Abstract:
A coating for conversion of formaldehyde to carbon dioxide includes an alcohol/aldehyde oxidase and a formate oxidase immobilized on a solid particulate support; and a latex binder.
Abstract:
The present disclosure provides for alkyl-aryl amine rich molecules impregnated into various porous substrates were examined for potential use as sorbents for CO2 capture from dilute and ultra-dilute gas streams such as flue gas and ambient air, respectively.
Abstract:
Described are single-walled metal oxide nanotubes having a plurality of organic functional units or moieties bonded generally in a covalent manner to the inner wall of the single-walled nanotubes. Functionalization of the single-walled metal oxide nanotubes is performed in a single-step during synthesis of the nanotubes. The organic functional units are found dispersed throughout the length of the inner wall and not sterically hindered or contained at only the mouth or ends of the single-walled metal oxide nanotubes.
Abstract:
Described is a liquid separation device comprising a porous support structure further comprising polymeric hollow fibers; an inorganic mesoporous silica membrane disposed on the porous support structure, wherein the inorganic mesoporous silica membrane is free of defects; and wherein the inorganic mesoporous silica membrane has a network of interconnected three-dimensional pores that interconnect with the porous support structure; and wherein the inorganic mesoporous silica membrane is a silylated mesoporous membrane. Also described are methods for making and using the liquid separation device.
Abstract:
A tunable species removal media including a polymer-impregnated porous material with the introduction of heteroatoms into the porous material during the synthesis of the oxide support. The polymer can be poly(ethyleneimine) (PEI), the porous material a framework of silica nanoparticles, and the heteroatoms selected from Zr, Ti, Fe, Ce, Al, B, Ga, Co, Ca, P, and Ni. The media has a CO2 adsorption of greater than 0.19 mmol CO2/g when exposed to a 400 ppm CO2/Ar flow at a rate of 100 mL/min, and can also have a CO2 adsorption of greater than 0.65 mmol CO2/g when exposed to a 10% CO2/Ar flow at a rate of 100 mL/min. The media can have a heteroatom/Si molar ratio greater than or equal to 0.002.
Abstract translation:一种可调物质去除介质,包括聚合物浸渍的多孔材料,在合成氧化物载体期间将杂原子引入多孔材料中。 聚合物可以是聚(乙烯亚胺)(PEI),多孔材料是二氧化硅纳米颗粒的骨架,以及选自Zr,Ti,Fe,Ce,Al,B,Ga,Co,Ca,P和Ni的杂原子。 当以100mL / min的速率暴露于400ppm CO 2 / Ar流时,介质具有大于0.19mmol CO 2 / g的CO 2吸附,并且当暴露时,介质也可以具有大于0.65mmol CO 2 / g的CO 2吸附 至100%/分钟的10%CO 2 / Ar流。 介质可以具有大于或等于0.002的杂原子/ Si摩尔比。
Abstract:
The present disclosure is directed towards sorbents, contactors, methods of using sorbents or contactors to capture CO2, and systems and devices using the sorbents or contactors to capture CO2. The methods, systems, contactors, and sorbents of the present disclosure can be advantageous over current technologies since they are relatively more robust and reduce the cost of capturing CO2, in particular from ambient air.
Abstract:
Supported amine polymer adsorbents based on polymers containing only or primarily primary amines sites are to be used as regenerable adsorbents for CO2 capture from ultra-dilute gas streams, such as ambient air, or from mixtures of gases containing preferably at least I 0% oxygen. and can also be useful for use at the moderate gas pressures found in typical post-combustion capture processes, such as flue gas from large point sources such as coal-fired power plants. Preferred supported solid amine adsorbents of this invention are based on poly(allylamine) (“PAA”) and poly(vinyl amine) (“PVAm”), both of which are linear polymers, and their derivatives, containing substantially all primary amine groups, supported on substrates. Preferred such substrates include silica mesocellular foam (MCF) and mesoporous-.gamma.-alumina, as well on mesoporous-.gamma.-alumina coated throughout the pores of MCF, most preferably of monolithic structure. Preferred derivatives include the guanidinylated and cross-linked poly(allylamine) materials.
Abstract:
Systems, devices and methods for molecular separation including a molecular separation device comprising at least a polycrystalline metal-organic framework (MOF) and a nanocrystalline, zeolite MFI, wherein the MOF forms a polycrystalline membrane with zeolite MFI nanoparticles dispersed therein, and the MOF membrane matrix contacting and surrounding the zeolite MFI nanoparticles form a permselective nanoporous structure.
Abstract:
Supported amine polymer adsorbents based on polymers containing only or primarily primary amines sites are to be used as regenerable adsorbents for CO2 capture from ultra-dilute gas streams, such as ambient air, or from mixtures of gases containing preferably at least 10% oxygen. and can also be useful for use at the moderate gas pressures found in typical post-combustion capture processes, such as flue gas from large point sources such as coal-fired power plants. Preferred supported solid amine adsorbents of this invention are based on poly(allylamine) (“PAA”) and poly(vinyl amine) (“PVAm”), both of which are linear polymers, and their derivatives, containing substantially all primary amine groups, supported on substrates. Preferred such substrates include silica mesocellular foam (MCF) and mesoporous-γ-alumina, as well on mesoporous-γ-alumina coated throughout the pores of MCF, most preferably of monolithic structure. Preferred derivatives include the guanidinylated and cross-linked poly(allylamine) materials.