ZIF-8-90 METAL ORGANIC FRAMEWORK (MOF) MEMBRANES FOR n-BUTANE/i-BUTANE SEPARATIONS
    1.
    发明申请
    ZIF-8-90 METAL ORGANIC FRAMEWORK (MOF) MEMBRANES FOR n-BUTANE/i-BUTANE SEPARATIONS 审中-公开
    ZF-8-90金属有机骨架(MOF)用于正丁醇/非丁醇分离的膜

    公开(公告)号:US20160130199A1

    公开(公告)日:2016-05-12

    申请号:US14926395

    申请日:2015-10-29

    CPC classification number: C07C7/144 B01D69/148 C07F3/06 C07F15/065

    Abstract: A method for forming a hybrid zeolitic imidazolate framework (ZIF) comprises the formation steps of: preparing a first solution comprising: a 2-methylimidazolate or a functionalized derivative thereof; and a carboxaldehyde-2-imidazolate or a functionalized derivative thereof; preparing a second solution comprising a metal ion; and combining the first solution and the second solution to form the hybrid ZIF, wherein a first fraction of 2-methylimidazolate or a functionalized derivative thereof in the hybrid ZIF is from about 5 to about 95 or any value there between and a second fraction carboxaldehyde-2-imidazolate or a functionalized derivative thereof in the hybrid ZIF is 100—the first fraction is disclosed. A metal-organic framework (MOF) comprising the hybrid ZIF and a molecular sieve device comprising the hybrid ZIF are also disclosed.

    Abstract translation: 形成杂合沸石咪唑酸酯骨架(ZIF)的方法包括以下步骤:制备包含2-甲基咪唑酸酯或其官能化衍生物的第一溶液; 和羧甲基-2-咪唑酸酯或其官能化衍生物; 制备包含金属离子的第二溶液; 以及将所述第一溶液和所述第二溶液组合以形成所述杂化ZIF,其中所述杂化ZIF中的2-甲基咪唑酸盐或其官能化衍生物的第一级分为约5至约95或其间的任何值和第二级分甲醛 - 混合ZIF中的2-咪唑啉或其官能化衍生物为100-公开了第一级分。 还公开了包含杂化ZIF的金属 - 有机骨架(MOF)和包含混合ZIF的分子筛装置。

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