membrane-based device configured to concentrate black liquor, which results from papermaking. Certain embodiments may comprise a nanofiltration membrane configured to remove lignin from black liquor, and the nanofiltration membrane may include a first macroporous polymer substrate and a first graphene oxide membrane covering the first macroporous polymer substrate. Some embodiments may comprise a reverse osmosis membrane, which may include a second macroporous polymer substrate and a second graphene oxide membrane covering the second macroporous polymer substrate.
Abstract:
Systems, devices and methods for molecular separation including a molecular separation device comprising at least a polycrystalline metal-organic framework (MOF) and a nanocrystalline, zeolite MFI, wherein the MOF forms a polycrystalline membrane with zeolite MFI nanoparticles dispersed therein, and the MOF membrane matrix contacting and surrounding the zeolite MFI nanoparticles form a permselective nanoporous structure.
Abstract:
Systems, devices and methods for molecular separation including a molecular separation device comprising at least a polycrystalline metal-organic framework (MOF) and a nanocrystalline, zeolite MFI, wherein the MOF forms a polycrystalline membrane with zeolite MFI nanoparticles dispersed therein, and the MOF membrane matrix contacting and surrounding the zeolite MFI nanoparticles form a permselective nanoporous structure.
Abstract:
The disclosed technology includes a membrane-based device configured to concentrate black liquor, which results from papermaking. Certain embodiments may comprise a nanofiltration membrane configured to remove lignin from black liquor, and the nanofiltration membrane may include a first macroporous polymer substrate and a first graphene oxide membrane covering the first macroporous polymer substrate. Some embodiments may comprise a reverse osmosis membrane, which may include a second macroporous polymer substrate and a second graphene oxide membrane covering the second macroporous polymer substrate.